静园草坪灌溉系统的改进

在本文中 ,我将讨论一个从自己的实际观察中总结出来的数学模型——静园草坪的灌溉系统问题 .文中证明了灌溉系统的最大效率是 3 32π .这个结论还可以应用于其他的一些领域 .这实际上是一个决策问题 ,它归结为用小块的图形去覆盖平面区域 .我们需要找到一种最佳的覆盖方法 ,使得重叠的部分最少 .这样 ,我们就有两个问题要解决 ,首先是如何评价覆盖方法的优劣 ,其次是如何找到最佳的覆盖方法 .文中给出了合理的评价准则 ,并且提出了一些深入研究的方向和建议 .     

π-electron density dependence of third-order optical nonlinearities in poly(1,4-phenylene vinylene) derivatives

The third-order nonlinear optical properties of poly(1,4-phenylene vinylene) (PPV), poly(2-bromo-1,4-phenylene vinylene) (BrPPV) and poly(2-chloro-1,4-phenylene vinylene) (ClPPV) were studied by forward degenerate four-wave mixing (DFWM). They have large and ultrafast third-order optical nonlinear responses, which mainly arise from the distortion of the large π-conjugated electronic charge distribution in the backbone. It was found that there was a significant contribution to π-electron density and thus χ⁽³⁾ values from the substituents at the phenylene ring.     

Sequentially Estimating the Approximate Conditional Mean Using Extreme Learning Machines

This study examined the extreme learning machine (ELM) applied to the Wald test statistic for the model specification of the conditional mean, which we call the WELM testing procedure. The omnibus test statistics available in the literature weakly converge to a Gaussian stochastic process under the null that the model is correct, and this makes their application inconvenient. By contrast, the WELM testing procedure is straightforwardly applicable when detecting model misspecification. We applied the WELM testing procedure to the sequential testing procedure formed by a set of polynomial models and estimate an approximate conditional expectation. We then conducted extensive Monte Carlo experiments to evaluate the performance of the sequential WELM testing procedure and verify that it consistently estimates the most parsimonious conditional mean when the set of polynomial models contains a correctly specified model. Otherwise, it consistently rejects all the models in the set.     

中成药中微量砷的溶出伏安法分析

研究了利用阳极电位溶出法测定中成药-牛黄解毒丸中的微量砷的可行性. 实验采用金膜电极作工作电极的三电极系统, 在浓度为4.8 mol/L HCl和1.1 mol/L HNO3的混合底液中, 砷在峰电位(Ep)为 0.16 V (vs. SCE)左右有一灵敏的一阶导数峰, 在选定的实验条件下, 该峰峰高(Hp)与砷的质量浓度在0.5～5 μg/L之间有较好的线性关系, 相关系数r=0.9954, 检出限为0.17 μg/L, 精密度平均值为2.8%, 回收率在96.78%～103.3%之间, 常见干扰离子Pb2 、 Zn2 、 Cd2 、 Cu2 、 Hg2 对砷的测量无影响. 在线性范围内对牛黄解毒丸样品中的砷量进行了测定.     

E面和H面方向图等化的双模圆锥喇叭设计

 介绍用于Φ7.3 m Cassegrain天线的高功率馈源喇叭的设计。为使E面和H面方向图在照射区域内具有高的等化度,选择双模圆锥喇叭作为馈源的结构形式。由于高功率源采用BJ-32波导输出信号,故馈源系统中还应包含一个矩形到圆形的模式转换器,将TE10模转换为TE11模。设计了双模圆锥喇叭和模式转换器,并进行了功率容量估算。测试结果表明,所设计的馈源达到了设计要求,理论计算结果和实验测试数据吻合良好。     

液氮冲击压缩特性的理论计算

 用修正的WCA理论计算了液氮冲击压缩至70 GPa的一次冲击Hugoniot数据。计算中引入与体系比容有关的分子离解因子，计算结果表明，在33GPa以上液氮体系发生的相变为分子离解相变，该过程对体系热力学状态有较大影响，分子离解是对冲击能量的吸收过程，导致体系冲击压力和温度增长率下降。     

一种大动态范围的磁光电流传感器方案

提出了一种扩大磁光式电流传感器动态范围的方法。磁光式电流传感器是基于法拉第效应和安培环路定律实现电流测量的。由于法拉第旋转角随被测电流周期性增大，测量时只能利用正弦曲线单调变化的部分，因此限制了电流的测量范围。利用光纤维尔德常数随光波长变化这一特性，通过测量两种光波旋转的角度差，获得了大电流的测量值。在正常计量范围内利用单波长数据获得精度较高的计量值，达到扩大传感器测量范围的目的。分析表明，当两波长的维尔德常数相差20％时，电流测量范围可以扩大到单波长时的6倍。采用这种方法可望用一个传感器同时满足电力系统中的计量和保护两种用途。     

射频激励板条波导CO2激光器远场空间压窄单峰输出模式特性的实验研究

报道了射频激励扩散型冷却板条波导CO₂激光器远场呈空间窄单斑分布的模式特性及其模式演化过程的实验现象,实验研究了远场出现压窄单斑时的模式结构.通过实验研究发现实验中所获得的近场呈多点分布和远场呈空间窄单峰分布的板条波导激光器输出模式是一种新的单模频振荡模式. 关键词：     

Conjugated polymer covalently modified multiwalled carbon nanotubes for optical limiting

A new soluble multiwalled carbon nanotubes (MWNTs) covalently functionalized with conjugated polymer PCBF, in which the wt % of MWNTs is approximately calculated as 7.3%, and the average thickness of PCBF covalently grafted onto MWNTs is 10.4 nm, was synthesized by an amidation reaction. In contrast to the starting polymer PCBF‐NH₂, grafting of PCBF onto MWNTs led to a 0.3 eV red‐shift of the N1s XPS peak at 399.7 eV assigning to N in the unreacted NH₂moieties in the resulting copolymer structure and an appearance of new peak at 402 eV corresponding to N bound to the carbonyl C (i.e., NH? C?O). Unlike PCBF‐NH₂, which only displayed a weak optical limiting response at 532 nm, Z‐scan for MWNT‐PCBF exhibited a much broader reduction in transmission and a scattering accompanying on the focus of the lens at both 532 and 1064 nm, indicating a prominent broadband optical limiting response. The thermally induced nonlinear scattering is responsible for the optical limiting. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

离轴三反光学遥感器遮光罩的设计与试验验证

遮光罩是空间光学遥感器的重要组成部分,是抑制空间光学遥感器杂散光的首要措施。遮光罩削弱杂散光效果的好坏直接影响到光学遥感器光学系统的成像品质。本文设计了一种满足离轴三反空间光学遥感器要求的大尺寸碳纤维/环氧复合材料遮光罩,并结合有限元分析、杂散光分析及力学试验、光学系统传递函数检测手段来验证该遮光罩是否满足航天使用要求。结果显示,各视场光学系统传递函数检测结果基本一致,均在0.2以上。表明该大尺寸遮光罩具备良好的结构的稳定性、可靠性,能够满足空间应用要求。