频闪及Matlab技术验证机械能守恒实验装置

利用摄像头频闪技术及Matlab软件组装了一个利用单摆验证机械能守恒的实验装置,主要解决学生在缺乏打点计时器的情况下,利用简便设备进行探究的难题,并将验证推广到二维.利用数据采集量大的优点,解决了传统实验只能验证机械能相等而不能验证机械能守恒的问题.     

Spectroscopic investigations and luminescence spectra of Nd and Dy doped different phosphate glasses

Spectral properties of Nd³⁺ and Dy³⁺ ions in different phosphate glasses were studied and several spectroscopic parameters were reported. Covalency of rare-earth-oxygen bond was studied in these phosphate glass matrices with the variation of modifier in host glass matrix. Using Judd-Ofelt intensity parameters (Ω₂, Ω₄ and Ω₆), radiative transition probabilities (A) and radiative lifetimes (τ_R) of certain excited states of Nd³⁺ and Dy³⁺ ions are estimated in these glass matrices. From the magnitudes of branching ratios (β_R) and integrated absorption cross-sections (Σ), certain transitions of both the ions are identified for laser excitation. From the emission spectra, peak stimulated emission cross-sections (σ_P) are evaluated for the emission transitions observed in all these phosphate glass matrices for both Nd³⁺ and Dy³⁺ ions.     

Vibrational spectroscopy of bio-molecules: an algebraic approach

Porphyrins have received numerous considerable attentions during recent years because of their great biological importance. The most interesting areas of current research in molecular spectroscopy are the study of the vibrational ground and excited states of polyatomic molecules especially for the Metalloporphyrins. In this paper, we have calculated the fundamental and extrapolated vibrational energy levels of Magnesium, Nickel, Copper, Zinc, Metalloporphyrin molecules using U (2) algebraic model Hamiltonian. The results obtained by this method are in good agreement with the experimental data. This study gives a general approach for solving the vibrational spectra of Metalloporphyrin molecules.     

Design studies of a high-current radiofrequency quadrupole for accelerator-driven systems programme

A 3 MeV, 30 mA radiofrequency quadrupole (RFQ) accelerator has been designed for the low-energy high-intensity proton accelerator (LEHIPA) project at BARC, India. The beam and cavity dynamics studies were performed using the computer codes LIDOS, TOUTATIS, SUPERFISH and CST microwave studio. We have followed the conventional design technique with slight modifications and compared that with the equipartitioned (EP) type of design. The sensitivity of the RFQ to the variation of input beam Twiss-Courant parameters and emittance has also been studied. In this article we discuss both design strategies and the details of the 3D cavity simulation studies.     

Correlations of projectile-like fragments in heavy-ion reactions at Fermi energy

Correlations between pairs of projectile-like fragments, emitted by the system ¹⁶O$ + $¹⁹⁷Au at the laboratory bombarding energy of 515MeV, have been studied under two stipulated conditions: 1) at least one member of the pair is emitted at an angle less than the grazing angle for the system, 2) both the members of the pair are emitted at angles larger than the grazing angle. A surprisingly large difference, by more than an order of magnitude, is found between the correlations for the two cases. This observation could be explained on the basis of a simple semi-classical break-up model. Further analysis of the variation of the charge correlation function with the difference in the nuclear charges of the correlated pair showed trends which are consistent with an “inelastic break-up process”, in which the projectile breaks up at the radius of contact, in such a way that, one fragment (preferably the lighter) is emitted to one side within the grazing angle, while the other orbits around the target nucleus for a while and emerges on the other side, at a negative scattering angle, much like in a deep inelastic scattering.     

Variable temperature EPR spectra of Copper (II) ions in kainite crystals

X-band electron paramagnetic resonance (EPR) studies on divalent copper ions embedded in KMgClSO₄·3H₂O single crystals have been performed at low temperature (123 K). The angular variation of the EPR spectra reveals the presence of two Cu²⁺ sites, which have different orientations. The spin-Hamiltonian parameters of this six-coordinated cupric ion have been evaluated from the EPR spectra at 123 K. The forbidden lines due to Δm_I=±1 transitions are observed in between allowed transitions. The temperature variation EPR studies have also been performed both for a single crystal and a polycrystalline sample. The ground state wavefunction of Cu²⁺ ions has been estimated and is found to be an admixture of d_3z²−r² and d_x²−y². The temperature variation of the EPR spectra reveals that Cu²⁺ ions exhibit dynamic Jahn-Teller effect. From the polycrystalline EPR data, the temperature dependent magnetic susceptibilities are evaluated and discussed.     

Assignment of surface IR absorption spectra observed in the oxidation reactions: 2H + H2O/Si(1 0 0) and H2O + H/Si(1 0 0)

Infrared reflection absorption spectroscopy that used buried metal layer substrates (BML-IRRAS) and density functional cluster calculations were employed to investigate the water related oxidation reactions of 2H + H₂O/Si(1 0 0)-(2 × 1), 2D + H₂O/Si(1 0 0)-(2 × 1), and H₂O + H/Si(1 0 0)-(2 × 1). In addition to the oxygen inserted coupled monohydrides, which were previously reported in the former reaction system, we report several other oxidized Si hydride species in our BML-IRRAS experiments. Three new pairs of vibrational bands are identified between 900 and 1000 cm⁻¹. These vibrational frequencies were calculated using Si9 and Si10 cluster models that included all possible structures from zero to five oxygen insertions into the top layer silicon atoms using a B3LYP gradient corrected density functional method with a polarized 6-31G** basis set for all atoms. The three pairs of vibrational modes are assigned to the scissoring modes of adjacent and isolated SiH₂ with zero, one, and two oxygen atoms inserted into the Si back bonds. All the other newly observed vibrational peaks related to Si oxidation are also assigned in this study. The Si-O stretching bands observed in the reaction 2D + H₂O/Si(1 0 0)-(2 × 1) show an isotope effect, which suggests that in the system 2H + H₂O/Si(1 0 0)-(2 × 1) also, hydrogen atom tunneling plays an important role for the insertion of oxygen atoms into Si back bonds that form oxidized adjacent dihydrides.     

High pressure transport behaviour of AgI-Ag2O-MoO3 glasses and the cluster model

The effect of pressure on the conductivity of fast ion conducting AgI-Ag₂O-MoO₃ glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application of cluster model to the ionic glasses. Contribution No. 258 from the Solid State and Structural Chemistry Unit.     

Thermal neutron polarisation

The basic principle for the production of polarised thermal neutrons is discussed and the choice of various crystal monochromators surveyed. Brief mention of broad-spectrum polarisers is made. The application of polarised neutrons to the study of magnetisation density distributions in magnetic crystals, the dynamic concept of polarisation, principle and use of polarisation analysis, the neutron spin-echo technique are discussed.