Enhanced Efficiency of Polymer： Fullerene Bulk Heterojunction Solar Cells with the Insertion of Thin TiO2 Layer near the LiF/A1 Electrode

The insertion layer of TiO2 between polymer-fullerene blend and LiF/AI electrode is used to enhance the shortcircuit current Isc and fill factor （FF）. The solar cell based on the blend of poly[2-methoxy-5-（2＇-ethylhexyloxy）- 1,4-phenylenevinylene] （MEH-PPV） and C60 with the modifying layer of TiO2 （about 20nm） shows the open- circuit Voc of about 0.62 V, short circuit current Isc of about 2.35 mA/cm^2, filling factor FF of about 0.284, and the power conversion efficiency （PCE） of about 2.4% under monochromatic light （50Onto） photoexcitation of about 17mW/cm^2. Compared to ceils without the TiO2 layer, the power conversion efficiency increases by about 17.5%. Similar effect is also obtained in cells with the undoped MEH-PPV structure of ITO/PEDOT：PASS/MEH- PPV/（TiO2）LiF/AI. The improved solar cell performance can be attributed to enhanced carrier extraction efficiency at the active layer/electrode interfaces when TiO2 is inserted.     

Magnetic Properties and Nanostructures of FePtCu：C Thin Films with FePt Underlayers

Magnetic properties and nanostructures of FePtCu：C thin films with FePt underlayers （ULs） are studied. The effect of FePt ULs on the orlentation and magnetic properties of the thin films are investigated by adjusting FePt UL thicknesses from 2nm to 14nm. X-ray diffraction （XRD） scans reveal that the orientation of the films is dependent on FePt UL thickness. For a 5-nm FePtCu：C nanocomposite thin film with a 2-nm FePt UL, the coercivity is 6.S KOe, the correlation length is 59 nm, the desired face-centred-tetragonal （fct） ordered structure [Llo phase] is formed and the c axis normal to the film plane [（001） texture] is obtained. These results indicate that the beffer orientation and magnetic properties of the films can be tuned by decreasing the thockness of the FePt UL.     

Structure Stability of LaAlO3 Thin Films on Si Substrates

A series of amorphous and single-crystalline LaAlO3 （LAO） thin films are fabricated by laser molecular-beam epitaxy technique on Si substrates under various conditions of deposition. The structure stability of the LAO films annealed in high temperature and various ambients is studied by x-ray diffraction as well as high-resolution transmission electron microscopy. The results show that the epitaxial LAO films have very good stability, and the structures of amorphous LAO thin films depend strongly on the conditions of deposition and post-annealing. The results reveal that the formation of LAO composition during the deposition is very important for the structure stability of LAO thin films.     

新型Brφnsted酸性离子液体的合成与表征

制备了五种对水稳定性好、带-SO3H官能团的磺酸类Brφnsted酸离子液体,用核磁共振(NMR)、红外光谱(IR)、电喷雾质谱(ESI-MS)、热重分析(TG)等表征手段对制备的离子液体进行了表征.结果表明,制备的离子液体与预期设计的结构一致,离子液体纯度大于95%;热重分析发现离子液体具有高的热稳定性和较宽的液态范围,其分解温度均高于300 ℃;五种离子液体均存在四种离子存在形式,H 可以单独以离子形式存在,并不是通常所认为的仅有两种离子存在形式.另外,研究了离子液体在常用溶剂中的溶解性,发现制备的离子液体易溶于水、甲醇,不溶于乙醚、甲苯和乙酸乙酯.     

红光皂甙元及其两个甾体皂甙的NMR研究

从番麻(Agave americana L.)发酵的叶汁中分离得到红光皂甙元(hongguanggenin)、Cantalasaponin-1及一个新的甾体皂苷Agameroside-1. 运用2D NMR技术,包括DQF ¹H-¹H COS Y,HSQC,HMBC,HSQC-TOCSY,ROESY等技术,首次全归属了3个甾体化合物的氢和碳的化学位移,并总结了红光皂甙元的甙化位移效应,从而修正了文献中部分碳信号归属以及甙元的甙化位移效应.     

