Synthesis,Crystal Structure and Luminescent Properties of Some Zn(II) Schiff Base Complexes: Experimental and Computational Study

A series of Zn(II)-Schiff bases I, II and III complexes were synthesized by reaction of o-phenylenediamine with 3-methylsalicylaldehyde, 4-methylsalicylaldehyde and 5-methylsalicylaldehyde. These complexes were characterized using FT-IR, UV-Vis, Diffuse reflectance UV-Vis, elemental analysis and conductivity. Complex III was characterized by XRD single crystal, which crystallizes in the triclinic system, space group P-1, with lattice parameters a?=?9.5444(2) Å, b?=?11.9407(2) Å, c?=?21.1732(3) Å, V?=?2390.24(7) ų, D _c ?=?1.408 Mg m^?3, Z?=?4, F(000)?=?1050, GOF?=?0.981, R1?=?0.0502, wR2?=?0.1205. Luminescence property of these complexes was investigated in DMF solution and in the solid state. Computational study of the electronic properties of complex III showed good agreement with the experimental data.     

Statefinder diagnostic and stability of modified gravity consistent with holographic and agegraphic dark energy

Recently one of us derived the action of modified gravity consistent with the holographic and new-agegraphic dark energy. In this paper, we investigate the stability of the Lagrangians of the modified gravity as discussed in (Setare in Int J Mod Phys D 17:2219, 2008; Setare in Astrophys Space Sci 326:27, 2010). We also calculate the statefinder parameters which classify our dark energy model.     

Restoring New Agegraphic Dark Energy in RS II Braneworld

Motivated by recent works (Saridakis in Phys. Lett. B 660:138, 2008; Sheykhi in Int. J. Mod. Phys. D 19(3):305, 2010), we investigate the new agegraphic model of dark energy in the framework of RS II braneworld. We also include the case of variable gravitational constant G in our model. Moreover, we reconstruct the potential and the dynamics of the quintessence, tachyon, K-essence and dilaton scalar field models according to the evolutionary behavior of the new agegraphic dark energy model in RS II braneworld cosmology including varying G.     

A study of the effect of laser beam geometries on laser bending of sheet metal by buckling mechanism

Laser beam forming has emerged as a new and very promising technique to form sheet metal by thermal residual stresses. The objective of this work is to investigate numerically the effect of rectangular beam geometries, with different transverse width to length aspect ratio, on laser bending process of thin metal sheets, which is dominated by buckling mechanism. In this paper, a comprehensive thermal and structural finite element (FE) analysis is conducted to investigate the effect that these laser beam geometries have on the process and on the final product characteristics. To achieve this, temperature distributions, deformations, plastic strains, stresses, and residual stresses produced by different beam geometries are compared. The results suggest that beam geometries play an important role in the resulting temperature distributions on the workpiece. Longer beam dimensions in the scanning direction (in relation to its lateral dimension) produce higher temperatures due to longer beam–material interaction time. This affects the bending direction and the magnitude of the bending angles. Higher temperatures produce more plastic strains and hence higher deformation. This shows that the temperature-dependent yield stress plays a more dominant role in the deformation of the plate than the spread of the beam in the transverse direction. Also, longer beams have a tendency for the scanning line to curve away from its original position to form a concave shape. This is caused by buckling which develops tensile plastic strains along both ends of the scanning path. The buckling effect produces the opposite curve profile; convex along the tranverse direction and concave along the scanning path.     

