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151.
Christopher P. Walczak Matthew M. Yonkey Philip J. Squattrito Dillip K. Mohanty Kristin Kirschbaum 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(5):o248-o251
1,3‐Bis(ethylamino)‐2‐nitrobenzene, C10H15N3O2, (I), and 1,3‐bis(n‐octylamino)‐2‐nitrobenzene, C22H39N3O2, (II), are the first structurally characterized 1,3‐bis(n‐alkylamino)‐2‐nitrobenzenes. Both molecules are bisected though the nitro N atom and the 2‐C and 5‐C atoms of the ring by twofold rotation axes. Both display intramolecular N—H...O hydrogen bonds between the amine and nitro groups, but no intermolecular hydrogen bonding. The nearly planar molecules pack into flat layers ca 3.4 Å apart that interact by hydrophobic interactions involving the n‐alkyl groups rather than by π–π interactions between the rings. The intra‐ and intermolecular interactions in these molecules are of interest in understanding the physical properties of polymers made from them. Upon heating in the presence of anhydrous potassium carbonate in dimethylacetamide, (I) and (II) cyclize with formal loss of hydrogen peroxide to form substituted benzimidazoles. Thus, 4‐ethylamino‐2‐methyl‐1H‐benzimidazole, C10H13N3, (III), was obtained from (I) under these reaction conditions. Compound (III) contains two independent molecules with no imposed internal symmetry. The molecules are linked into chains via N—H...N hydrogen bonds involving the imidazole rings, while the ethylamino groups do not participate in any hydrogen bonding. This is the first reported structure of a benzimidazole derivative with 4‐amino and 2‐alkyl substituents. 相似文献
152.
Krzysztof Idzik Jadwiga Sołoducho Joanna Cabaj Mariusz Mosiądz Mieczysław Łapkowski Sylwia Golba 《Helvetica chimica acta》2008,91(4):618-627
The substituted monomers 4a , c , d, 5a , b, 6a, 7a , b , and 8a of novel poly(diphenylamines), possessing the respective photochromic groups, were synthesized by the Stille cross‐coupling methodology (Scheme). The hyperbranched structures were characterized by 1H‐ and 13C‐NMR spectroscopy. The obtained monomers show good stability in common organic solvents such as CHCl3, toluene, and CH2Cl2, and exhibit excellent thermal stability. Electrochemical results and theoretical calculations suggest that oxidation and reduction of the monomers start from the side of the amine function and the five‐membered heterocyclic ring moieties, respectively. 相似文献
153.
Gwenaël Joret Piotr Micek Kevin G. Milans William T. Trotter Bartosz Walczak Ruidong Wang 《Combinatorica》2016,36(4):431-450
Over the last 30 years, researchers have investigated connections between dimension for posets and planarity for graphs. Here we extend this line of research to the structural graph theory parameter tree-width by proving that the dimension of a finite poset is bounded in terms of its height and the tree-width of its cover graph. 相似文献
154.
Alan R. Katritzky Ashraf A.A. Abdel-Fattah Krzysztof R. Idzik Bahaa El-Dien M. El-Gendy Jadwiga Soloducho 《Tetrahedron》2007,63(28):6477-6484
Reactions of readily available and stable 1-(α-alkoxyalkyl)benzotriazoles type 9a,b and 10a-d with a variety of silyl enol ethers 11 or 1,3-dicarbonyl compounds 13 give the expected ketones 12a-l (60-92%), β-keto esters 14a,b (62-67%), and malonates 14c,d (79-88%) in which a tetrahydrofuran or tetrahydropyran moiety has been introduced at the α position. 1-(Benzotriazol-1-yl)alkyl esters 7 are converted by cyanide anion into cyanohydrin esters 15a-i (55-98%). 相似文献
155.
Robust partial least squares model for prediction of green tea antioxidant capacity from chromatograms 总被引:1,自引:0,他引:1
In this paper a robust version of the partial least squares model (partial robust M-regression, PRM) was built to predict the total antioxidant capacity of green tea extracts. In order to construct a calibration model, chromatograms obtained by a fast high-performance liquid chromatographic method on a monolithic silica column were related with the total antioxidant capacity of green tea extracts as determined by the Trolox antioxidant capacity method. Since natural samples are the subject of the study, some outlying samples are present in the data, as shown in an earlier work. Therefore, to construct reliable calibration models, they were detected and removed prior to modeling. With the applied robust partial least squares approach, where a weighting scheme is embedded to down-weight the negative influence of outliers upon the model it is possible to construct a robust calibration model, without prior identification of outlying objects. It was shown that a robust model, allowing satisfactory prediction for test samples, can be used in controlling green tea antioxidant capacity based on their chromatograms. The constructed robust partial least squares model was shown to have virtually the same fit and predictive power as the classical partial least squares model when outlying samples were removed from the data. 相似文献
156.
