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41.
The reaction between freshly precipitated silver oxide Ag2O and an aqueous solution of tetrabenzenecarboxylic acid H4L leads to the anhydrous Ag2H2L complex. It crystallizes in the space groupP21/c, witha=6.457(1),b=8.180(1),c=9.982(1) Å, β=97.83(1)°,V=522.3(1) Å3,Z=2,d=2.976 g cm?3. This structure is a three dimensional polymeric network polymer without any silver...silver interaction. The silver environment is a bipyramid trigonal polyhedron with three short bond distances in the equatorial plane (Ag?O=2.255(2), 2.295(2), and 2.499(2) Å) and two longer bond distances in axial positions (Ag?O=2.558(2) and 2.617(2) Å). Thus, the silver polyhedron involves five different ligands. It is noteworthy that the (H2L2)2? ligand is located around an inversion centre. 相似文献
42.
43.
Omid Jahanmahin Mohammad Mehdi Montazer Rahmati Toraj Mohammadi Jaber Babaee Arash Khosravi 《Chemical Papers》2016,70(7):913-925
In this study, a novel flat-type synergic-supported liquid membrane was evaluated with a mixture of N-methyl-N,N,N-trioctylammonium chloride (Aliquat 336) and tributyl phosphate (TBP) as the carrier and kerosene as the diluent to remove Cr(VI) from synthetic waste water. The main parameters involved in the process were identified and optimised. The parameters were divided into two groups, those that were independent and those having an interaction. The parameters of the carrier/kerosene volumetric proportion and stirring rate were optimised individually due to their nature. The optimal values of these parameters were 0.5 and 500 min?1, respectively, for a constant carrier/kerosene ratio and stirring rate in the designed experiments using the response surface method (RSM). The four parameters of TBP/Aliquat 336, chromium concentration in the feed phase, feed and product pH were optimised using RSM; it was observed that the TBP/Aliquat 336 ratio, feed pH, pH of the stripping phase and interaction of this parameter with feed concentration have the most important effects on the removal of Cr(VI). The optimal levels of these parameters were 0.61, 71.75 mg L?1, 3.5 and 12.66 for the ratio of TBP/Aliquat 336, feed chromium concentration, pH of the feed and pH of the product, respectively. An experimental removal rate of 94.63 % at the optimized levels was obtained. 相似文献
44.
Farough Nasiri Morteza Bidar Bahareh Atashkar 《Monatshefte für Chemie / Chemical Monthly》2009,140(4):463-466
Abstract The reaction between dibenzoylacetylene and enol systems, such as acetylaceton or cyclohexane-1,3-dione in the presence of
triphenylphosphine in THF/H2O, leads to 4-acetyl-3-benzoyl-1-phenyl-1,5-hexanedione and 2-hydroxy-3-(2-oxo-2-phenylethyl)-2-phenyl-3,5,6,7-tetrahydro-1-benzofuran-4(2H)-one. Subsequently, these compounds undergo cyclization and elemination reactions in acidic dichloromethane at room temperature
to produce known highly functionalized furan derivatives.
Graphical abstract
相似文献
45.
Jaber et al. [M.Y. Jaber, R.Y. Nuwayhid, M.A. Rosen, Price-driven economic order systems from a thermodynamic point of view, Int. J. Prod. Res. 42 (24) (2004) 5167–5184] suggested that it might be possible to improve production systems performance by applying the first and second laws of thermodynamics to reduce system entropy (or disorder). They then used these laws to modify the economic order quantity (EOQ) model to derive an equivalent entropic order quantity (EnOQ). The results suggested that larger quantities should be ordered than is suggested by the classical EOQ model. 相似文献
46.
Three-dimensional free vibration analysis of functionally graded piezoelectric (FGPM) annular plates resting on Pasternak foundations with different boundary conditions is presented. The material properties are assumed to have an exponent-law variation along the thickness. A semi-analytical approach which makes use of state-space method in thickness direction and one-dimensional differential quadrature method in radial direction is utilized to obtain the influences of the Winkler and shearing layer elastic coefficients of the foundations on the non-dimensional natural frequencies of functionally graded piezoelectric annular plates. The analytical solution in the thickness direction can be acquired using the state-space method and approximate solution in the radial direction can be obtained using the one-dimensional differential quadrature method. Numerical results are given to demonstrate the convergency and accuracy of the present method. The influences of the material property graded index, circumferential wave number and thickness of the annular plate on the dynamic behavior are also investigated. Since three-dimensional free vibration analysis of FGPM annular plates on elastic foundations has not been implemented before, the new results can be used as benchmark solutions for future researches. 相似文献
47.
We have previously reported that robust mesostructured films will grow at the surface of alkaline solutions containing cetyltrimethylammonium bromide (CTAB), polyethylenimine (PEI), and silica precursors. Here we have used time-resolved small-angle X-ray scattering to investigate the structural evolution of the micellar solution from which the films form, at several different CTAB-PEI concentrations. Simple models have been employed to quantify the size and shape of the micelles in the solution. There are no mesostructured particles occurring in the CTAB-PEI solution prior to silica addition; however, after the addition of silicate species the hydrolysis and condensation of these species causes the formation of mesophase particles in a very short time, much faster than ordering observed in the film at the interface. The mesophase within the CTAB-PEI-silica particles finally rearranges into a 2D hexagonal ordered structure. With the aid of the previous neutron reflectivity data on films formed at the air/water interface from similar solutions, a formation mechanism for CTAB-PEI-silica films at the air/water interface has been developed. We suggest that although the route of mesostructure evolution of the film is the same as that of the particles in the solution, the liquid crystalline phase at the interface is not directly formed by the particles that developed below the interface. 相似文献
48.
One-pot reaction between enaminocarbonyl compounds derived from six-membered 1,3-diketones and substituted benzylamines, and electron-deficient acetylenic esters in the presence of triphenylphosphine lead to alkyl 2-(1-benzyl-6,6-dimethyl-2,4-dioxo-2,3,4,5,6,7-hexahydro-1H-indol-3-yl)acetate derivatives in good yields. 相似文献
49.
Samarium diiodide catalyzes a one-pot procedure allowing to perform sequentially the Michael addition of a ketene silyl acetal on a cyclic ,β-unsaturated ketone, followed by the addition of a glyoxylic or aromatic imine. The presence of a coordinating group on the imine increases the rate of the reaction. 相似文献
50.
A magnetic heterogeneous nanocatalyst based on novel rhodium complex is designed. The transfer hydrogenation of ketones with 2‐propanol as hydrogen donor and the rhodium complex as nanocatalyst was achieved. High yields of ketones under mild conditions were obtained from easily available precursors. 相似文献