全文获取类型
收费全文 | 3487篇 |
免费 | 222篇 |
国内免费 | 55篇 |
专业分类
化学 | 2758篇 |
晶体学 | 28篇 |
力学 | 74篇 |
综合类 | 6篇 |
数学 | 294篇 |
物理学 | 604篇 |
出版年
2023年 | 10篇 |
2022年 | 46篇 |
2021年 | 84篇 |
2020年 | 59篇 |
2019年 | 94篇 |
2018年 | 65篇 |
2017年 | 60篇 |
2016年 | 149篇 |
2015年 | 126篇 |
2014年 | 175篇 |
2013年 | 278篇 |
2012年 | 295篇 |
2011年 | 317篇 |
2010年 | 197篇 |
2009年 | 158篇 |
2008年 | 211篇 |
2007年 | 207篇 |
2006年 | 198篇 |
2005年 | 174篇 |
2004年 | 153篇 |
2003年 | 137篇 |
2002年 | 164篇 |
2001年 | 58篇 |
2000年 | 45篇 |
1999年 | 35篇 |
1998年 | 19篇 |
1997年 | 23篇 |
1996年 | 21篇 |
1995年 | 17篇 |
1994年 | 18篇 |
1993年 | 13篇 |
1992年 | 6篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1980年 | 5篇 |
1977年 | 4篇 |
1975年 | 4篇 |
1973年 | 3篇 |
1927年 | 3篇 |
1914年 | 3篇 |
1913年 | 4篇 |
1909年 | 4篇 |
1908年 | 4篇 |
排序方式: 共有3764条查询结果,搜索用时 15 毫秒
51.
Depigmenting activity and low cytotoxicity of alkoxy benzoates or alkoxy cinnamte in cultured melanocytes 总被引:2,自引:0,他引:2
To obtain effective and safe topical depigmenting agents, we synthesized hydroxybenzoates, alkoxybenzoates, and 3,4,5-trimethoxycinnamate containing a thymol moiety and screened then for high-level inhibitory activity against melanin synthesis in cultured melanocytes. Eight compounds were tested for their depigmenting effect and cytotoxicity using a murine melanocyte cell line. We found that 3,4,5-trialkoxybenzoates and 3,4,5-trimethoxycinnamate, synthesized by conjugating 3,4,5-trialkoxybenzoic acids and 3,4,5-trimethoxycinnmic acid with thymol, showed a potent depigmenting effect and low cytotoxicity. Compound 4h, 5-methyl-2-(methylethyl)phenyl (2E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoate, showed the most potent depigmenting effect (IC50=10 microM) with low cytotoxicity (IC50=200 microM). 相似文献
52.
We consider quantum unbounded spin systems (lattice boson systems) in -dimensional lattice space Z. Under appropriate conditions on the interactions we prove that in a region of high temperatures the Gibbs state is unique, is translationally invariant, and has clustering properties. The main methods we use are the Wiener integral representation, the cluster expansions for zero boundary conditions and for general Gibbs state, and explicitly -dependent probability estimates. For one-dimensional systems we show the uniqueness of Gibbs states for any value of temperature by using the method of perturbed states. We also consider classical unbounded spin systems. We derive necessary estimates so that all of the results for the quantum systems hold for the classical systems by straightforward applications of the methods used in the quantum case. 相似文献
53.
Van Bang Le 《Periodica Mathematica Hungarica》1993,27(2):105-124
For a finite or infinite graphG, theGallai graph (G) ofG is defined as the graph whose vertex set is the edge setE(G) ofG; two distinct edges ofG are adjacent in (G) if they are incident but do not span a triangle inG. For any positive integert, thetth iterated Gallai graph
t
(G) ofG is defined by (
t–1(G)), where 0(G):=G. A graph is said to beGallai-mortal if some of its iterated Gallai graphs finally equals the empty graph. In this paper we characterize Gallai-mortal graphs in several ways. 相似文献
54.
LetA be a finite dimensional commutative semisimple algebra over a fieldk and letV be a finitely generatedA-module. We examine the action of the general linear group GL
A
(V) on the set of flags ofk-subspaces ofV. Also, let (V, B) be a finitely generated symplectic module overA. We also investigate the action of the symplectic group Sp
A
(V, B) on the set of flags ofB-isotropick-subspaces ofV, whereB=°B is thek-symplectic form induced by a nonzerok-linear map :A k. In both cases, the orbits are completely classified in terms of certain integer invariants provided that dim
k A=2.This work is partially supported by a KOSEF research grant. 相似文献
55.
56.
Yong‐Min Lee Yoon‐Bo Shim Seung Jae Lee Sung Kwon Kang Sung‐Nak Choi 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(12):o733-o734
The structure of the title compound, C15H27N2+·ClO4?, consists of a monoprotonated sparteinium cation and a perchlorate anion. The two tertiary N atoms of the cation, one perchlorate O atom and a H atom form a bifurcated hydrogen bond, the four hydrogen‐bonding atoms being nearly in the same plane. 相似文献
57.
58.
Lee JH Je J Schlautmana MA Carraway ER 《Chemical communications (Cambridge, England)》2003,(2):270-271
The maximum intensity, Imax, and time required to reach the maximum emission, taumax, for 1-aminopyrene monitored in 1,1'-oxalyldi-4-methylimidazole (OD4MI) chemiluminescence (CL) reactions are approximately 61 times higher and 16 times faster than their respective values for bis(2,4,6-trichlorophenyl)oxalate (TCPO) CL reactions in the presence of imidazole (ImH). 相似文献
59.
Sang Chul Shim Chil Hoon Doh Tae Jeong Kim Hak Ki Lee Ki Doo Kim 《Journal of heterocyclic chemistry》1988,25(5):1383-1385
Ethanolic tetracarbonylhydridoferrate combined with adipaldehyde is very efficient for the selective transformation of an amino group into perhydroazepine. A large variety of both aliphatic and aromatic amines react with adipaldehyde in the presence of tetracarbonylhydridoferrate at room temperature and carbon monoxide to give the corresponding N-alkyl- and N-arylperhydroazepines in good to excellent yields. 相似文献
60.
Jae Ha Kim Young Tae Jeong Seong Ihl Woo 《Journal of polymer science. Part A, Polymer chemistry》1994,32(15):2979-2987
Highly active catalysts for copolymerization have been prepared by the precipitation of MgCl2/ToCl4 complex with or without high surface area silica. Copolymerization of ethylene and 1-butene has been tested by using the prepared catalysts at various concentrations of 1-butene. The catalytic activities are 20–80 kg/g Ti h. The rate of copolymerization is strongly affected by the addition of 1-butene. The decay rate of copolymerization is first order with respect to time. Analyses of copolymers with solvent extraction, DSC, IR, XRD, and NMR were performed. Ethylene reactivity ratio (k11) for TiCl4/MgCl2/THF catalyst is calculated to be about 26 by NMR spectrum. © 1994 John Wiley & Sons, Inc. 相似文献