A Stable 2012.1 nm Single-Longitudinal-Mode Tm：YAG Ceramic Laser with Volume Bragg Grating and Fabry-Perot Etalon

We demonstrate a stable single longitudinal mode Tm：YAG ceramic laser operating at a single wavelength of 2012.1 nm. The single-longitudinal-mode Tin： YAO ceramic laser is obtained by employing volume Bragg grating as one cavity mirror and inserting a Fabry-Perot etalon into the laser cavity. A maximum single longitudinal mode output power of 165roW with a slope efficieney of 6.6% is achieved under the pump power of 5.02 W. The laser has a beam quality of M2 = 1.18 at the maximum single longitudinal mode output power.     

毛白杨环氧水解酶的异源表达及其在催化拆分手性环氧化物中的应用

对已公布的全基因组进行检索发现,杨树(Populus tomentosa)至少含有24个预测为可溶性环氧水解酶的基因.从中选取了7个可能的环氧水解酶基因进行克隆,通过扩增得到其中5个毛白杨(Populus tomentosa Carr)环氧水解酶基因.序列分析显示,它们与已克隆的巨大芽胞杆菌环氧水解酶的同源性仅为24％～26％.对该系列基因进行了在E.coli中的异源表达,并将得到的5个环氧水解酶(PTEH 1～5)用于缩水甘油苯基醚和对硝基苯乙烯氧化物的酶促水解反应.结果发现,其中3个重组酶具有显著的环氧水解酶活性.进一步研究表明,PTEH1和PTEH2对于缩水甘油苯基醚显示了一定的反常规的     

服役导线的力学性能退化研究

为更清楚地了解阳江35kV服役导线的运行状态,从分析导线断线原因出发,通过对老旧导线的单丝断裂强度、弹性模量、应力应变曲线、拉断力、抗拉强度等综合指标的测试与分析,研究服役导线的力学性能,由试验结果得出:35kV老旧导线钢芯的直径变化对于架空导线的外径变化有直接的影响,老旧导线的铝线直径变化较小,其外径增大1.67%~4.24%;钢单线的拉断应力仍能达到标准中规定值的106%,且伸长率也满足要求;部分铝线的抗拉强度低于95%;绞线拉断力仍能达到95%的计算拉断力。但是相同规格下的老旧导线的抗拉强度比新导线的抗拉强度低2%~18%。结果表明:阳江地区服役三十年以上的老旧导线在力学性能上仍能继续承载。     

钢纤维掺量对活性粉末混凝土力学性能的影响

通过实验研究了活性粉末混凝土的基本力学性能(抗压强度、劈拉强度和抗折强度),分析了钢纤维掺量对活性粉末混凝土力学性能的影响,拟合得到了抗折强度与劈拉强度之间的关系表达式。在实验分析的基础上,建立了不同钢纤维体积含量活性粉末混凝土受压应力-应变全曲线的数学表达式。研究结果表明：钢纤维体积含量在1.0%～3.5% 之间时,活性粉末混凝土的抗压强度、劈拉强度和抗折强度均随着钢纤维掺量的增加而增大;当钢纤维体积含量超过3.5% 后,活性粉末混凝土抗压强度下降,劈拉强度略有提高,而抗折强度仍有明显的提高。     

溶胶-凝胶法制备Al2O3粉体及其陶瓷的性能研究

以硝酸铝、柠檬酸为原料,采用溶胶-凝胶法制备Al2O3粉体.利用X射线衍射仪、扫描电子显微镜对Al2O3粉体的晶体结构、形貌及粒径进行表征,并研究以MgO-CuO-TiO2作为添加剂时,Al2O3陶瓷的烧结特性及介电性能.结果表明:干凝胶经1000℃煅烧2h后得到了分散性良好的Al2O3粉体,粒径大约为50～ 80 nm.随着MgO掺杂量的增加,Al2O3陶瓷的相对密度、介电常数以及Q·f值都呈先增大后减小的趋势;随着温度的升高,烧结体的相对密度不断增大.当烧结温度为1500℃,MgO含量为0.5wt;时,Al2O3陶瓷的综合性能较好:相对密度为91.52;,介电常数和Q·f值达到最大值分别为9.46,19862 GHz.     

CoⅡ(salen*)存在下的氯丁二烯自由基聚合

研究了N,N'-双(3,5-二叔丁基水杨醛)-1,2-环己二胺钴(Ⅱ)[Co^Ⅱ(salen*)]存在下氯丁二烯(CP)的自由基聚合, 考察了不同溶剂、 引发剂用量及配体对聚合反应的影响. 结果表明, 随着引发剂用量的增加, 聚合反应的诱导期缩短, 以[ABVN]₀/[ Co^Ⅱ(salen*)]₀=3/1配比投料, 聚合反应表现出较好的可控聚合特征. 在苯、 甲苯、 四氢呋喃(THF)和乙酸乙酯(EA) 4种溶剂中按照[CP]₀/[Co^Ⅱ(salen*)]₀/[ABVN]₀=400/1/3的配比投料, 在苯中的可控聚合程度最好: 在低转化率(40%以下)实测聚合物分子量(M_n,GPC)与理论值(M_n,th)吻合, 且分子量随转化率增加呈线性增长. 研究了THF、 三乙胺(NEt₃)、 吡啶(Py)及水等不同配体对聚合反应的影响, 发现在添加THF时, 低转化率(40%以下)下M_n,GPC与M_n,th相符, 分子量分布(PDI)相对较窄.     

Regioselective Synthesis of Functionalized Dihydroquinolines via Organocatalytic Allylic Alkylation

The regioselective allylic alkylation of 1,2-dihydroquinolines and Morita-Baylis-Hillman(MBH) adducts has been developed. By surveying various reaction parameters, we summarized the effects of temperatures, relative reactant doses, catalysts, solvents and N-protected groups on the regioselectivity of this transformation. This method provides a facile protocol for the preparation of allylic α-substituted dihydroquinolines.     

基于GIS的长三角城市群经济空间集聚特征研究

本文在界定长三角城市群空间范围的基础上,利用长三角城市群各城市2013年相关数据,应用GIS的空间聚类分析功能分别从全局聚类检验和局部聚类检验两个方面分析了长三角城市群的经济空间集聚特征。研究结果表明长三角城市群的经济产出和经济生产要素在全局上存在空间集聚现象,在局部上,GDP、人均GDP等经济产出在向上海市、苏州市等个别城市高-高集聚,而劳动、资本、技术、能源等经济生产要素也在向上海市、苏州市等个别城市高-高集聚。     

Optimal allocation of policy limits and deductibles under distortion risk measures

In the literature, orderings of optimal allocations of policy limits and deductibles were established by maximizing the expected utility of wealth of the policyholder. In this paper, by applying the bivariate characterizations of stochastic ordering relations, we reconsider the same model and derive some new refined results on orderings of optimal allocations of policy limits and deductibles with respect to the family of distortion risk measures from the viewpoint of the policyholder. Both loss severities and loss frequencies are considered. Special attention is given to the optimization criteria of the family of distortion risk measures with concave distortions and with only increasing distortions. Most of the results presented in this paper can be applied to some particular distortion risk measures. The results complement and extend the main results in Cheung [Cheung, K.C., 2007. Optimal allocation of policy limits and deductibles. Insurance: Mathematics and Economics 41, 291-382] and Hua and Cheung [Hua, L., Cheung, K.C., 2008a. Stochastic orders of scalar products with applications. Insurance: Mathematics and Economics 42, 865-872].