Synthesis and characterization of Mg-doped ZnO hollow spheres

Mg-doped ZnO nanoparticles were synthesized by a simple chemical method at low temperature with Mg:Zn atomic ratio from 0 to 7%. The synthesis process is based on the hydrolysis of zinc acetate dihydrate and magnesium acetate tetrahydrate were heated under refluxing at 65 °C using methanol as a solvent. X-ray diffraction analysis reveals that the Mg-doped ZnO crystallizes in a wurtzite structure with crystal size of 5–12 nm. These nanocrystals self-aggregated themselves into hollow spheres of size of 800–1100 nm. High resolution transmission electron microscopy images show that each sphere is made up of numerous nanoparticles of average diameter 5–11 nm. The XRD patterns, SEM and TEM micrographs of doping of Mg in ZnO confirmed the formation of hollow spheres indicating that the Mg²⁺ is successfully substituted into the ZnO host structure of the Zn²⁺ site. Furthermore, the UV–Vis spectra and photoluminescence (PL) spectra of the ZnO nanoparticles were also investigated. The band gap of the nanoparticles can be tuned in the range of 3.36–3.55 eV by the use of the dopants.     

Nanotechnology in the public eye: the case of Iran,as a developing country

Using survey data, public awareness of and attitudes toward nanotechnology are examined in Iran (N = 759). Iran is a developing country with a national nanotechnology action plan for a ten year period starting from 2003 and has been active in the field of research and development of nanotechnology meanwhile. First, the results show that majority of people are still not familiar with nanotechnology and perceived risks posed by this technology are not considered to be a lot and most people feel its benefits outweigh the risks. The emotions toward this technology are of a hopeful and positive nature and this technology is looked upon favorably in Iran. In particular, our results reveals that although the level of trust is high specially in scientists to communicate the risks with the public, there are a great number who just have some trust not quite a lot of it. Knowing that it is a hard and time-consuming effort to manage a nation’s view on nanotechnology, extensive research as well as collaboration with other countries is needed to effectively communicate the risks in time.     

Dynamical effects of QCD in q2$ \bar{{q}}^{{2}}_{}$ systems

We study the coupling of a tetraquark system to an exchanged meson-meson channel, using a pure gluonic theory based four-quark potential matrix model which is known to fit well a large number of data points for lattice simulations of different geometries of a four-quark system. We find that if this minimal-area-based potential matrix replaces the earlier used simple Gaussian form for the gluon field overlap factor f in its off-diagonal terms, the resulting T -matrix and phase shifts develop an angle dependence whose partial-wave analysis reveals D wave and higher angular-momentum components in it. In addition to the obvious implications of this result for the meson-meson scattering, this new feature indicates the possibility of orbital excitations influencing properties of meson-meson molecules through a polarization potential. We have used a formalism of the resonating group method, treated kinetic energy and overlap matrices on model of the potential matrix, but decoupled the resulting complicated integral equations through the Born approximation. In this exploratory study we have used a quadratic confinement and not included the spin dependence; we also used the approximation of equal constituent quark masses.     

A Note on Classification of Cylindrically Symmetric Non-static Space–Times According to Their Teleparallel Killing Vector Fields in the Teleparallel Theory of Gravitation

In this paper, we explored the conservation laws of cylindrically symmetric non-static space–times by using direct integration technique. This classification also covers non-static plane symmetric space–times, static cylindrically symmetric space–times and plane symmetric static space–times. In this paper, we will only present the results of non-static cylindrically symmetric and non-static plane symmetric space–times. The results of static cylindrically symmetric space–times and plane static space–times can be found in Shabbir and Khan (Mod Phys Lett A 25:525, 2010). It turns out that the non-static cylindrically symmetric space–times admit four, five, or seven conservation laws. It is important to note that the above space–times admit at least one or at the most four extra conservation laws.     

Gas by-products of CF3I under AC partial discharge

This paper presents the decomposition by-products of trifluro-iodo-methane and their relative proportions in the gas phase under the occurrence of partial discharge. The experiment was performed in the presence of water vapor from 250 to 400 ppm under a non-uniform electric field configuration. The experimental results reveal that the by-products of C₂F₆, C₂F₄, C₂F₅I with the amount of 1300, 200, and 55 (CH₃I) ppm, respectively, were produced for a cumulative charge of 161 mC. Other by-products, such as C₃F₈, CHF₃, C₃F₆ CH₃I were obtained at less than 30 ppm C₂F₆ was the dominant gas by-product of trifluro-iodo-methane suffering partial discharge.