Spherical Kadomtsev-Petviashvili Solitons in a Suprathermal Complex Plasma

The nonlinear aspects of nonplanar dust acoustic (DA) solitary waves are investigated in an unmagnetized complex plasma comprising of cold dust grains, kappa-distributed ions as well as electrons. The nonplanar DA solitons are studied based on the reductive perturbation technique. It is shown that the evolution of DA solitons is governed by a spherical Kadomtsev-Petviashvili (sKP) equation and then the impact of suprathermality on the spatial structure as well as the nature of DA soliton is studied. It seems that the properties of DA solitons in nonplanar geometry are quite different from that of the planar solitons.     

Theoretical description of electron phonon Fock space for gapless and gapped nanowires

We study the effect of electron–phonon(e–ph) interaction on the elastic and inelastic electronic transport of a nanowire connected to two simple rigid leads within the tight-binding and harmonic approximations. The model is constructed using Green's function and multi-channel techniques, taking into account the local and nonlocal e–ph interactions. Then, we examine the model for the gapless(simple chain) and gapped(PA-like nanowire) systems. The results show that the tunneling conductance is improved by the e–ph interaction in both local and nonlocal regimes, while for the resonance conductance, the coherent part mainly decreases and the incoherent part increases. At the corresponding energies which depend on the phonon frequency, two dips in the elastic and two peaks in the inelastic conductance spectra appear. The reason is the absorption of the phonon by the electron in transition into inelastic channels.     

The complex networks approach for authorship attribution of books

Authorship analysis by means of textual features is an important task in linguistic studies. We employ complex networks theory to tackle this disputed problem. In this work, we focus on some measurable quantities of word co-occurrence network of each book for authorship characterization. Based on the network features, attribution probability is defined for authorship identification. Furthermore, two scaling exponents, q-parameter and α-exponent, are combined to classify personal writing style with acceptable high resolution power. The q-parameter, generally known as the nonextensivity measure, is calculated for degree distribution and the α-exponent comes from a power law relationship between number of links and number of nodes in the co-occurrence network constructed for different books written by each author. The applicability of the presented method is evaluated in an experiment with thirty six books of five Persian litterateurs. Our results show high accuracy rate in authorship attribution.     

Generalized vector variational-like inequalities and vector optimization

In this paper, we consider different kinds of generalized vector variational-like inequality problems and a vector optimization problem. We establish some relationships between the solutions of generalized Minty vector variational-like inequality problem and an efficient solution of a vector optimization problem. We define a perturbed generalized Stampacchia vector variational-like inequality problem and discuss its relation with generalized weak Minty vector variational-like inequality problem. We establish some existence results for solutions of our generalized vector variational-like inequality problems.     

CuI/Fe3O4 NPs@Biimidazole IL‐KCC‐1 as a leach proof nanocatalyst for the synthesis of imidazo[1,2‐a]pyridines in aqueous medium

In the present work, an innovative leach proof nanocatalyst based on dendritic fibrous nanosilica (DFNS) modified with ionic liquid loaded Fe₃O₄ NPs and CuI salts was designed and applied for the rapid synthesis of imidazo[1,2‐a]pyridines from the reaction of phenyl acetylene, 2‐aminopyridine, and aldehydes in aqueous medium. The structure of the synthesized nanocatalyst was studied by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Fourier transform infrared (FT‐IR), flame atomic absorption spectroscopy (FAAS), energy‐dispersive X‐ray (EDX), and X‐ray diffraction (XRD), vapor–liquid–solid (VLS), and adsorption/desorption analysis (Brunauer–Emmett–Teller [BET] equation) instrumental techniques. CuI/Fe₃O₄NPs@IL‐KCC‐1 with high surface area (225 m² g^?1) and porous structure not only exhibited excellent catalytic activity in aqueous media but also, with its good stability, simply recovered by an external magnet and recycled for eight cycles without significant loss in its intrinsic activity. Higher catalytic activity of CuI/Fe₃O₄NPs@IL‐KCC‐1 is due to exceptional dendritic fibrous structure of KCC‐1 and the ionic liquid groups that perform as strong anchors to the loaded magnetic nanoparticles (MNPs) and avoid leaching them from the pore of the nanocatalyst. Green reaction media, shorter reaction times, higher yields (71–97%), easy workup, and no need to use the chromatographic column are the advantages of the reported synthetic method.     

