全文获取类型
收费全文 | 944篇 |
免费 | 29篇 |
专业分类
化学 | 745篇 |
晶体学 | 6篇 |
力学 | 11篇 |
数学 | 121篇 |
物理学 | 90篇 |
出版年
2023年 | 6篇 |
2022年 | 13篇 |
2021年 | 8篇 |
2020年 | 10篇 |
2019年 | 18篇 |
2018年 | 5篇 |
2017年 | 10篇 |
2016年 | 15篇 |
2015年 | 22篇 |
2014年 | 14篇 |
2013年 | 42篇 |
2012年 | 62篇 |
2011年 | 54篇 |
2010年 | 32篇 |
2009年 | 23篇 |
2008年 | 53篇 |
2007年 | 57篇 |
2006年 | 54篇 |
2005年 | 52篇 |
2004年 | 42篇 |
2003年 | 48篇 |
2002年 | 49篇 |
2001年 | 12篇 |
2000年 | 14篇 |
1999年 | 17篇 |
1998年 | 7篇 |
1997年 | 17篇 |
1996年 | 26篇 |
1995年 | 11篇 |
1994年 | 10篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1988年 | 6篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 14篇 |
1976年 | 15篇 |
1975年 | 11篇 |
1974年 | 9篇 |
1973年 | 11篇 |
1972年 | 4篇 |
1971年 | 3篇 |
排序方式: 共有973条查询结果,搜索用时 15 毫秒
51.
52.
Carole Diederichs David Taj Thimothe Lecomte Crisitiano Ciuti Philippe Roussignol Claude Delalande Aristide Lemaître Ludovic Largeau Olivia Mauguin Jacqueline Bloch Charles Leyder Alberto Bramati Elisabeth Giacobino Jrme Tignon 《Comptes Rendus Physique》2007,8(10):1198-1204
We report the realization of a monolithic vertical-cavity, surface emitting micro-optical parametric conversion nanostructure, triply resonant with the parametric frequencies, allowing parametric oscillation with ultra-low pump power threshold. The photonic phase-space naturally provides triple resonance for the parametric frequencies, together with built-in cavity phase-matching for the pump wave at normal incidence. Parametric oscillation is observed in both the strong and weak exciton–photon coupling regime, allowing a high operating temperature. Signal and idler beams can be collected at 0° or at finite angles. The OPO threshold is low enough to envisage the realization of an all-semiconductor electrically-pumped micro-parametric oscillator. To cite this article: C. Diederichs et al., C. R. Physique 8 (2007). 相似文献
53.
Julien Amalric Claude Poleunis Arnaud Delcorte Jacqueline Marchand-Brynaert 《Surface science》2012,606(13-14):1071-1077
Chalcogenide glasses are useful optic materials that find applications in infrared spectroscopy, sensors and thermal imaging. A route for direct surface modification of such glasses with organic layers has been investigated by static Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The GAS (germanium–arsenic–selenium) glasses are modified by deposition followed by UV-irradiation of disulfide- or/and silane-functionalized organic molecules. SIMS analysis shows the characteristic fragments of the grafted molecules and organic–inorganic fragments which prove unambiguously the binding mode to the surface: disulfides, after S–S cleavage, are linked to arsenic and selenium; triethoxysilanes bind exclusively to oxidized germanium. The successive grafting of disulfide and silane compounds on the same substrate (IG2 glass with 33% of Ge) affords a “mixed” organic layer on the glass surface. From water contact angle measurements and X-ray Photo-electron Spectroscopy (XPS), the coverage density is not significantly improved comparatively to the “non-mixed” layers. However, the grafting of both types of molecules allows to reach a more homogeneous coverage. 相似文献
54.
Dimitri D.J. Rousseaux Xavier Drooghaag Pierre Godard Jacqueline Marchand-Brynaert 《Polymer Degradation and Stability》2010,95(3):363-3521
Polypropylene ionic thermoplastic elastomers have been prepared by melt radical grafting of maleic anhydride onto polypropylene in the presence of N-bromosuccinimide followed by neutralization of the resulting elastomeric grafted polypropylene using sodium salts. Sodium hydroxide and sodium acetate were compared in aqueous solution, as anhydrous or hydrated powders. The neutralization reaction was followed by Fourier transform infrared spectroscopy, allowing the development of a method to determine the effective neutralization degree. Important physical changes were recorded upon neutralization. Especially thermal stability, shear storage modulus and complex viscosity in the flow region were largely increased as a function of the neutralization degree. 相似文献
55.
