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111.
Acid strength distributions of Mo–Al–Si and Ni–Mo–Al oxide systems have been found by means of a relationship that gives pKa values from amounts of ammonia adsorption. Molybdenum is suggested to cause a homogenization in the acid strength distribution of alumina but a heterogenization in silicaalumina, whereas nickel is found to neutralize strong acid sites inherent to molybdenum.
Mo–Al–Si Ni–Mo–Al , . , , .相似文献
112.
Xue J Song L Khaja SD Locke RD West CM Laine RA Matta KL 《Rapid communications in mass spectrometry : RCM》2004,18(17):1947-1955
Fixed-energy sequential tandem mass spectrometry (MS(n)) capabilities offered by quadrupole ion trap instruments have been explored in a systematic study of six isomers of Gal-Fucalpha-OBenzyl disaccharides. Under collision-induced dissociation (CID), sodiated molecular species generated in the positive-ion electrospray ionization mode yield simple and predictable mass spectra. Information on interglycosidic linkages and configurations can be deduced from the relative intensities of the selected diagnostic fragments arising from the glycosidic bond cleavages and corroborated by the fragments arising from cross-ring cleavages. As the CID patterns are not dependent on the number of prior tandem mass spectrometric steps, structures can be unambiguously assigned by matching the spectra with a library. The rules governing the fragmentation behavior of this class of oligosaccharides were tested for a representative isomeric disaccharide, Glcbeta1,3Fucalpha-OAllyl. The findings establish a basis for using MS(n) with a quadrupole ion trap instrument to elucidate structures of hexose-fucose subunits from more complicated oligosaccharides. Energy-resolved mass spectra were also acquired by CID tandem triple-quadrupole mass spectrometry. The breakdown behavior of the molecular ions revealed patterns which could differentiate stereoisomers of Gal-Fuc disaccharides over a range of collision energy from 20 to 50 eV. 相似文献
113.
Anne M. Sauer Frank R. Fronczek Betty C. R. Zhu William E. Crowe Gregg Henderson Roger A. Laine 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):o254-o256
Nootkatone, or (4R,4aS,6R)‐4,4a,5,6,7,8‐hexahydro‐4,4a‐dimethyl‐6‐(1‐methylethenyl)naphthalen‐2(3H)‐one, C15H22O, a sesquiterpene with strong repellent properties against Formosan subterranean termites and other insects, has the valencene skeleton. The dibromo derivative (1S,3R,4S,4aS,6R,8aR)‐1,3‐dibromo‐6‐isopropyl‐4,4a‐dimethyl‐1,2,3,4,5,6,7,8‐octahydronaphthalen‐2‐one, C15H24Br2O, has two independent molecules in the asymmetric unit, which differ in the rotation of the isopropyl group with respect to the main skeleton. The C—Br distances are in the range 1.950 (4)–1.960 (4) Å. Both independent molecules form zigzag chains, with very short intermolecular carbonyl–carbonyl interactions, having the perpendicular motif and O⋯C distances of 2.886 (6) and 2.898 (6) Å. These chains are flanked by intermolecular Br⋯Br interactions of distances in the range 4.067 (1)–4.218 (1) Å. The absolute configuration of the dibromo derivative was determined, from which that of nootkatone was inferred. 相似文献
114.
Johanna Huttunen Mahmoud Agami Janne Tampio Ahmed B. Montaser Kristiina M. Huttunen 《Molecules (Basel, Switzerland)》2022,27(1)
l-Type amino acid transporter 1 (LAT1), expressed abundantly in the brain and placenta and overexpressed in several cancer cell types, has gained a lot of interest in drug research and development, as it can be utilized for brain-targeted drug delivery, as well as inhibiting the essential amino acid supply to cancer cells. The structure of LAT1 is today very well-known and the interactions of ligands at the binding site of LAT1 can be modeled and explained. However, less is known of LAT1′s life cycle within the cells. Moreover, the functionality of LAT1 can be measured by several different methods, which may vary between the laboratories and make the comparison of the results challenging. In the present study, the usefulness of indirect cis-inhibition methods and direct cellular uptake methods and their variations to interpret the interactions of LAT1-ligands were evaluated. Moreover, this study also highlights the importance of understanding the intracellular kinetics of LAT1-ligands, and how they can affect the regular function of LAT1 in critical tissues, such as the brain. Hence, it is discussed herein how the selected methodology influences the outcome and created knowledge of LAT1-utilizing compounds. 相似文献
115.
116.
We establish a sharp integrability condition on the partial derivatives of a Sobolev mapping to guarantee that sets of measure
zero get mapped to sets of measure zero. This condition is sharp also for continuity and differentiability almost everywhere.
Received: 6 January 1999 / Revised version: 5 May 1999 相似文献
117.
118.
Sellinger A Tamaki R Laine RM Ueno K Tanabe H Williams E Jabbour GE 《Chemical communications (Cambridge, England)》2005,(29):3700-3702
A new solution processable nanocomposite material has been prepared via the Heck coupling of octavinylsilsesquioxane with a selected bromoaromatic hole transport compound. Resultant electroluminescent devices show an 18% improvement in external quantum efficiencies over their small molecule analogues. 相似文献
119.
Whispering-gallery modes in silica microspheres can be accessed very efficiently with the recently introduced stripline pedestal antiresonant reflecting optical waveguide (SPARROW) structure. This integrated-optics coupling technique creates novel application opportunities for the high-Q spherical cavities. We report the demonstration of a narrow-band wavelength-drop configuration utilizing SPARROW waveguides and a silica microsphere. 相似文献
120.
Kenneth Laine Ketner 《Historia Mathematica》1982,9(3):326-332
Carolyn Eisele's unique, ongoing career as a scholar is sketched, and the importance of her contributions to Peirce Studies and other fields is emphasized. The essay concludes with a series of suggestions about how to interpret Peirce's works based on themes related to the pioneering efforts of Dr. Eisele. 相似文献