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961.
962.
Treatment of phenylenediamines with methyl trimethoxyacetate led to the formation of 3-methoxy-quinoxalin-2-ones with the assistance of lanthanide-based Lewis acids. 相似文献
963.
Motivated by a recent paper of Liu and Ma, we describe a number of general WP-Bailey chains. We show that many of the existing
WP-Bailey chains (or branches of the WP-Bailey tree), including chains found by Andrews, Warnaar and Liu and Ma, arise as
special cases of these general WP-Bailey chains. We exhibit three new branches of the WP-Bailey tree, branches which also
follow as special cases of these general WP-Bailey chains. Finally, we describe a number of new transformation formulae for
basic hypergeometric series which arise as consequences of these new WP-Bailey chains. 相似文献
964.
Debadi Chakraborty Mohit Bajaj Leslie Yeo James Friend Matteo Pasquali J. Ravi Prakash 《ournal of non Newtonian Fluid Mechanics》2010,165(19-20):1204-1218
We compute the flow of three viscoelastic fluids (Oldroyd-B, FENE-P, and Owens blood model) in a two-dimensional channel partly bounded by a tensioned membrane, a benchmark geometry for fluid–structure interactions. The predicted flow patterns are compared to those of a Newtonian liquid. We find that computations fail beyond a limiting Weissenberg number. Flow fields and membrane shape differ significantly because of the different degree of shear thinning and molecular extensibility underlying the three different microstructural models. 相似文献
965.
Igor V. Kuvychko James B. Whitaker Kristin J. Suhr Olga V. Boltalina 《Journal of fluorine chemistry》2011,132(10):679-685
The first systematic study of heterogeneous fullerene trifluoromethylation using an innovative gradient-temperature gas-solid reactor revealed a significant effect of CF3I pressure on the conversion of C60 and C70 into trifluoromethylated products and on the range of fullerene(CF3)n compositions that were obtained. The design of the reactor allowed us to lower the residence times of fullerene(CF3)n species in the hot zone which resulted in the significant differences in relative isomeric distributions as compared to the earlier methods. For the first time, gram quantities of trifluoromethylated fullerenes were prepared using the new reactor, and the selective synthesis of a single-isomer C60(CF3)2 was developed. The relative reactivity of C70 as a CF3 radical scavenger was found to be much lower than that of C60, especially at an early radical addition stage, which led to the cost-efficient synthesis of C60(CF3)2 from a fullerene extract. 相似文献
966.
967.
968.
Eric James Davis Brian H. Clowers William F. Siems Herbert H. Hill Jr. 《International Journal for Ion Mobility Spectrometry》2011,14(2-3):117-124
Scientific applications of Ion Mobility Spectrometry require the ability to easily compare data between different laboratories. Reduced mobility values attempt to provide this functionality, but no standard exists for the collection and manipulation of the raw data obtained during an IMS experiment. We have created a comprehensive software suite based on the LabVIEW programming language that can be used to collect and interpret IMS data. The software may be used to collect data from a stand-alone IMS cell, a voltage sweep IMS cell, or a coupled chromatography-IMS system, and this framework may be adapted to incorporate mass spectral data analysis as well. This software is provided under an open source license for the benefit of the IMS community. 相似文献
969.
970.
Michael J. James Prof. Peter O'Brien Prof. Richard J. K. Taylor Dr. William P. Unsworth 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(9):2856-2881
This Review provides an in‐depth account of the synthesis of spirocyclic indolenines. Over the last 77 years, a wide array of diverse synthetic methods has been developed in order to generate these synthetically useful and biologically important spirocyclic scaffolds. The main synthetic strategies discussed are grouped into three main categories, namely interrupted Fischer indolisations, dearomatisation reactions of indoles and condensation reactions. The historical background, common synthetic challenges, current state‐of‐the‐art and future perspectives of this field are examined. 相似文献