The influence of La2O3 and TiO2 on NiO/MgO/α-Al2O3

Summary The effect of La₂O₃ and TiO₂ on product selectivity, methane conversion and coke formation over NiO/MgO/ α -Al₂O₃ catalyst were studied in a simultaneous steam and CO₂ reforming of methane to syngas. La₂O₃ and TiO₂ were added to the catalyst via incipient wetness impregnation and bulk precipitation techniques and catalyst activity was tested in a fixed bed quartz reactor. Results reveal that although the addition of these oxides has no effect on the product selectivity and methane conversion, but can reduce coke formation on the surface of the catalysts as it can enhance the mobility of lattice oxygen anions. The results further show that the catalysts prepared by bulk precipitation technique decrease the coke formation more effectively.     

Separation of B6 vitamers with micellar liquid chromatography using UV and electrochemical detection

Separation of six vitamers of vitamin B6 was performed by RP-HPLC using micellar mobile phase, UV and electrochemical detection. Effect of temperature, type and amount of organic modifier in mobile phase on efficiency and asymmetry factor showed that, the appropriate conditions were temperature of 35 degrees C and 3.0-5.0% (v/v) 1-butanol in mobile phase. Variations of selectivity factor versus 1-butanol concentration, pH of mobile phase, and SDS concentration was investigated and the following optimized conditions were selected for the separation: 3.0% (v/v) 1-butanol, pH=5.5 and 65 mM SDS in mobile phase. Electrochemical behavior of vitamers in optimized mobile phase was investigated using cyclic voltammetry, and potential of +1.2 V versus Ag/AgCl(Sat.) was chose as working potential. Finally, separation of B6 vitamers using UV detection at 254 nm and electrochemical detection at +1.2 V was compared.     

Development of an optical chemical sensor based on 2-(5-bromo-2-pyridylazo)-5-(diethylamino)phenol in Nafion for determination of nickel ion

An optical chemical sensor based on immobilization of 2-(5-bromo-2-pyridylazo)-5-(diethylamino)phenol (Br-PADAP) in Nafion membrane is described. The membranes were cast onto glass substrates and were used for the determination of nickel in aqueous solutions by spectrophotometry. The sensor system is highly transparent, mechanically stable and showed no evidence of reagent leaching. The influence of several parameters such as pH, ligand concentration, and type and concentration of regenerating solution were optimized. The sensor system showed good sensitivity in the range 0.5-20 μg ml⁻¹ with a detection limit of 0.3 μg ml⁻¹ Ni(II). The sensor has been incorporated into a home-made flow-through cell for determination of nickel in flowing streams with improved sensitivity, precision and detection limit. The calibration curve in the flow system was linear in the range 0.1-16 μg ml⁻¹ with a detection limit of 0.07 μg ml⁻¹. The sensor is easily regenerated by dilute nitric acid solution. The proposed method was successfully applied to the determination of nickel content in vegetable oil and chocolate samples and the results were compared with those obtained using atomic absorption spectrometry.     

Green Oxidations. Manganese(II) Sulfate Aided Oxidations of Organic Compounds by Potassium Permanganate

Summary. The oxidation of arenes and sulfides by potassium permanganate was accomplished in good yields under solvent free and heterogeneous conditions when manganese(II) sulfate is used as a solid support. After extraction of the organic products, the inorganic products can be reoxidized to permanganate. This result is important because it provides an approach to oxidation reactions that is, in theory, infinitely sustainable.     

Thermodynamic Properties of Aqueous Glucose–Urea–Salt Systems

In this work, the thermodynamic behavior of aqueous solutions containing the solutes NaCl, glucose, and/or urea is investigated. These substances are vital components for living bodies and further they are main components of blood serum. Osmotic coefficients were determined by cryoscopic measurements in single-solute and multi-solute aqueous solutions containing salts (NaCl, KCl, CaCl₂), glucose, and/or urea. The results show that NaCl determines the osmotic coefficients in the urea/glucose/NaCl/water system. Investigation of the effect of different salts on osmotic coefficients revealed ion-specific effects. At physiologically important solute concentrations in typical blood serum solutions, the osmotic coefficients were found to be in the range of 0.90–0.93. In a second step, the state of water in different glucose/salt/water and urea/salt/water systems was investigated. Depending on the kind of salt, the chemical potential of water in urea/salt/water is either higher or lower than in glucose/salt/water systems at equal nonelectrolyte concentrations. This result was found to be independent of the salt molality. Finally, the investigated systems were modeled with the Pitzer model and the ePC-SAFT equation of state, which allowed predicting of the properties of these multi-solute aqueous solutions.