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991.
We consider the nonequilibrium evolution in the spin-1/2 XXZ Heisenberg chain for fixed magnetization after a local quantum quench. This model is equivalent to interacting spinless fermions. Initially an infinite magnetic field is applied to n consecutive sites and the ground state is calculated. At time t=0 the field is switched off and the time evolution of observables such as the z component of spin is computed using the time evolving block decimation algorithm. We find that the observables exhibit strong signatures of linearly propagating spinon and bound state excitations. These persist even when integrability-breaking perturbations are included. Since bound states ("strings") are notoriously difficult to observe using conventional probes such as inelastic neutron scattering, we conclude that local quantum quenches are an ideal setting for studying their properties. We comment on implications of our results for cold atom experiments. 相似文献
992.
993.
We study contact problems with contact models of normal compliance type, where the compliance function tends to infinity for a given finite interpenetration. Such models are physically more realistic than standard normal compliance models, where the interpenetration is not restricted, because the interpenetration is typically justified by deformations of microscopic asperities of the surface; therefore it should not exceed a certain value that corresponds to a complete flattening of the asperities. The model can be interpreted as intermediate between the usual normal compliance models and the unilateral contact condition of Signorini type. For the static problem without friction, we prove the existence and uniqueness of solutions and establish the equivalence to an optimization problem. For the static problem with Coulomb friction, we show the existence of a solution. The analysis is based on an approximation of the problems by standard normal compliance models, the derivation of regularity results for these auxiliary problems in Sobolev spaces of fractional order by a special translation technique, and suitable limit procedures. 相似文献
994.
Jana Rotková Lucie Korecká Miroslava Jandová Daniel Horák 《Journal of magnetism and magnetic materials》2009,321(10):1335-1340
Laccase catalyzing the oxidation of p-diphenols has been applied in many industrial and biotechnology areas. Immobilized form of laccase has overcome the problem with contamination of the final product. Nevertheless sensitive enzymes immobilized to the matrix can be inactivated by the environmental conditions. The aim of this research was to prepare carrier with improved activity and responsible stability even under extreme reaction conditions. Laccase immobilized through carbohydrate moieties on magnetic hydrazide bead cellulose with a final activity of 0.63 I.U./1 ml of settled carrier confirmed that carriers with oriented immobilized enzyme might be useful in routine biocatalytic applications. 相似文献
995.
Dalila Meziane Julie Hardouin Abdelhamid Elias Erwann Gunin Marc Lecouvey 《Heteroatom Chemistry》2009,20(6):369-377
Diethyl phosphonates and tetraethyl alkyldiphosphonates were efficiently and rapidly prepared via the Michaelis–Becker reaction, under microwave irradiation. These compounds were then hydrolyzed to phosphonic and diphosphonic acids or selectively monodealkylated to give monoesters of phosphonic acids and symmetrical diethyl esters of diphosphonic acids. These reactions were also achieved rapidly in satisfactory yields with microwave methodology. This methodology was applied with success to the functionalization of a polymer resin. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:369–377, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20561 相似文献
996.
Kah-Yoong Chan Elias Hashem Aad Gordijn Helmut Stiebig Dietmar Knipp 《Applied Physics A: Materials Science & Processing》2009,96(3):751-758
Hydrogenated microcrystalline silicon has recently emerged as a promising material system for large-area electronic applications
such as thin-film transistors and solar cells. In this paper, thin-film transistors based on microcrystalline silicon were
realized with charge carrier mobilities exceeding 40 cm2/Vs. The electrical characteristics of the microcrystalline silicon thin-film transistors are limited by the influence of
contact effects. The influence of the contact effects on the charge carrier mobility was investigated for transistors with
different dimensions of the drain and source contacts. The experimental results were compared to an electrical model which
describes the influence of the drain and source contact dimension on the transistor parameters. Furthermore, the Transmission
Line Method was applied to investigate the contact effects of the thin-film transistors with different drain and source contact
dimensions. Finally, optimized device geometries like the channel length of the transistor and dimension of the drain and
source contacts were derived for the microcrystalline transistors based on the electrical model. 相似文献
997.
998.
In this paper, we introduce the possibilistic mean value and variance of continuous distribution, rather than probability distributions. We propose a multi-objective Portfolio based model and added another entropy objective function to generate a well diversified asset portfolio within optimal asset allocation. For quantifying any potential return and risk, portfolio liquidity is taken into account and a multi-objective non-linear programming model for portfolio rebalancing with transaction cost is proposed. The models are illustrated with numerical examples. 相似文献
999.
Soumita Mukherjee Gouranga P. Jana Binay K. Ghorai 《Journal of organometallic chemistry》2009,694(25):4100-4106
The reaction of Fischer carbene complex with o-alkynylpyridine carbonyl derivatives has been investigated. This involves the generation of furo[3,4-c]pyridine as transient intermediates through the coupling of o-alkynylpyridine carbonyl derivatives with carbene complex and subsequent Diels–Alder trapping with suitable dienophiles resulted in the formation of isoquinoline derivatives and the entire sequence can be run in one pot. When an olefinic tether was present, intramolecular Diels–Alder cycloaddition occurred followed by ring opening to yield tricyclic alcohols. 相似文献
1000.
Md. Mijanuddin Atish Dipankar Jana Michael G.B. Drew Chang Seop Hong Basab Chattopadhyay Monika Mukherjee Mahasweta Nandi Asim Bhaumik Madeline Helliwell Golam Mostafa Mahammad Ali 《Polyhedron》2009
Two concomitant polymorphic coordination complexes (dark blue – I and black – II) with the formula (Cu2C44H60N4O4) have been synthesized and characterized crystallographically. Magnetic measurements show the presence of a strong antiferromagnetic interaction and the 2J value corresponds extremely well to the theoretically calculated one, indicating the fact that it follows nicely the magneto-structural relationship. Immobilization of the copper(II) complex 1 on a 2D-hexagonal mesoporous silica showed good catalytic efficiency in the liquid phase partial oxidation of olefins in the presence of TBHP as an oxidant. 相似文献