The modified BCR three-step sequential extraction procedure has been applied to two different samples of urban particulate
matters (PM). The distribution of selected trace elements As, Cd, Cr, Mn, Ni, Pb, Zn was investigated and, in a comparative
study, the presence of common organic air filters in extraction procedures was evaluated. Analytes in separate fractions were
determined by ICP-OES and GFAAS, respectively, depending on concentration levels. While, due to air filters, a significant
increase of some analytes mobility in individual fractions has been observed in case of the jet-milled PM (tunnel Letna),
but in case of the PKC sample such effect was not found. The analyte impurities built in some filters has been tested, and
the impact on the reliability of analyte results has been discussed. The arsenic species occurrence and their stability in
presence of air filters (size 47 mm) were investigated in both urban PM samples as well, using HPLC-ICP-MS technique. Water
soluble and by three-step BCR procedure extractable arsenic forms are shown in chromatograms 相似文献
This research proposes a differential evolution-based regression framework for forecasting one day ahead price of Bitcoin. The maximal overlap discrete wavelet transformation first decomposes the original series into granular linear and nonlinear components. We then fit polynomial regression with interaction (PRI) and support vector regression (SVR) on linear and nonlinear components and obtain component-wise projections. The sum of these projections constitutes the final forecast. For accurate predictions, the PRI coefficients and tuning of the hyperparameters of SVR must be precisely estimated. Differential evolution, a metaheuristic optimization technique, helps to achieve these goals. We compare the forecast accuracy of the proposed regression framework with six advanced predictive modeling algorithms- multilayer perceptron neural network, random forest, adaptive neural fuzzy inference system, standalone SVR, multiple adaptive regression spline, and least absolute shrinkage and selection operator. Finally, we perform the numerical experimentation based on—(1) the daily closing prices of Bitcoin for January 10, 2013, to February 23, 2019, and (2) randomly generated surrogate time series through Monte Carlo analysis. The forecast accuracy of the proposed framework is higher than the other predictive modeling algorithms.
A series of symmetrical diamido biaryls has been synthesized in good yield by direct homocoupling of iodoarylbenzamides by palladium-catalysis. No cross product has been isolated from the reaction mixture of two different iodoarylbenzamides under similar conditions. However, only in the case of 2-iodo-N-phenylbenzamide, the intramolecularly coupled product phenanthridone has been isolated as a minor product along with the major intermolecularly coupled product. Biphenyl chiral diamides have been synthesized by this coupling method. This coupling reaction also works well with the reductive dimerization of functionalized heterocyclic compounds. Thus 6,6′-dipivaloylamino-3,3′-bipyridine and 6,6′-dimethyl-2,2′-bipyridine have been efficiently synthesized. In two cases, the X-ray crystal structures have been solved to establish the structures of symmetrical and chiral diamido biaryls and their supramolecular networks. 相似文献
We have treated the Hulthén-modified separable potentials within the framework of the phase-function method and obtained a
closed form expression fors-wave scattering phase shift. Specializing to a rank one separable potential we have found out the limiting conditions in
which the Hulthén-modified phase shift goes over to its Coulomb counterpart. We demonstrate the usefulness of our approach
by means of a model calculation.
Based in part on a Ph.D. thesis to be submitted by one of the authors (AKJ) to Visva-Bharati University. 相似文献
[structure: see text] The interaction of a macrocycle containing three trans-(1R,2R)-diaminocyclohexane units connected by p-xylene spacers with the isomers 1,3,5-benzenetricarboxylic (1,3,5-BTC), 1,2,4-benzenetricarboxylic (1,2,4-BTC), and 1,2,3-benzenetricarboxylic (1,2,3-BTC) acids and their relevant anions is studied by means of potentiometric and NMR analysis. The interaction is highest for the isomer 1,3,5-BTC, which perfectly fits within the macrocyclic cavity of the host species. The studies have been extended to the triacid 1,3,5-benzenetriacetic observing in this case the effect of a size mismatch between host and guest species. 相似文献
In the setting of doubling metric measure spaces with a 1-Poincaré inequality, we show that sets of Orlicz Φ-capacity zero have generalized Hausdorff h-measure zero provided thatwhere Θ−1 is the inverse of the function Θ(t)=Φ(t)/t, and s is the “upper dimension” of the metric measure space. This condition is a generalization of a well known condition in Rn. For spaces satisfying the weaker q-Poincaré inequality, we obtain a similar but slightly more restrictive condition. Several examples are also provided. 相似文献
In this note we show that -admissible measures in one dimension (i.e. doubling measures admitting a -Poincaré inequality) are precisely the Muckenhoupt -weights.
Silver and gold nanorods with aspect ratios from 1 to 16 have been used as substrates for surface enhanced Raman spectroscopy (SERS) in colloidal solution. The nanorod aspect ratio is varied to give different degrees of overlap between the nanorod longitudinal plasmon band and excitation source in order to determine its effect on overall surface enhancement. Results suggest that enhancement factors are a factor of 10-10(2) greater for substrates that have plasmon band overlap with the excitation source than for substrates whose plasmon bands do not. 相似文献
A novel, simple, and inexpensive approach to sorptive extraction, which we call solvent in silicone tube extraction (SiSTEx), was applied to pesticide residue analysis and its effectiveness and efficiency were evaluated. In SiSTEx, which is a form of open tubular sorptive extraction, a piece of silicone tubing (4 cm long, 1.47 mm ID, 1.96 mm OD in this study) is attached to the cap of a 20 mL glass vial that contains the aqueous sample. The tubing is plugged at the end dangling in the sample solution, and MeCN (e.g., 40 microL) added by syringe to the inner tube volume through a septum in the cap. A stir-bar is used to mix the sample for a certain time (e.g., 60 min), which allows chemicals to partition into the tubing where they diffuse across the silicone and partition into the MeCN. The final MeCN extract is then analyzed for the concentrated analytes. In this study, the SiSTEx approach was evaluated for the analysis of organophosphorus (OP) and organochlorine (OC) pesticides in fruits and vegetables using GC/pulsed flame photometric (PFPD) and halogen specific (XSD) detectors for analysis. The produced samples were initially extracted by a rapid MeCN procedure, and 5 mL of the initial extract was diluted four-fold with water to undergo sorptive extraction for 60 min. The final extract was analyzed by GC/PFPD + XSD for 14 OP and 22 OC pesticides. This simple approach was able to detect 26 of the 36 pesticides at 10 ng/g or less original equivalent sample concentration with average reproducibility of 11% RSD. For those 26 pesticides, a 44-fold lower detection limit on average was achieved in matrix extracts using SiSTEx despite the four-fold dilution with water. 相似文献