凝结水精处理阳树脂硫酸根溶出特性研究

电站给水系统中存在微量的SO42-就会对金属材料造成严重腐蚀。针对目前凝结水精处理系统投运后导致核电站蒸汽发生器或炉水中SO42-含量升高的问题,采用动态循环溶出和静态浸泡的方法对几种凝结水精处理常用阳树脂的SO42-溶出行为进行了研究。结果表明,不同树脂的SO42-溶出行为有较大差异,SO42-含量在短时间内随时间增长呈上升趋势,新树脂溶出SO42-的量比旧树脂大得多。通过对溶出液进行高温和氧化处理,发现溶出物中还含有一些有机磺酸盐,它们在高温或氧化条件下会分解产生SO42-和酸性物质。     

EPR Effect of Amphiphilic Copolymer Micelles Observed by Fluorescent Imaging

Enhanced permeation and retention(EPR) targeting effect of rhodamine B labeled PEG-b-P(LA-co-DHP) [PEG:poly(ethylene glycol);LA:L-lactide;DHP:2,2-dihydroxylmethyl-propylene carbonate] micelles(RhB-micelles) was observed in H22 liver cancer bearing mice.The RhB-micelles were prepared by conjugating rhodamine B with the DHP units of amphiphilic block copolymer PEG-b-P(LA-co-DHP) followed by subsequent self-assembling of the conjugate.The parent copolymer PEG-b-P(LA-co-DHP) was synthesized by ring-opening copo...     

新型5,5'-双[对-(4-氨基苯氧基)苯氧基]联嘧啶的合成

2-氯-5-溴嘧啶通过碘代,Ullmann,Williamson和还原反应,合成了新型5,5'-双[对-(4-氨基苯氧基)苯氧基]联嘧啶,其结构经1H NMR,IR和元素分析表征.     

Polymer/hemoglobin assemblies: biodegradable oxygen carriers for artificial red blood cells

In routine clinical procedures, blood transfusion is now suffering from the defects of the blood products, like cross-matching, short storage time and virus infection. Various blood substitutes have been designed by researchers through continual efforts. With recent progress in nanotechnology, new types of artificial red blood cells with cellular structure are available. This article aims to describe some artificial red blood cells which encapsulate or conjugate hemoglobin molecules through various approaches, especially the nanoscale self-assembly technique, to mitigate the adverse effects of free hemoglobin molecules. These types of artificial red blood cell systems, which make use of biodegradable polymers as matrix materials, show advantages over the traditional types.     

Fusiform micelles from nonlinear poly(ethylene glycol)/polylactide copolymers as biodegradable drug carriers

PEG-PLA copolymers with dumbbell- and Y-shaped structures are prepared. They can self-assemble from nanoparticles to micro-sized fusiform micellar particles in aqueous solution. In particular the micelles formed by the (PLA)2-PEG-(PLA)2 particles show a better drug loading capacity and encapsulation efficiency than those formed by linear MPEG-PLA. In vitro studies show that the particles formed by Y-shaped copolymers show a particularly quick drug release. The copolymers have good biocompatibility with low cytotoxicity. These unique self-assembled systems thus have many possible biomedical applications, such as a sustained delivery of high-dosed water insoluble drugs, quick effective drugs for trauma, controlled delivery of the oral-administration drugs, and so forth.     

一类具有非局部扩散的时滞Lotka-Volterra竞争模型的行波解

本文研究一类具有非局部扩散的时滞Lotka-Volterra竞争模型{(δ)/(δ)t u1(x,t)=d1 [(J1*u1)(x,t)-u1(x,t)]+r1u1(x,t)[1 - a1u1(x,t)- b1u1(x,t-Τ1)-c1u2(x,t-Τ2)],(δ)/(δ)tu2(x,t)=d2[(J2*u2)(x,t)-u2(x,t)]+r2u2(x,t)[1 - a2u2(x,t)- b2u2(x,t -Τ3)-c2u1(x,t-Τ4)]行波解的存在性问题.通过利用交叉迭代技巧,我们可以把行波解的存在性转化为寻找一对适当的上下解,这篇文章中的结果推广了已有的一些结果.     

第二类曲面积分的计算方法

针对第二类曲面积分的计算进行探讨,指出计算时可以把曲面方程代入到被积函数中,且可以利用轮换对称性及奇偶性来简化计算,并提出可以利用公式法、高斯公式、两类曲面积分之间的关系及合一投影法四种方法来计算第二类曲面积分.     

一类消失项带有时间导数的对流方程

本文在Duijn等的基础上研究了方程ht f(h)x=εhxx ε2τ1hxxt ε2τhxxx的行波解,其中f(h)∈C2(R)是满足所谓凹凸性的任意已知函数,得出了在不同的τ1,τ2条件下,该方程行波解的存在性条件和唯一性条件,并利用行波解得到上述方程的解,从而得到了对流方程的弱解,并分析了对流方程的多解性.     

金属冲击温度测量中金属/窗口界面表观光谱辐亮度的再研究

 在冲击压缩下，理想接触的金属/窗口界面温度历史是时间无关的，因而一般认为界面的表观光谱辐亮度也是时间无关的。研究表明：（1）在冲击压缩下，将伴随金属对光的吸收系数减小和光学厚度增大。因此，在考虑辐射输运效应后，理想接触的金属/窗口界面处的表现光谱辐亮度是时间相关的。非常明显的时间相关过程自冲击波到达界面后持续约10 ns。（2）若把存在空间温度梯度的金属界面辐射看作是透光厚度内平均温度的等效辐射效应，其结果与辐射输运效应的计算结果是很相近的。     

n型硅脉冲激光掺铟的物理过程与缺陷特性研究

用Nd-YAG脉冲激光对n型硅掺铟,形成外p⁺n结。利用二次离子质谱仪(SIMS)、卢瑟福背散射(RBS)等方法,研究了硅内铟的分布,并分析了用20ns脉冲激光硅掺铟的物理过程,发现当激光能量密度足够大时,在硅表面层存在硅-铟混合熔体和液态硅两部分。当激光能量密度较小时,硅表面层仅有液态硅层、用I-V,C-V和深能级瞬态谱(DLTS)等方法研究了p⁺n结的电学性质,发现在p⁺n结的n区存在两个缺陷。一个能通过快速热退火,在600℃,60s条件下消失,研究表明可能为空位与杂质的复合体。另一个通过快速热退火不能消失,可能与位错有关。 关键词：