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101.
Multiplicity distributions up to the Collider energies could be described by various two-parameter compounded distributions having in common Poisson distributed number of clusters. Among them the logarithmic distribution for hadronization via decaying clusters leads to energyindependent number of clusters above the ISR energies, replacing the previous KNO-scaling.Dedicated to the 30th anniversary of the Joint Institute for Nuclear Research. 相似文献
102.
M. Rotter B. Sedlák J. Englich P. Čížek M. Finger P. Malinský 《Czechoslovak Journal of Physics》1986,36(11):1331-1335
The results of NMR/ON measurements on56,57,60Co isotopes in iron are presented in the paper. To avoid the uncertainties caused by local demagnetizing field inhomogeneities the measurements on two cobalt isotopes in one sample have been carried out. The values of nuclear-factors ratios
57/
60=1·805(20),
60/
56 = 0·761(20),
56/
57 = 0·726(20) and hyperfme anomalies56
60 = –0·036(10),60
57 = 0·017(10) and57
56 = 0·018(10) have been calculated from the experimental results.Dedicated to the 30th anniversary of the Joint Institute for Nuclear Research. 相似文献
103.
104.
Peter Šemrl 《Aequationes Mathematicae》1986,31(1):184-190
LetX be a leftA-module, whereA is either a complex Banach *-algebra with an identity element or the field of quaternions. The main result of this note is that forQ, anA-quadratic functional defined onX, there exists a sesquilinear functionalB such thatB(x,x)=Q(x) holds for allxX. 相似文献
105.
106.
Bimetallic ruthenium-tin catalysts were prepared using the sol-gel method and the method of carrier impregnation. Two different
procedures were used for their reduction — reduction in hydrogen atmosphere under an increased temperature, and reduction
using an aqueous solution of sodium borohydride. Hydrogenation of 3-phenylpropenal (cinnamaldehyde) in tetrahydrofuran at
433 K and the total pressure 7 MPa was used as the model reaction for comparing the catalytic properties of the prepared catalysts.
It was demonstrated that a tin addition notably affected catalytic properties of ruthenium in the sense of a selectivity increment
related to the production of an unsaturated alcohol. 相似文献
107.
J. Mikuski J. Moravec E. Ochab V. Šára 《Journal of Radioanalytical and Nuclear Chemistry》1981,62(1-2):83-90
The structure of the complex Ag·TBDTPP (tetrabutyl S-dithiopyrophosphate) formed in HNO3 medium was studied by IR and NMR methods. The complex is involved in the isomerization of TBDTPP in the presence of Ag+ and NO
3
−
ions. In the IR spectra, we observe the disappearance of P−O−P band and the occurrence of new absorption bands associated
with P−S−P and P=O bonds. The silver ion is coordinated to the thiophosphoryl group of the isomer molecule. The influence
of HNO3 concentration on complex formation is discussed. 相似文献
108.
J. Brandštetr 《Journal of Thermal Analysis and Calorimetry》1981,21(2):357-365
A review of instruments for thermochemical (thermometric) solution analysis is given, including new types of isoperibol reaction of bomb calorimeters, the design of which can influence the future development of thermochemical measuring techniques. The new type of Dithermanal (Vaskut-EMG, Hungary, and Herrmann- Morris, France) controls the individual steps of the thermochemical analysis, adding memory and computing capabilities. Similar programming units with microprocessors for bomb and/or reaction calorimetry have been developed by Parr Comp. and Leco Comp. (USA). The latest modification of the Technicon flow analyzer permits on-line analysis of solid samples. For thermochemical titrations, the Sanda titrator (USA) and Vaskut automatic titrator (Hungary) are available. In the USA, the Tronac isothermal or isoperibol calorimeters are widely used. At the Technical University of Brno, ?SSR, smaller table instruments with a water-bath are applied for different modes of solution thermochemical analysis, and also for the reactions of solid samples in liquids. For the measurement of very small temperature differences, PTC thermistors are used. The possibilities of the future development of measuring techniques are outlined. 相似文献
109.
Rudovsky J Hermann P Botta M Aime S Lukes I 《Chemical communications (Cambridge, England)》2005,(18):2390-2392
A marked increase of relaxivity has been observed upon rigidifying the internal frame of Gd-containing PAMAM dendrimers: the effect has been attained by either protonation of the dendrimer or by forming supramolecular adducts with cationic polyaminoacids. 相似文献
110.
The development of piezoelectric immunosensors for human serum albumin (HSA) is reported. The piezoelectric crystals were modified either with monoclonal antibody AL-01 (direct assay) or with HSA (competitive assay). Measurements were carried out in the flow-through mode. Affinity interaction between albumin and the antibody was characterised. With immobilised antibody and HSA in solution, the kinetic association rate constant k(a) was 18 100 l mol(-1) s(-1) and the dissociation constant k(d) was 0.00369 s(-1). For the opposite arrangement (immobilised HSA), a slower dissociation was observed, k(d) was 0.00085 s(-1). A competitive assay for HSA was developed with working range of 1-5 mug ml(-1) and a total time for one analysis equal to 17 min. Samples of urine were analysed after tenfold dilution. The developed system was successfully evaluated on real samples from diabetic patients and the obtained results correlated well with the standard reflectometric assay of proteins in urine. 相似文献