全文获取类型
收费全文 | 1320篇 |
免费 | 31篇 |
国内免费 | 24篇 |
专业分类
化学 | 898篇 |
晶体学 | 17篇 |
力学 | 17篇 |
数学 | 289篇 |
物理学 | 154篇 |
出版年
2022年 | 18篇 |
2021年 | 30篇 |
2020年 | 12篇 |
2019年 | 18篇 |
2018年 | 23篇 |
2017年 | 20篇 |
2016年 | 38篇 |
2015年 | 31篇 |
2014年 | 44篇 |
2013年 | 103篇 |
2012年 | 71篇 |
2011年 | 76篇 |
2010年 | 49篇 |
2009年 | 36篇 |
2008年 | 61篇 |
2007年 | 85篇 |
2006年 | 73篇 |
2005年 | 60篇 |
2004年 | 68篇 |
2003年 | 45篇 |
2002年 | 51篇 |
2001年 | 33篇 |
2000年 | 22篇 |
1999年 | 16篇 |
1998年 | 18篇 |
1997年 | 15篇 |
1996年 | 23篇 |
1995年 | 20篇 |
1994年 | 11篇 |
1993年 | 19篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 13篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1987年 | 12篇 |
1986年 | 6篇 |
1985年 | 14篇 |
1984年 | 15篇 |
1983年 | 9篇 |
1982年 | 13篇 |
1981年 | 18篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1974年 | 3篇 |
1973年 | 6篇 |
1972年 | 5篇 |
1970年 | 2篇 |
排序方式: 共有1375条查询结果,搜索用时 15 毫秒
41.
Alicja Boryło Bogdan Skwarzec Grzegorz Romańczyk Janusz Siebert 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(3):1685-1691
The determination of polonium 210Po in human blood samples is presented and discussed in this paper. The human blood samples were collected from patients of Medical University of Gdańsk with ischaemic heart disease (morbus ischaemicus cordis, MIC). The polonium concentrations in analyzed human blood samples are very differentiated. 210Po is of particular interest in public health and although is present in the environment in extremely low amounts, it is easily bioaccumulated to the human body. The study shows that the amount of 210Po that is incorporated into the human body depends on the food habits and some difference in its levels could be observed between smokers and non-smokers. 相似文献
42.
A food web model with a closed nutrient cycle is presented and analyzed via Monte Carlo simulations. The model consists of three trophic levels, each of which is populated by animals of one distinct species. While the species at the intermediate level feeds on the basal species, and is eaten by the predators living at the highest level, the basal species itself uses the detritus of animals from higher levels as the food resource. The individual organisms remain localized, but the species can invade new lattice areas via proliferation. The impact of different proliferation strategies on the viability of the system is investigated. From the phase diagrams generated in the simulations it follows that in general a strategy with the intermediate level species searching for food is the best for the survival of the system. The results indicate that both the intermediate and top level species play a critical role in maintaining the structure of the system. 相似文献
43.
Szymon Godlewski Jakub S. Prauzner-Bechcicki Janusz Budzioch Lukasz Walczak Irena G. Stará Ivo Starý Petr Sehnal Marek Szymonski 《Surface science》2012,606(21-22):1600-1607
Helicenes are carbon-rich materials with an ordered structure that possess interesting and remarkable electronic, chiroptical, mechanical and magnetic properties either in bulk or as single molecule devices. We report on the first attempt to anchor and organize [11]anthrahelicene ([11]AH) molecules onto a metal oxide surface. Molecular structures obtained on the (110) and (011) faces of rutile titania are characterized using scanning probe microscopy. On the (110) surface, [11]AH molecules form islands that are comprised of small domains of two types that are mirror reflections of each other and have an ordered quasi-hexagonal lattice. In contrast, molecules form unordered clusters on the (011) surface. Single molecules on both faces are imaged with sub-molecular resolution. 相似文献
44.
Three new chiral urea-type anion receptors were synthesized from aromatic diamines and 1-amino-1-deoxyglucose. The anion binding properties of these receptors were studied using chiral carboxylates derived from mandelic acid and three α-amino acids. We found that the size of the anion binding pocket played an important role in chiral recognition processes. The best results were obtained for 1,8-diaminoanthracene and α-amino acid anions. 相似文献
45.
2,5- and 2,6-dideuterobenzoquinone-1,4 were prepared by a direct catalytic (NaBD4/PdCl2) exchange of bromine in the corresponding dibromo derivatives and the subsequent oxidation with Ag2O. The structure of the products was unambiguously established by proton-carbon and deuteron-carbon splitting pattern of their NMR spectra. 相似文献
46.
