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61.
F. Matloubi Moghaddam L. Hojabri S. Taheri P. Pirani 《Journal of the Iranian Chemical Society》2010,7(3):781-790
Spiro thio-oxindoles are prepared in situ by the reaction of the corresponding aldehydes and thio-oxindoles in a straightforward, environmentally friendly, highly efficient and simple procedure. The reaction took place in water with no catalyst added. This one-pot reaction afforded regio- and diastereoselective products in high yields (61–93%). 相似文献
62.
Mohammad Reza R. Moghaddam All Reza Salemkar Ahmad Gholami 《Southeast Asian Bulletin of Mathematics》2000,24(2):255-261
Let be a variety of groups defined by the set of laws V. In this paper we study the concept of -isologism of groups in terms of -extensions and their connections with the Baer-invariant of groups are also discussed.AMS Subject Classification (2000): primary 20F14, 20F19, secondary 20E10 相似文献
63.
Palladium(II) Immobilized Onto the Glucose Functionalized Magnetic Nanoparticle as a New and Efficient Catalyst for the One‐pot Synthesis of Benzoxazoles 下载免费PDF全文
Palladium(II) have been immobilized into the nano magnetic Fe3O4 which was functionalized with glucose in order to achieve a one‐pot synthesis of 2‐substituted benzoxazole derivatives with high yields in the diverse range of organic solvents. The nano catalyst is highly dispersive in polar solvents and can be easily recovered and reused for 6 runs without significant loss of its activity. Finally, the catalyst was fully characterized by FT‐IR, TGA, CHN, SEM, EDX and atomic absorption spectroscopy. 相似文献
64.
65.
A new isogeometrical procedure for optimization of material composition of functionally graded structures in thermo-mechanical processes is introduced. The proposed method employs a generalized form of the standard isogeometric analysis method, allowing for gradation of material properties through patches. The variations of material properties are captured in a fully isogeometric formulation using the same NURBS basis functions employed for construction of the geometry and approximation of the solution. Subsequently, the applicates of control points that define the surfaces of volume fractions of the constituents are considered as the design variables and obtained by solving the optimization problem using a mathematical programming algorithm. Some numerical examples under thermal and mechanical loadings are considered to demonstrate the performance and applicability of the proposed method. Comparison of the obtained results with those of the other existing approaches such as finite elements and meshfree methods verifies the presented results. It will be seen that the proposed procedure considerably removes the difficulties of the existing methods and provides a promising tool for material design of functionally graded structures. 相似文献
66.
A mathematical model is developed for analysis the dynamics of an intra-cavity laser spectroscopy and mode competition using the CO2 laser as the coherent source. The governing equations of system are derived and effect of the absorbing material on the laser modes, as a time-dependent term is considered. Thus, the application of the CO2 laser for intra-cavity laser spectroscopy with considering an inhomogeneous medium and effect of the absorbing material is investigated. 相似文献
67.
Moghaddam S Yang C Rekharsky M Ko YH Kim K Inoue Y Gilson MK 《Journal of the American Chemical Society》2011,133(10):3570-3581
A dicationic ferrocene derivative has previously been shown to bind cucurbit[7]uril (CB[7]) in water with ultrahigh affinity (ΔG(o) = -21 kcal/mol). Here, we describe new compounds that bind aqueous CB[7] equally well, validating our prior suggestion that they, too, would be ultrahigh affinity CB[7] guests. The present guests, which are based upon either a bicyclo[2.2.2]octane or adamantane core, have no metal atoms, so these results also confirm that the remarkably high affinities of the ferrocene-based guest need not be attributed to metal-specific interactions. Because we used the M2 method to compute the affinities of several of the new host-guest systems prior to synthesizing them, the present results also provide for the first blinded evaluation of this computational method. The blinded calculations agree reasonably well with experiment and successfully reproduce the observation that the new adamantane-based guests achieve extremely high affinities, despite the fact that they position a cationic substituent at only one electronegative portal of the CB[7] host. However, there are also significant deviations from experiment, and these lead to the correction of a procedural error and an instructive evaluation of the sensitivity of the calculations to physically reasonable variations in molecular energy parameters. The new experimental and computational results presented here bear on the physical mechanisms of molecular recognition, the accuracy of the M2 method, and the usefulness of host-guest systems as test-beds for computational methods. 相似文献
68.
Mojtaba Mirhosseini Moghaddam Dr. Mostafa Baghbanzadeh Dr. Amin Sadeghpour Prof. Dr. Otto Glatter Prof. Dr. C. Oliver Kappe 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(35):11629-11636
In recent years, continuous‐flow/microreactor processing for the preparation of colloidal nanocrystals has received considerable attention. The intrinsic advantages of microfluidic reactors have opened new opportunities for the size‐controlled synthesis of nanocrystals either in the laboratory or on a large scale. Herein, an experimentally simple protocol for the size‐tunable continuous‐flow synthesis of rather monodisperse CdSe quantum dots (QDs) is presented. CdSe QDs are manufactured by using cadmium oleate as cadmium source, selenium dioxide as selenium precursor, and 1‐octadecene as solvent. Exploiting selenium dioxide as selenium source and 1‐octadecene as solvent allows execution of the complete process in open air without any requirement for air‐free manipulations using a glove box or Schlenk line. Continuous‐flow processing is performed with a stainless steel coil of 1.0 mm inner diameter pumping the combined precursor solution through the reactor by applying a standard HPLC pump. The effect of different reaction parameters, such as temperature, residence time, and flow rate, on the properties of the resulting CdSe QDs was investigated. A temperature increase from 240 to 260 °C or an extension of the residence time from 2 to 20 min affords larger nanocrystals (range 3–6 nm) whereas the size distribution does not change significantly. Longer reaction times and higher temperatures result in QDs with lower quantum yields (range 11–28 %). The quality of the synthesized CdSe QDs was confirmed by UV/Vis and photoluminescence spectroscopy, small‐angle X‐ray scattering, and high‐resolution transmission electron microscopy. Finally, the potential of this protocol for large‐scale manufacturing was evaluated and by operating the continuous‐flow process for 87 min it was possible to produce 167 mg of CdSe QDs (with a mean diameter of 4 nm) with a quantum yield of 28 %. 相似文献
69.
Moghaddam M. Azadi Kolahan F. 《Journal of Applied Mechanics and Technical Physics》2021,62(6):991-1000
Journal of Applied Mechanics and Technical Physics - The effects of the most important process-adjusting variables (welding current and welding speed) and the percentage of the combination of... 相似文献
70.
Askari Azam Entezari Amir Arsalan Pordel Mehdi Beigoli Sima Nezafat Yazdi Zeinab Jahani Moghaddam Arya Chamani Jamshidkhan 《Journal of the Iranian Chemical Society》2020,17(1):135-149
Journal of the Iranian Chemical Society - Evaluating the binding interaction between biomacromolecules and various chemical compounds is one of the most biologically researched topics. The present... 相似文献