Ln7O6（BO3）（PO4）2：Eu（Ln=Al,Gd,Y）的UVU—UV激发和辐射发光

本文报道了Ln7O6(BO3)(PO4)2:Eu(Ln=La,Gd,Y)在UVU－UV区的激发光谱及Eu^3 在可见区的发射光谱,其激发光谱包括基质在真空紫外区的激发带和激活剂离子在紫外区的Eu^3 -O^2-电荷迁移带,随着La^3 ,Gd^3 ,Y^3 离子半径逐渐减小,Eu^3 -O^2-电荷迁移带的重心位置逐渐向高能量方向移动,Gd7O6(BO3)(PO4)2:Eu和Y7O6（BO3）（PO4）2：Eu在真空紫外区的吸收与Eu^3 -O^2-电荷迁移带位于紫外区的吸收的比值要高于在La7O6(BO3)(PO4)2:Eu中的这个比值,激发能可被基质吸收,传递给激活剂离子,得到Eu^3 的红光发射,在Gd7O6(BO3)(PO4)2:Eu中,^5D0→^7F1的发射强度较强,在Y7O6（BO3）（PO4）2：Eu中,^5D0→^7F2和^5D0→^7F3的跃迁较强。     

放射性核束物理与核天体物理

基于兰州重离子加速器国家实验室 (HIRFL )的中能放射性核束线 (RIBLL)及北京串列加速器国家实验室 (HI- 1 3 )的低能放射性核束线 (GIRAFFE) ,开展放射性核束物理和核天体物理研究 ,拟解决的关键科学问题是 :远离β稳定线核的结构与反应 ;超重新核素及近滴线核素的合成和性质研究 ,极端同位旋非对称核物质特性和关键的天体核反应研究 .研究内容分成 7个课题 :(1 )晕核研究 ;(2 )新核素合成及超重新核素研究 ;(3 )丰中子核结构和反应 ;(4)丰质子核结构和反应 ;(5 )高自旋的同位旋相关性 ;(6 )关键天体核反应 ;(7)系统的理论研究 .上述研究也将是2005年建成的国家大科学工程——兰州冷却贮存环的主要科学目标的研究基础 .简述了近期的主要工作进展. Based on the intermediate energy radioactive Ion Beam Line in Lanzhou (RIBLL) of Heavy Ion Research Facility in Lanzhou(HIRFL) and Low Energy Radioactive Ion Beam Line (GIRAFFE) of Beijing National Tandem Accelerator Lab (HI-13) the radioactive ion beam physics and nuclear astrophysics will be researched in detail. The key scientific problems which will be researched as high priority are: the nuclear structure and reaction for nucleus far from β-stability line; the syntheses...     

高能量密度激光器腔镜有限元分析

 通过对高能量密度激光器运行过程中腔镜存在的表面及背面吸收热量的有限元分析,得出腔镜表面在不同吸收热流密度和约束条件条件下热变形分布。指出提高腔镜反射率,改变腔镜的基底材料以及优化腔镜的约束条件是显著降低腔镜反射面变形的有效途径。     

分形粗糙面双站散射的快速前后向迭代法数值模拟

为模拟复杂分形表面特别是在低掠角入射条件下的双站散射,发展了一种结合前后向迭代方法(FBM)与谱加速算法(SAA)快速求解散射场的Monte Carlo数值方法,计算了在TE,TM锥形波入射在一维分形导体粗糙面的双站散射以及有规则异物存在时的双站散射,讨论了分形粗糙面双站散射的角度性分布与其分数维的关系. 关键词： GFBM/SAA 分形粗糙面 双站散射     

基于智能手机和Matlab的居家悬滴法表面张力测量实验

本文基于智能手机和Matlab软件设计了一种居家环境下可实现的悬滴法水滴表面张力测量实验.借助智能手机拍照功能获得水滴图像,利用Matlab进行边缘检测及计算,从而得出表面张力系数.对于不同清晰度的情况提出了对应的分析和处理方法,实验结果表明该方法稳定可靠.为后疫情时代开展居家大学物理实验教学提供了一个典型案例.