47.
Michal Achmatowicz Agnieszka Szczepańska Daniel T. Gryko Piotr Salański Janusz Jurczak 《Supramolecular chemistry》2013,25(1):93-95
Abstract Bisamidation of oxaloyl chloride using L-amino acid methyl ester hydrochlorides afforded chiral diesters. The following reactions of diesters with 2,2-(ethylene-dioxy)diethylamine, afforded tetramides possessing C2 symmetry. Coupling of N-hydroxysuccinimide ester of N-benzyloxycarbonyl-L-alanine with 1,5-diamino-3-oxapentane, followed by cleavage of protecting groups, afforded an optically active diamine, which was transformed consequently into tetramide via the reaction with diglycolic acid dimethyl ester under high pressure conditions. 相似文献
48.
Agata Górniak Bożena Karolewicz Ewa Żurawska-Płaksej Janusz Pluta 《Journal of Thermal Analysis and Calorimetry》2013,111(3):2125-2132
The objective of the present investigation was to study the effect of eutectic formation on in vitro dissolution of simvastatin (SIM) released from mixtures with acetylsalicylic acid (ASA) prepared by a grinding method. SIM–ASA mixtures were characterized by means of differential scanning calorimetry (DSC), infrared spectroscopy (IR), X-ray powder diffractometry (XRPD), and in vitro dissolution tests. IR spectroscopy and XRPD studies indicated no interaction between SIM and ASA in the solid state. The DSC investigation has revealed that SIM and ASA form a simple eutectic system containing 66.6 % w/w of SIM at the eutectic point. In vitro dissolution studies of SIM and its mixtures with ASA were carried out. The eutectic mixture shows an appreciable increase in the dissolution rate in comparison with other ratios and SIM in 0.5 % w/v sodium lauryl sulfate. The dissolution enhancement of SIM was related to the effective wetting of the drug particles with a significantly reduced size released from eutectic composition. In conclusion, dissolution of SIM can be enhanced through eutectic formation with ASA by means of simple mechanical activation (a grinding method). 相似文献
49.
Niko Guskos Janusz Typek Aleksander Guskos Grzegorz Zolnierkiewicz Pawel Berczynski Diana Dolat Barbara Grzmil Antoni Morawski 《Central European Journal of Chemistry》2013,11(12):1996-2004
Nanoparticles of nitrogen-modified TiO2 (N-doped TiO2) calcined at 300°C and 350°C, have been prepared with and without water rinsing. Samples were characterized by x-ray diffractrometry (XRD) and optical spectroscopy. The electron paramagnetic resonance (EPR) spectra from centers involving oxygen vacancies were recorded for all samples. These could be attributed to paramagnetic surface centers of the hole type, for example to paramagnetic oxygen radicals O?, O2 ? etc. The concentration of these centers increased after water rising and it further increased for samples annealed at higher temperature. Additionally, for samples calcined at 300°C, and calcined at 350°C and rinsed, the EPR spectra evidenced the presence of magnetic clusters of Ti3+ ions. The photocatalytic activity of samples was studied towards phenol decomposition under unltraviolet-visible (UV-Vis) irradiation. It was found that, in comparison to the starting materials, the rinsed materials showed increased photocatalytic activity towards phenol oxidation. The light absorption (UV-Vis/DRS) as well as surface Fourier transform infrared/diffuse reflectance spectroscopy (FTIR/DR) studies confirmed a significantly enhanced light absorption and the presence of nitrogen groups on the photocatalysts surfaces, respectively. A significant increase of concentration of paramagnetic centers connected with oxygen vacancies after water rising has had an essential influence on increasing their photocatalytic activity. 相似文献
50.
Barbara Bojko Krzysztof Gorynski German Augusto Gomez-Rios Jan Matthias Knaak Tiago Machuca Vinzent Nikolaus Spetzler Erasmus Cudjoe Michael Hsin Marcelo Cypel Markus Selzner Mingyao Liu Shaf Keshavjee Janusz Pawliszyn 《Analytica chimica acta》2013
Metabolomics and biomarkers discovery are an integral part of bioanalysis. However, untargeted tissue analysis remains as the bottleneck of such studies due to the invasiveness of sample collection, as well as the laborious and time-consuming sample preparation protocols. In the current study, technology integrating in vivo sampling, sample preparation and global extraction of metabolites – solid phase microextraction was presented and evaluated during liver and lung transplantation in pig model. Sampling approaches, including selection of the probe, transportation, storage conditions and analyte coverage were discussed. The applicability of the method for metabolomics studies was demonstrated during lung transplantation experiments. 相似文献