全文获取类型
收费全文 | 10416篇 |
免费 | 426篇 |
国内免费 | 88篇 |
专业分类
化学 | 7162篇 |
晶体学 | 100篇 |
力学 | 269篇 |
综合类 | 1篇 |
数学 | 1746篇 |
物理学 | 1652篇 |
出版年
2023年 | 81篇 |
2022年 | 121篇 |
2021年 | 193篇 |
2020年 | 210篇 |
2019年 | 250篇 |
2018年 | 160篇 |
2017年 | 159篇 |
2016年 | 388篇 |
2015年 | 288篇 |
2014年 | 321篇 |
2013年 | 604篇 |
2012年 | 609篇 |
2011年 | 655篇 |
2010年 | 454篇 |
2009年 | 406篇 |
2008年 | 587篇 |
2007年 | 631篇 |
2006年 | 497篇 |
2005年 | 547篇 |
2004年 | 443篇 |
2003年 | 352篇 |
2002年 | 338篇 |
2001年 | 162篇 |
2000年 | 145篇 |
1999年 | 96篇 |
1998年 | 104篇 |
1997年 | 110篇 |
1996年 | 114篇 |
1995年 | 93篇 |
1994年 | 85篇 |
1993年 | 101篇 |
1992年 | 79篇 |
1991年 | 80篇 |
1990年 | 75篇 |
1989年 | 64篇 |
1988年 | 51篇 |
1987年 | 55篇 |
1986年 | 70篇 |
1985年 | 103篇 |
1984年 | 101篇 |
1983年 | 80篇 |
1982年 | 69篇 |
1981年 | 74篇 |
1980年 | 68篇 |
1979年 | 64篇 |
1978年 | 70篇 |
1977年 | 41篇 |
1976年 | 41篇 |
1975年 | 51篇 |
1974年 | 56篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
871.
872.
873.
874.
Kameník Jan Dragounová Kateřina Kučera Jan Bryknar Zdeněk Trepakov Vladimir A. Strunga Vladimír 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(2):1333-1338
Instrumental neutron activation analysis was used for determination of vanadium mass fraction in crystals of incipient ferroelectric strontium titanate and ferroelectric barium titanate. In order to improve vanadium limit of detection, discriminating gamma-ray spectrometry was used by inserting an absorption filter between the samples and an HPGe detector. The use of the absorption lead filter 6-mm thick yielded improvement of the vanadium limit of detection by a factor of two. The vanadium mass fraction determined in a quality control sample, which was NIST standard reference material SRM 1648 Urban Particulate Matter, was in close agreement with the certified value.
相似文献875.
The use of air as a lubricant in aerodynamic bearings is advantageous, particularly in the food industry. Aerodynamic bearings
with tilting pads have complicated stiffness and damping properties and need a very detailed theoretical and experimental
research. Response curves of rigid rotor supported on aerodynamic bearings are presented for a linear but evolutive mathematical
model. Due to non-monotone properties of stiffness and damping matrices at variable revolutions, a new resonance appears.
The mathematical model of rotor vibrations in the whole area of bearing clearance is also developed in the consideration of
strongly nonlinear properties of aerodynamic bearing. 相似文献
876.
Nearly all the available information on the transient flow behaviour of liquid crystalline polymers has been obtained on model systems, especially on solutions of polybenzylglutamate (PBG) and hydroxypropylcellulose (HPC). The assessment of rheological models has been based almost entirely on these model systems. It is not clear how much of the available theoretical and experimental knowledge can be applied to systems of industrial relevance, which have quite different molecular structures. Here, an industrial lyotropic system, poly(p-phenylenetherephthalamide) (PpPTA) in sulphuric acid (TWARON from AKZO), is investigated. Various techniques to study transient behaviour are used, these include measurements of transient shear and normal stresses after sudden changes in shear rate, dynamic moduli and stress relaxation after cessation of flow and elastic recoil. At all shear rates studied the PpPTA solution is shear thinning, and the first normal stress difference remains positive. For the stress transients a strain scaling applies reasonably well as it did in model systems. The moduli increase with time upon cessation of flow, indicating that the molecules become less oriented in the previous flow direction. This particular behaviour is similar to that of HPC. Transients also resemble more closely those of HPC rather than those of PBG. This latter difference might be attributed to the higher flexibility of HPC and PpPTA chains as compared with PBG molecules. 相似文献
877.
