全文获取类型
收费全文 | 258篇 |
免费 | 8篇 |
国内免费 | 7篇 |
专业分类
化学 | 203篇 |
晶体学 | 2篇 |
力学 | 10篇 |
数学 | 31篇 |
物理学 | 27篇 |
出版年
2023年 | 1篇 |
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 7篇 |
2019年 | 9篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 11篇 |
2014年 | 9篇 |
2013年 | 23篇 |
2012年 | 16篇 |
2011年 | 24篇 |
2010年 | 14篇 |
2009年 | 10篇 |
2008年 | 14篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 10篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 9篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1994年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有273条查询结果,搜索用时 15 毫秒
241.
A simple, mild, and regioselective method for the nitration of some aromatic compounds using sodium nitrate in the presence of benzyltriphenylphosphonium peroxodisulfate in acetonitrile as solvent is reported. Mild reaction conditions and good to excellent yields of the products are the noteworthy advantages of the method. 相似文献
242.
Pyrroloquinoline quinone (PQQ) was covalently attached to a gold electrode surface via the self-assembled monolayers of aminoalkanethiols (NH2)(CH2)nSH) with different alkyl chain lengths (n=2, 6, 8, and 11). The voltammetric behaviors of PQQ-SAMs both at full and at partial monolayers were examined. It was found that the redox response of PQQ became more reversible with increasing dilution by alkanethiols owing to the less lateral interaction between PQQ heads. Voltammograms were transformed from quasi-reversibility to irreversibility as the alkyl chain spacer became longer. The electron tunneling barrier constant (beta) and distance dependence of the long range electron-transfer parameters have been studied in acidic solution using cyclic voltammetry. A logarithmic dependence of the heterogeneous electron-transfer rate constant on the alkyl chain length was found for full and partial PQQ monolayers. The beta value was close to 1.0 per CH2 unit regardless of dilution effect. 相似文献
243.
Abdol-Rahim Farahmand Seyed Reza Yousefi Neda Sheijooni Fumani Solmaz Mirza Mojtaba Shamsipur Jalal Hassan 《Mikrochimica acta》2009,166(1-2):89-94
A simple and sensitive method is presented for solid phase extraction (SPE) and preconcentration of trace quantities of beryllium using octadecyl silica gel modifed with aurin tricarboxylic acid (aluminon). Beryllium is then determined by flame atomic absorption spectroscopy. Parameters affecting SPE such as pH, sample solution and eluent flow rate, type, concentration and volume of eluent, interfering ions and breakthrough volume, were investigated. Under optimal conditions, the beryllium ions were retained on the sorbent at pH 6–6.7, while 3.0 mL of 0.05 mol L?1 HNO3 is sufficient to elute the ions. The limit of detection (LOD) based on 3σ was 0.8 µg L?1 for 250 mL sample solution and 5 mL 0.05 mol L?1 HNO3 as eluent. The LOD can reach 0.1 µg L?1 for 1 L sample solution and 3 mL of 0.05 mol L?1 HNO3. The accuracy and precision (RSD %) of the method is >90% and <10%, respectively. The method was applied to the determination of beryllium in aqueous samples. 相似文献
244.
A fast and effective sample cleanup procedure for the quantification of polycyclic aromatic hydrocarbons (PAHs) in fish samples is presented. The procedure involved extraction of fish samples using acetonitrile and cleanup by an automated gel-permeation chromatography (GPC) following liquid?Cliquid partition into n-hexane. The extracted samples were analyzed by gas chromatography-mass spectrometry (GC?CMS). Electron ionization was employed in a single analysis for the determination of PAHs in the selected ion monitoring mode. Three different solvents were studied for the extraction step: acetonitrile/n-hexane, methanol/n-hexane and acetone/n-hexane. The best solvent was found to be acetonitrile/n-hexane. The cleanup technique resulted in a good separation of analytes from co-extractive matrix compounds. 相似文献
245.
Marini RD Groom C Doucet FR Hawari J Bitar Y Holzgrabe U Gotti R Schappler J Rudaz S Veuthey JL Mol R Somsen GW de Jong GJ Ha PT Zhang J Van Schepdael A Hoogmartens J Briône W Ceccato A Boulanger B Mangelings D Vander Heyden Y Van Ael W Jimidar I Pedrini M Servais AC Fillet M Crommen J Rozet E Hubert P 《Electrophoresis》2006,27(12):2386-2399
246.