Ainara Imaz Jacqueline Forcada 《Journal of polymer science. Part A, Polymer chemistry》2008,46(7):2510-2524
Poly(N‐vinylcaprolactam) (PVCL) is well known for its thermoresponsive behavior in aqueous solutions. PVCL combines useful and important properties; it is biocompatible polymer with the phase transition in the region of physiological temperature (32–38 °C). This combination of properties allows consideration of PVCL as a material for design biomedical devices and use in drug delivery systems. In this work, PVCL based temperature‐sensitive crosslinked particles (microgels) were synthesized in a batch reactor to analyze the effect of the crosslinker, initiator, surfactant, temperature, and VCL concentration on polymerization process and final microgels characteristics. The mean particle diameters at different temperatures and the volume phase‐transition temperature of the final product were analyzed. To obtain information about the inner structure of microgel particles, semicontinuous polymerizations were carried out and the evolution of the hydrodynamic average particle diameters at different temperatures of the microgel synthesized was investigated. In the case of microgel particles obtained in a batch reactor the size and the swelling‐de‐swelling behavior as a function of the temperature of the medium can be tuned by modulating the reaction variables. When the microgel particles were synthesized in a semibatch reactor different swelling‐de‐swelling behaviors were observed depending on particles inner structure. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2510–2524, 2008 相似文献
56.
The dinitrotoluenes (DNT) are some widely used compounds despite the first general impression one might have. They are the intermediates of several economically important industrial reactions such as the continuous nitration process of trinitrotoluene (TNT).3,4 As we were interested in the spectral characteristics of the various isomers of DNT5, we realized that the 3,5 isomer was not u-sually obtained during the nitration process of toluene6, thus making its availability quite restricted. It appeared relevant to find a useful and practical way to synthesize that particular isomer as it could also lead to the formation of new polyurethanes7, many polymerization processes uses DNT (mainly the 2,4 isomer because of its availability and its low price). 相似文献
57.
Sbastien Gibanel Valrie Heroguez Jacqueline Forcada 《Journal of polymer science. Part A, Polymer chemistry》2002,40(16):2819-2827
New diblock macromonomers were used as reactive emulsifiers in the emulsion polymerization of styrene. The nature of the reactive group, the molecular weight, the length of the poly(ethylene oxide) (PEO) block, and the molecular structure of the macromonomer were systematically investigated during this process by analyzing the evolution of the conversion and particle diameters. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2819–2827, 2002 相似文献
58.
Jacqueline Jiménez Mildred López Vladimir Carranza Angel Mendoza Jenaro Varela Estibaliz Sansinenea Aurelio Ortiz 《Tetrahedron letters》2017,58(3):235-239
An alternative methodology for the synthesis of chiral 3-(p-tolyl) butanoic acids is presented. This was accomplished through the diastereoselective hydrogenation reaction of different chiral N-3-(p-tolyl) but-2-enamides, using Pd/C in EtOH, to produce the corresponding chiral N-3-(p-tolyl) butanamides with high chemical yields and moderate diastereomeric ratios. Removal of the chiral auxiliary from N-3-(p-tolyl) butanamides gave the respective enantiomerically pure acids. 相似文献
59.
Thomas L. Theis Bhavik R. Bakshi Delcie Durham Vasilis M. Fthenakis Timothy G. Gutowski Jacqueline A. Isaacs Thomas Seager Mark R. Wiesner 《固体物理学:研究快报》2011,5(9):312-317
While significant advances in our understanding of the behavior of engineered nanoparticles in the environment continue, there remains a need to engage the nanoparticle research community directly in the development and evaluation of environmentally benign nanoparticles to ensure that nanomaterial‐based industries emerge as tools for sustainability rather than environmental liabilities. Current research efforts aimed at understanding the environmental implications of nanotechnology emphasize existing groups of nanoparticles and products already in commercial distribution. While this is clearly necessary, this approach fails to identify and address the many tradeoffs associated with product performance and environmental quality. We believe this to be a critical gap in the ongoing exploration of nanostructured materials and their properties and applications. We posit that a number of issues are not being holistically addressed, including resource availability and allocation, manufacturing energy requirements and embodied energy, material efficiency, environmental properties of nanomaterials and nanoproducts, and waste generation. An interdisciplinary approach to research, based on the life cycle paradigm and devoted to the identification, investigation, synthesis, testing, and analysis of groups of new, more environmentally conscious nanoparticles is needed. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
60.
Carbon-13 NMR methods were used to monitor changes in the proportions of crystalline and non-crystalline cellulose, and the exposure of chains on crystallite surfaces, in samples of alkali-treated kraft pulp and regenerated cellulose. A large increase in the amount of disorderd cellulose, as a result of conversion to cellulose II, is the major effect of alkali treatment with kraft pulp. Removal of small crystallites is the major effect with regenerated cellulose. Samples were examined never-dried, or were vacuum-dried prior to remoistening for characterization. Changes in molecular ordering consistent with pore collapse and coalescence of crystallite surfaces accompanied the removal of water. 相似文献