Xu F Zhang H Ilavsky J Stanciu L Ho D Justice MJ Petrache HI Xie J 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):19199-19208
The dispersion of Nafion ionomer particles and Pt/C catalyst aggregates in liquid media was studied using both ultra-small-angle X-ray scattering (USAXS) and cryogenic TEM. A systematic approach was taken to study first the dispersion of each component (i.e., ionomer particles and Pt/C aggregates), then the combination of the components, and last the catalyst ink. Multiple-level curve fitting was used to extract the particle size, size distribution, and geometry of the Pt/C aggregates and the Nafion particles in liquid media from the scattering data. The results suggest that the particle size, size distribution, and geometry are not uniform throughout the systems but rather vary significantly. It was found that the interaction of each component (i.e., the Nafion ionomer particles and the Pt/C aggregates) occurs in the dispersion. Cryogenic TEM was used to observe the size and geometry of the particles in liquid directly and to validate the scattering results. The TEM results showed excellent agreement. 相似文献
878.
JPC – Journal of Planar Chromatography – Modern TLC - The epimers of cefaclor have been separated, identified, and analyzed quantitatively by TLC. The stationary phase was silica gel 60... 相似文献
879.
Alexander M. Khenkin Dr. Irena Efremenko Dr. Lev Weiner Dr. Jan M. L. Martin Prof. Ronny Neumann Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(4):1356-1364
A polyoxometalate of the Keggin structure substituted with RuIII, 6Q5[RuIII(H2O)SiW11O39] in which 6Q=(C6H13)4N+, catalyzed the photoreduction of CO2 to CO with tertiary amines, preferentially Et3N, as reducing agents. A study of the coordination of CO2 to 6Q5[RuIII(H2O)SiW11O39] showed that 1) upon addition of CO2 the UV/Vis spectrum changed, 2) a rhombic signal was obtained in the EPR spectrum (gx=2.146, gy=2.100, and gz=1.935), and 3) the 13C NMR spectrum had a broadened peak of bound CO2 at 105.78 ppm (Δ1/2=122 Hz). It was concluded that CO2 coordinates to the RuIII active site in both the presence and absence of Et3N to yield 6Q5[RuIII(CO2)SiW11O39]. Electrochemical measurements showed the reduction of RuIII to RuII in 6Q5[RuIII(CO2)SiW11O39] at ?0.31 V versus SCE, but no such reduction was observed for 6Q5[RuIII(H2O)SiW11O39]. DFT‐calculated geometries optimized at the M06/PC1//PBE/AUG‐PC1//PBE/PC1‐DF level of theory showed that CO2 is preferably coordinated in a side‐on manner to RuIII in the polyoxometalate through formation of a Ru? O bond, further stabilized by the interaction of the electrophilic carbon atom of CO2 to an oxygen atom of the polyoxometalate. The end‐on CO2 bonding to RuIII is energetically less favorable but CO2 is considerably bent, thus favoring nucleophilic attack at the carbon atom and thereby stabilizing the carbon sp2 hybridization state. Formation of a O2C–NMe3 zwitterion, in turn, causes bending of CO2 and enhances the carbon sp2 hybridization. The synergetic effect of these two interactions stabilizes both Ru–O and C–N interactions and probably determines the promotional effect of an amine on the activation of CO2 by [RuIII(H2O)SiW11O39]5?. Electronic structure analysis showed that the polyoxometalate takes part in the activation of both CO2 and Et3N. A mechanistic pathway for photoreduction of CO2 is suggested based on the experimental and computed results. 相似文献
880.
In this paper, we report on ordered mesoporous NiFe(2)O(4) thin films synthesized via co-assembly of hydrated ferric nitrate and nickel chloride with an amphiphilic diblock copolymer, referred to as KLE. We establish that the NiFe(2)O(4) samples are highly crystalline after calcination at 600 °C, and that the conversion of the amorphous inorganic framework comes at little cost to the ordering of the high quality cubic network of pores averaging 16 nm in diameter. We further show that the synthesis method employed in this work can be readily extended to other ferrites, such as CoFe(2)O(4), CuFe(2)O(4), MgFe(2)O(4), and ZnFe(2)O(4), which could pave the way for innovative device design. While this article focuses on the self-assembly and characterization of these materials using various state-of-the-art techniques, including electron microscopy, grazing incidence small-angle X-ray scattering (GISAXS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), X-ray photoelectron spectroscopy (XPS), as well as UV-vis and Raman spectroscopy, we also examine the electrochemical properties and show the benefits of combining a continuous mesoporosity with nanocrystalline films. KLE-templated NiFe(2)O(4) electrodes exhibit reasonable levels of lithium ion storage at short charging times which stem from facile pseudocapacitance. 相似文献