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31.
Mass Spectrometric Investigations of the Gaseous Phase above As2O5 The gaseous phase above solid As2O5 has been investigated in the temperature range between 862 and 939 K by mass spectrometric methods. The presence of gaseous As4Ox-molecules (6 ≤ × ≤ 10) and O2 was proved. Using the partial pressures, heats of formation (ΔfH°(900), kJ · mol?1; 2nd law calculations) were calculated (As4O7,g: -1209,5; As4O8,g: -1361,9; As4O9,g: -1495,4; As4O10,g: -1618,8). The enthalpy of formation of solid As2O5 was determined to be ΔfH°(298) = ?1007,9 kJ · mol?1. The thermochemical data of the As4Ox-molecules are discussed in context with possibilities for the synthesis of solid As4O10. 相似文献
32.
Oxides of cesium play a key role in ameliorating the photoelectron emission of various opto-electronic devices. However, due to their extreme reactivity, their electronic and optical properties have hardly been touched upon. With the objective of better understanding the electronic and optical properties of Cs2O in relationship to its structure, an experimental and theoretical study of this compound was undertaken. First-principles density functional theory calculations were performed. The preferred structural motif for this compound was found to be anti-CdCl2. Here three Cs-O-Cs molecular layers are stacked together through relatively weak van-der-Waals forces. The energy bands were also calculated. The lowest transition at 1.45 eV, was found to be between the K point in the valence band to the Γ point in the conduction band. A direct transition at 2 eV was found in the center (Γ) of the Brillouin zone. X-ray powder diffraction, transmission electron microscopy and selected area electron diffraction were used to analyze the synthesized material. These measurements showed good agreement with the calculated structure of this compound. Absorption measurements at 4.2 K indicated two optical transitions with somewhat higher energy (indirect one at 1.65 and a direct transition at 2.2 eV, respectively). Photoluminescence measurements also showed similar transitions, suggesting that the lower indirect transition is enhanced by three nearby minima at 1.5 eV in the Brillouin zone. 相似文献
33.
Anhydrous disodium phosphonate, Na2HPO3, was prepared by dehydration of its pentahydrate. The crystal structure of Na2HPO3 was solved from high resolution X‐ray powder diffraction data (P21/n; Z = 4; a = 9.6987(1), b = 6.9795(1), c = 5.0561(1) Å, β = 92.37(1)°; V = 341.97(1) Å3). The crystal structure consists of two types of sodium‐oxygen polyhedra, which are connected via common edges and vertices forming layers perpendicular to [100]. These Na(1)‐ and Na(2)‐layers are interlinked via common edges, forming in a 3D‐framework. The resulting topology is providing oxygen arrangements that please the coordinative requirement of phosphorus(III). 相似文献
34.
Contributions to the 121Sb-Mössbauer Effect. VI. 121Sb-Mössbauer Spectrum and Vibrational Spectrum of Sb2O5 The results of 121Sb-Mössbauer spectroscopy at 4.2 K on pure Sb2O5, obtained by hydrothermal synthesis, are reported. The vibrational spectrum (i.r., raman) is correlated with the expectations of factor group analysis. The findings are compared to measurements carried out on samples hitherto regarded as Sb2O5. 相似文献
35.
Dimethyl-diphenyl and dimethyl-dibenzyl-silane react in liqu. NH3 in the presence of KKH2 giving rise to the formation of H2N? Si(Me2)? NH? Si(Me3)? NHK (III); exclusively C6H5 and C6H5CH2 are split off and substituted by NH2. Reaction of the potassium compound III with the equivalent amount of NH4Cl brings about a mixture of octamethylcyclotetrasilazane and hexamethylcyclotrisilazane. 相似文献
36.
The novel ionic ozonide {[N(C4H9)4](O3)}4·4.75NH3 was synthesized by ion‐exchange reaction in liquid ammonia. The crystal structure was determined by single crystal diffraction at 100 K (monoclinic space group P21, a = 15.014(11) Å, b = 13.696(10) Å, c = 19.890(15) Å, β = 105.407(12)°, V = 3943(5) Å3, Z = 2). The structure consists of a packing of sandwich‐like dimeric ion pairs in which two ozonide anions are interspersed between two tetrabutylammonium cations. Ammonia molecules from the solvent are localized in cavities in the structure. They are involved in hydrogen bonding with the ozonide ions. The desolvated tetrabutylammonium ozonide forms stable solutions in dichloromethane which may open up novel possibilities of tapping into the synthetic potential of the ozonide ion. 相似文献
37.
Background
The completion of several genome-sequencing projects has increased our need to assign functions to newly identified genes. The presence of a specific protein domain has been used as the determinant for suggesting a function for these new genes. In the case of proteins that are predicted to interact with mRNA, most RNAs bound by these proteins are still unknown. In yeast, several protocols for the identification of protein-protein interactions in high-throughput analyses have been developed during the last years leading to an increased understanding of cellular proteomics. If any of these protocols or similar approaches shall be used for the identification of mRNA-protein complexes, the integrity of mRNA is a critical factor. 相似文献38.
McCarthy TJ Plog MA Floy SA Jansen JA Soukup JK Soukup GA 《Chemistry & biology》2005,12(11):1221-1226
Natural RNA catalysts (ribozymes) perform essential reactions in biological RNA processing and protein synthesis, whereby catalysis is intrinsic to RNA structure alone or in combination with metal ion cofactors. The recently discovered glmS ribozyme is unique in that it functions as a glucosamine-6-phosphate (GlcN6P)-dependent catalyst believed to enable "riboswitch" regulation of amino-sugar biosynthesis in certain prokaryotes. However, it is unclear whether GlcN6P functions as an effector or coenzyme to promote ribozyme self-cleavage. Herein, we demonstrate that ligand is absolutely requisite for glmS ribozyme self-cleavage activity. Furthermore, catalysis both requires and is dependent upon the acid dissociation constant (pKa) of the amine functionality of GlcN6P and related compounds. The data demonstrate that ligand is integral to catalysis, consistent with a coenzyme role for GlcN6P and illustrating an expanded capacity for biological RNA catalysis. 相似文献
39.
Li2H4I2O10, the First Tetrahydrogendimesoperiodate Li2H4I2O10 has been obtained as an intermediate during the dehydration of LiH4IO6 · H2O to LiIO4, for the first time. According to the results of an X-ray structure determination (monoclinic, P21/n, a = 533.98(4), b = 471.85(4), c = 1431.48(10) pm, β = 91.614(7)°, Z = 2, 726 diffractometer data, R = 0.056), Li2H4I2O10 contains the previously unknown tetrahydrogendimesoperiodate ion H4I2O102?, consisting of two edge-shared IO6 octahedra. They are connected with LiO6 octahedra via common edges and vertices. The crystals are non-merohedrally twinned along (100). 相似文献
40.