Q-switched Er:YAG lasers resonantly pumped by Erbium fiber laser

The study describes efficient, acousto-optic Q-switching of Er:YAG laser at the 1645 nm eye-safe wavelength. For longitudinal pumping at wavelength 1532 nm, linear-polarized 10 W Erbium fiber laser radiation was used. The investigated Er:YAG crystals were 25 and 40 mm long and their Erbium concentration was 0.20 and 0.25%, respectively. For giant pulse generation, a fused silica acousto-optic modulator was inserted inside the Er:YAG laser oscillator. For a maximum incident pump power of 7.95 W, pulse energy up to 4.1 mJ was generated with pulse duration 34 ns at 500-Hz repetition rate; the corresponding peak power was 119 kW.     

Preparation and characterization of transparent Nd:YAG ceramics

Transparent Nd:YAG ceramics were produced by solid.state reaction of high.purity (4N) nanometric oxides powders, i.e., Al₂O₃, Y₂O₃ and Nd₂O₃. After sintering, mean grain sizes of 2% Nd:YAG samples were about 20 μm and their transparency were a bit worse than that of 0.9% Nd:YAG single crystal. Two types of active elements: rods and slabs were fabricated and characterized in several diode pumping schemes. In end pumping configuration as a pump source 20.W fiber coupled laser diode operating in low duty cycle regime (1 ms pump duration/20 Hz) was deployed. In the best case, 3.7 W of output power for 18 W of absorbed pump power, M² < 1.4 were demonstrated for uncoated ceramics Nd:YAG rod of ϕ 4×3mm size in preliminary experiments. For the ceramics of two times lower Nd dopant level above 30% slope efficiency was achieved. In case of Nd:YAG ceramic slab side pumped by 600.W laser diode stack above 12 W was demonstrated with slope efficiency of 3.5%.     

High repetition rate, tunable, Q-switched diode pumped Tm:YLF laser

The aim of work was to characterize a simple oscillator consisted of Tm:YLF crystal end-pumped by a fiber coupled diode laser and active Q-switch with tunability option. About 7 W with near 35% slope efficiency was demonstrated in a free-running mode. The divergence angle was about 4.3 mrad and estimated parameter M² < 1.3. Continuous tuning by means of Lyot’s filter, consisted of 2 quartz plates in the range of 1879.0–1939.4 nm with less than 1-nm linewidth, was achieved. For the best case (10-ms pump pulse duration, 42-A pump current corresponding to 266 mJ of pump energy), the Q-switched energy was 10.5 mJ with pulse duration of 22 ns corresponding to near 0.5 MW peak power. The 2.5 W of average power with 12.6-kW peak power and 2000-Hz repetition rate was demonstrated for cw pumping regime.     

A combined forward—reverse library search system for the identification of low-resolution mass spectra

A combined forward—reverse library search routine for low-resolution mass spectra is described. The routine requires binary-coded spectra. Masses and peak intensities are used for spectral comparison. On the basis of three possible search strategies, this routine is adaptable to analytical problems. The program was tested for 25 000 spectra from the ISAS, MSDC and EPA mass spectra libraries. The program is written completely in FORTRAN IV.     

Influence of Chelating Groups on the Luminescence Properties of Europium(III) and Terbium(III) chelates in the 2,2′-bipyridine series

Eight different 2,2′-bipyridine derivatives, i.e. 2, 5, 8, 10, 12, 13, 15 , and 19 (Schemes 1 and 2), were prepared to study the influence of the chelating groups on the luminescence properties of their Eu^III and Tb^III chelates. According to our luminescence results, 2,2′-(methylenenitrilo)bis(acetic acid) as well as (methylenenitrilo)bis-(methylphosphonic acid) in 6- and 6′-position of 2,2′-bipyridine is a suitable group when developing luminescent markers for bioaffinity assays based on time-resolved luminescence measurement.     

Equilibrium, FTIR, scanning electron microscopy and small wide angle X-ray scattering studies of chromates adsorption on modified bentonite

The study presents a discussion about the adsorption mechanism of chromate anions on bentonite modified by hexadecyltrimethylammonium bromide (HDTMA-Br). The formation of alkylammonium chromates: HDTMAHCrO₄, (HDTMA)₂Cr₂O₇ and to the lesser extent (HDTMA)₂CrO₄ at the water–bentonite interface is examined based on the Scanning Electron Microscopy and surface tension measurements. The histograms of HDTMA/Cr(VI) molar ratio on the bentonite surface, found from Scanning Electron Microscopy (SEM) measurements, show that for the majority of points of bentonite surface the value of this ratio is in 1–2 range. FTIR spectra of modified bentonite samples show the change from gauche to trans conformation in the surfactant arrangement in the clay interlayer accompanying its concentration increase.

In turn Small Wide Angle X-Ray Scattering (SWAXS) patterns evidently suggest incorporation of chromate anions into the interlamellar space of bentonite structure.     

High temperature polymers. III. Diphenyl sulfone-based polyamide-imides

High temperature thermoplastic polyamide-imides were prepared from a new series of aromatic diamines containing the diphenylsulfone unit and alternatively, oxydiphenyl and diphenylisopropylidene units. The polymers were prepared in their completely imidized form by using a facile in situ chemical imidization reaction which offers several advantages over the conventional thermal imidization process. The sulfone-based polyamide-imides exhibited an excellent combination of moldability, thermal stability, mechanical properties and solvent resistance. Analysis of the properties of these polymers in terms of structural variations permits a useful correlation of the effect of various structural units on performance. The polar diphenyl sulfone and amide-imide units increase the glass transition temperature and improve solvent resistance while the oxydiphenyl and diphenylisopropylidene units improve thermoplasticity. Sulfone ether diamine polyamide-imide (VI) offers the best combination of high temperature performance and moldability.     

Prediction of phenolic compounds in red wine fermentations by visible and near infrared spectroscopy

Near infrared (NIR) spectroscopy was used to simultaneously predict the concentrations of malvidin-3-glucoside (M3G), pigmented polymers (PP) and tannins (T) in red wine. A total of 495 samples from 32 commercial scale red wine fermentations over two vintages using two grape varieties (Cabernet Sauvignon and Shiraz), and also including as additional variables two types of fermenters, two different yeasts, and three fermentation temperatures were used. Samples were scanned in transmission mode (400-2500 nm) using a monochromator instrument (NIRSystems6500). Calibration equations were developed from high performance liquid chromatography (HPLC) and NIR data using partial least squares (PLS) regression with internal cross validation. Using PLS regression, very good calibration statistics (R_cal²>0.80) were obtained for the prediction of M3G, PP and T with standard deviation (S.D.)/standard error in cross validation (SECV) ratio (residual predictive deviation, RPD)) ranging from 1.8 to 5.8. It was concluded that near infrared spectroscopy could be used as rapid alternative method for the prediction of the concentration of phenolic compounds in red wine fermentations.     

Effect of water on the tautomeric equilibrium of uracil monoanions. A PCILO study

The PCILO method is used to calculate the stabilization energies of the anionic forms of uracil by water molecules forming the first hydration shell of the tautomers. The results show that the 1-HU^– tautomer is more stabilized by the solvent effect than the 3-HU^– tautomer by about 8 kcal/mole. The effect brings closer together the energies of the two tautomers which differ intrinsically by about 13 kcal/mole in favour of the 3-HU^– form. It operates in the direction inferred from experimental studies.This work was supported in part by R.C.P. 173 of the Centre National de la Recherche Scientifique of France and in part by the Polish Academy of Sciences within the project 09.3.1.