Deetlefs M Hussey CL Mohammed TJ Seddon KR van den Berg JA Zora JA 《Dalton transactions (Cambridge, England : 2003)》2006,(19):2334-2341
The electrochemistry of the salts, [emim]2[UBr6] and [emim]2[UO2Br4] ([emim] = 1-ethyl-3-methylimidazolium), has been investigated in both a basic and an acidic bromoaluminate(III) ionic liquid. In the basic ionic liquid, the hexabromo salt undergoes a one-electron reversible reduction process at a stationary glassy carbon disc electrode, while the tetrabromodioxo salt was reduced to a uranium(IV) species by an irreversible two-electron process with the simultaneous transfer of oxide to the ionic liquid. On the other hand, dissolution of either of the salts in an acidic bromoaluminate(III) ionic liquid resulted in the formation of the same electroactive species. The solid state structures of the uranium chloride salts, [emim]2[UCl6] and [emim]2[UO2Cl4], have previously been reported, but have now been re-evaluated using a new statistical model developed in our group, to determine the presence or absence of weak hydrogen bonding interactions in the crystalline state. 相似文献
247.
We study the problem of restricting Schrödinger maps onto Lagrangian submanifolds. The restriction is imposed by an infinite constraining potential. We show that, in the limit, solutions of the Schrödinger map equations converge to solutions of generalized wave map equations. This result is applied to the anti-ferromagnetic systems where we prove rigorously that the dynamics is governed by wave map equations into . 相似文献
248.
Zhang Z Xiang S Hong K Das MC Arman HD Garcia M Mondal JU Thomas KM Chen B 《Inorganic chemistry》2012,51(9):4947-4953
A three-dimensional triply interpenetrated mixed metal-organic framework, Zn(2)(BBA)(2)(CuPyen)·G(x) (M'MOF-20; BBA = biphenyl-4,4'-dicarboxylate; G = guest solvent molecules), of primitive cubic net was obtained through the solvothermal reaction of Zn(NO(3))(2), biphenyl-4,4'-dicarboxylic acid, and the salen precursor Cu(PyenH(2))(NO(3))(2) by a metallo-ligand approach. The triple framework interpenetration has stabilized the framework in which the activated M'MOF-20a displays type-I N(2) gas sorption behavior with a Langmuir surface area of 62 m(2) g(-1). The narrow pores of about 3.9 ? and the open metal sites on the pore surfaces within M'MOF-20a collaboratively induce its highly selective C(2)H(2)/CH(4) and CO(2)/CH(4) gas separation at ambient temperature. 相似文献
249.
Richard L. Jayaraj Rami Beiram Sheikh Azimullah Nagoor Meeran M. F. Shreesh K. Ojha Abdu Adem Fakhreya Yousuf Jalal 《Molecules (Basel, Switzerland)》2021,26(15)
Parkinson’s disease is characterized by the loss of dopaminergic neurons in substantia nigra pars compacta (SNpc) and the resultant loss of dopamine in the striatum. Various studies have shown that oxidative stress and neuroinflammation plays a major role in PD progression. In addition, the autophagy lysosome pathway (ALP) plays an important role in the degradation of aggregated proteins, abnormal cytoplasmic organelles and proteins for intracellular homeostasis. Dysfunction of ALP results in the accumulation of α-synuclein and the loss of dopaminergic neurons in PD. Thus, modulating ALP is becoming an appealing therapeutic intervention. In our current study, we wanted to evaluate the neuroprotective potency of noscapine in a rotenone-induced PD rat model. Rats were administered rotenone injections (2.5 mg/kg, i.p.,) daily followed by noscapine (10 mg/kg, i.p.,) for four weeks. Noscapine, an iso-qinulinin alkaloid found naturally in the Papaveraceae family, has traditionally been used in the treatment of cancer, stroke and fibrosis. However, the neuroprotective potency of noscapine has not been analyzed. Our study showed that administration of noscapine decreased the upregulation of pro-inflammatory factors, oxidative stress, and α-synuclein expression with a significant increase in antioxidant enzymes. In addition, noscapine prevented rotenone-induced activation of microglia and astrocytes. These neuroprotective mechanisms resulted in a decrease in dopaminergic neuron loss in SNpc and neuronal fibers in the striatum. Further, noscapine administration enhanced the mTOR-mediated p70S6K pathway as well as inhibited apoptosis. In addition to these mechanisms, noscapine prevented a rotenone-mediated increase in lysosomal degradation, resulting in a decrease in α-synuclein aggregation. However, further studies are needed to further develop noscapine as a potential therapeutic candidate for PD treatment. 相似文献
250.
Jalal Shatah 《Journal of Differential Equations》1982,46(3):409-425
We study the global existence and asymptotic behaviour of “small” solutions of a large class of nonlinear partial differential equations. If the nonlinear terms are of high degree the solutions will be asymptotic to solutions of the linear equation. 相似文献