The pollution of arable lands and water with petroleum-derived products is still a valid problem, mainly due the extensive works aimed to improve their production technology to reduce fuel consumption and protect engines. An example of the upgraded fuels is the BP 98 unleaded petrol with Active technology. A pot experiment was carried out in which Eutric Cambisol soil was polluted with petrol to determine its effect on the microbiological and biochemical properties of this soil. Analyses were carried out to determine soil microbiome composition—with the incubation and metagenomic methods, the activity of seven enzymes, and cocksfoot effect on hydrocarbon degradation. The following indices were determined: colony development index (CD); ecophysiological diversity index (EP); index of cocksfoot effect on soil microorganisms and enzymes (IFG); index of petrol effect on soil microorganisms and enzymes (IFP); index of the resistance of microorganisms, enzymes, and cocksfoot to soil pollution with petrol (RS); Shannon–Weaver’s index of bacterial taxa diversity (H); and Shannon–Weaver’s index of hydrocarbon degradation (IDH). The soil pollution with petrol was found to increase population numbers of bacteria and fungi, and Protebacteria phylum abundance as well as to decrease the abundance of Actinobacteria and Acidobacteria phyla. The cultivation of cocksfoot on the petrol-polluted soil had an especially beneficial effect mainly on the bacteria belonging to the Ramlibacter, Pseudoxanthomonas, Mycoplana, and Sphingobium genera. The least susceptible to the soil pollution with petrol and cocksfoot cultivation were the bacteria of the following genera: Kaistobacter, Rhodoplanes, Bacillus, Streptomyces, Paenibacillus, Phenylobacterium, and Terracoccus. Cocksfoot proved effective in the phytoremediation of petrol-polluted soil, as it accelerated hydrocarbon degradation and increased the genetic diversity of bacteria. It additionally enhanced the activities of soil enzymes. 相似文献
157.
R. Misiak R. Walczak B. Wąs M. Bartyzel J. W. Mietelski A. Bilewicz 《Journal of Radioanalytical and Nuclear Chemistry》2017,313(2):429-434
The therapeutic radionuclide 47Sc was produced through the 48Ca(p,2n) channel on a proton beam accelerator. The obtained results show that the optimum proton energies are in the range of 24–17 MeV, giving the possibility to produce 47Sc radionuclide containing 7.4% of 48Sc. After activation, the powdery CaCO3 target material was dissolved in HCl and scandium isotopes were isolated from the targets. The performed separation experiments indicate that, due to the simplicity of the operations and the chemical purity of the obtained 47Sc the best separation process is when scandium radioisotopes are separated on the 0.2 µm filter. 相似文献
158.
Density functional theory has been applied to the investigation of the reductive cleavage mechanism of methylcobalamin (MeCbl). In the reductive cleavage of MeCbl, the Co-C bond is cleaved homolytically, and formation of the anion radical ([MeCbl]*-) reduces the dissociation energy by approximately 50%. Such dissociation energy lowering in [MeCbl]*- arises from the involvement of two electronic states: the initial state, which is formed upon electron addition, has dominant pi*corrin character, but when the Co-C bond is stretched the unpaired electron moves to the sigma*Co-C state, and the final cleavage involves the three-electron (sigma)2(sigma*)1 bond. The pi*corrin-sigma*Co-C states crossing does not take place at the equilibrium geometry of [MeCbl]*- but only when the Co-C bond is stretched to 2.3 A. In contrast to the neutral cofactor, the most energetically efficient cleavage of the Co-C bond is from the base-off form. The analysis of thermodynamic and kinetic data provides a rationale as to why Co-C cleavage in reduced form requires prior departure of the axial base. Finally, the possible connection of present work to B12 enzymatic catalysis and the involvement of anion-radical-like [MeCbl]*- species in relevant methyl transfer reactions is discussed. 相似文献
159.
The Thermal Instability of 2,4 and 2,6‐N‐Alkylamino‐disubstituted and 2‐N‐Alkylamino‐substituted Nitrobenzenes in Weakly Alkaline Solution: sec‐Amino Effect
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Christopher Walczak Thomas J. Payne Colin B. Wade Matthew Yonkey Melissa Scheid Alec Badour Dilip K. Mohanty 《Journal of heterocyclic chemistry》2015,52(3):681-687
We report herein the preparation of two families of secondary amines by the reactions of two equivalents of monoamines with either 2,4 or 2,6‐difluoronitrobenzenes in N,N‐dimethylacetamide in the presence of anhydrous potassium carbonate, as precursors of biologically important nitric oxide donating N‐nitrosamines. In both instances, these compounds could be prepared in quantitative yield when the reaction temperature was held below 130°C. Above this reaction temperature, an unexpected cyclization reaction between the nitro and newly formed adjacent secondary amine group leads to the formation of benzimidazole or quinoxaline rings in low yields. Reasonable reaction mechanisms for the cyclization reaction are proposed. 相似文献
160.
In this article several approaches for the exploratory analysis of two-dimensional chromatographic signals (fingerprints) are presented. Their usefulness is illustrated on experimental chromatographic data obtained from high performance liquid chromatography using the photodiode-array detector (HPLC-DAD). Among the methods discussed are principal component analysis (PCA), hierarchical clustering methods and several N-way techniques such as PARAFAC, PARAFAC2 and Tucker3. In addition to the N-way methods, other approaches that allow for comparing samples represented by two-dimensional fingerprints are also presented (the Rv coefficient, the STATIS approach and ‘fuzzy’ variants of the similarity matrix). Exploratory analysis of the HPLC-DAD data with peak shifts is also discussed. 相似文献