Synthesis and Crystal Structure of a New μ-Oxamide Trimeric Hetero-tetranuclear Complex

A novel oxamide-bridged trimeric tetranuclear complex 1 incorporating a macro- cyclic oxamide of formula {[(CuL)3Mn](ClO4)2}3 (macrocyclic oxamide L = 2,3-dioxo-5,6,14,15- dibenzo-1,4,8,12-tetraazacyclopentadeca-7,12-diene) was prepared and structurally characterized. The compound [(CuL)3Mn](ClO4)2 crystallizes in the trigonal system, space group with a = 22.434(17), b = 22.434(17), c = 18.82(2) (A), α = β = 90, γ = 120o, V = 8203(13) (A)3, Z = 6, Dc = 1.751g/cm3, μ(MoKα) = 1.557, F(000) = 4392, the final R = 0.083 and wR = 0.1727 for 9604 obser- ved reflections with I > 2σ(I). The single-crystal X-ray analysis shows that 1 is a trimeric complex. There are three similar constitutes, dissimilar conformations and asymmetrically independent 'building-block' [(CuL)3Mn] in one crystal cell of the title complex 1.     

The N*(1710) contribution to the Θ+ production cross sections in p-p collisions

In this paper we derive the Θ production cross section in high energy proton-proton collisions in the relativistic framework through using effective hadronic couplings. Both the nucleon and N^*(1710) propagations are taken into account in the intermediate states. The one π and one ρ exchange mechanisms are considered and the commonly accepted coupling constants and form factors are used in the calculation. We find that ρ exchange is dominant in these processes and the N^*(1710) propagation in the intermediate state is important,which increases the Θ production cross section by a factor of a few tens at center of mass energy 4GeV.     

Assembly and Characterization of Rare-earth-containing Polyoxometalate [Eu （P2Mo17O61）2]^17- and Poly（allylamine hydrochloride） Multilayer Films

The ultrathin multilayer films of rare-earth-containing polyoxometalate cluster K17[Eu(P2Mo17O61)2](EuPMo) and poly(allylamine hydrochloride) (PAH) have been prepared by the Layer-by-Layer(LbL) selfassembly method. The photoluminescent behavior of the films investigated at room temperature shows the Eu^3 characteristic emission pattern of ^5Do→^7FJ(J=1—4). The occurrence of the photoluminescent activity confirms the potential of creating luminescent multilayer films with polyoxometalates (POMs).     

HDPE氧化交联与动态流变行为

研究了高密度聚乙烯(HDPE)熔体在200℃的动态流变行为,比较了空气、氮气及加入抗氧剂B215情况下体系动态粘弹行为的差异.研究表明,在空气环境中,HDPE在低频区域出现特征粘弹行为.随着测试前热处理时间的延长,动态储能模量(G')明显增加,在低频率(ω)区域lgG'～lgω关系呈现平台特征.同时损耗角tanδ变小并出现极大值.在氮气环境中,上述特征粘弹行为存在但不明显.在加入抗氧剂的条件下,特征粘弹行为完全消失.这些现象归因于高温下HDPE的氧化导致其发生交联.     

镧-依文思蓝-氨基糖苷类抗生素的显色反应及其分析应用

分光光度法;镧-依文思蓝-氨基糖苷类抗生素的显色反应及其分析应用     

Neutron Halos in the Excited States of Spherical Nuclei Near the β-Stable Line

The newly discovered neutron halos in the excited states of nuclei ¹²B, ¹³C, and ²⁰⁹Pb are studied by the relativistic mean-field theory. The calculated binding energies are very close to the experimental ones. The experimentally extracted root-mean-square radii of the last neutron with different occupations in nuclei are well reproduced by calculations. New candidates for the neutron halos in excited states are predicted and are useful for further search of neutron halos in the excited states of stable nuclei.     

配合物LaBi(edta)(NO3)2·7H2O的水热合成、表征及热分解研究

用NH4Bi(edta)·2H2O配合物和硝酸镧按1∶1的物质的量比在150℃条件下,通过水热方法合成了含铋(Ⅲ)和镧(Ⅲ)双金属配合物LaBi(edta)(NO3)2·7H2O.用元素分析仪和滴定分析法确定了产物的组成,用FT-IR、XRD和TG-DSC对产物进行了表征.该配合物为单斜晶系,晶胞参数:a=1.0399nm,b=1.2199nm,c=2.3617nm,β=93.999°.热稳定性研究发现该配合物分解时经过脱水、配体热分解、硝酸盐分解,最后在621℃稳定,残余物为La/Bi氧化物LaBiO3.68.     

初论中国古代对晶体的认识

本文在广泛调研中国古代文献中古代对晶体认识相关史料的基础上,总结了中国古代对于晶体及其基本特性的认识,特别是对晶体形态、对称性及其特征性质的认识.可以看出,中国古代对于晶体的认识虽然丰富,但多停留在表面,从而失去了发展现代晶体学的基础和机遇.     

水热合成NiS2粉晶及Rietveld结构精修

采用水热法一步合成了二硫化镍粉晶,利用XRD、SEM对样品进行了表征并使用Rieteveld粉末衍射峰形全谱拟合方法对不同水热反应条件下合成二硫化镍粉晶的晶体结构进行了研究.并用多相全谱拟合相定量分析法对水热合成二硫化镍粉晶中的杂相质量百分比进行了计算,分析了NiS2粉晶的合成机理.