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81.
This work aims to analyse the so‐called configurational entropy in the Weyl pure geometrical thick brane model. The Weyl structure plays a prominent role in the brane thickness of this model. We find a set of parameters associated to the brane width where the configurational entropy exhibits critical points. The information‐theoretical measure sets bounds into parameter of Weyl pure geometrical brane model. In addition, we also argue that a similar approach can be useful to analyze the corrections to Newtonian and Coulombian potentials in Weyl scenarios.  相似文献   
82.
The chromatography techniques are partially characterized by presence of two phases (stationary and mobile), which allows identification, semi-quantification or quantification of important compounds in different matrices. Among chromatography methods, the thin-layer chromatography (TLC) must be considered for using in routine laboratories due to a number of advantages such as practicality, fast results and effectiveness, low cost, and simultaneous determination of analytes. This review describes the application of this technique to foods of animal origin, as well as compares TLC with other chromatographic methods. TLC has a strong potential as a surrogate chromatographic model for qualitative and quantitative analysis. Therefore, several modifications have been carried out to the conventional TLC system. Nevertheless, further studies should be performed in order to contribute with the scientific community and propagate the TLC method, which has performance and economic advantages compared to other chromatographic techniques.  相似文献   
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85.
Chemical potential phase stability diagrams were calculated from relevant thermodynamic properties and used to predict the thermodynamic driving force under prospective conditions of room temperature mechanosynthesis. One analysed the dependence of chemical potential diagrams on temperature and partial pressure of evolving gases such as oxygen or carbon dioxide, as expected on using strontium peroxide or strontium carbonate as precursor reactants for the alkali earth component. Thermodynamic calculations were also obtained for changes in titania precursor reactants, including thermodynamic predictions for reactivity of strontium carbonate with amorphous titania. Experimental evidence showed that strontium titanate can be obtained by mechanosynthesis of strontium carbonate+anatase mixtures, due to previous amorphization under high energy milling. Ability to perform mechanosynthesis with less energetic milling depends on the suitable choice of alternative precursor reactants, which meet the thermodynamic requirements without previous amorphization; this was demonstrated by mechanosynthesis from anatase+strontium peroxide mixtures.  相似文献   
86.
An approach for the highly stereoselective synthesis of analogs of the macrolactone of isomigrastatin is described. Our optimized strategy is based on a very efficient lactone opening, a Wittig olefination reaction and a ring closing metathesis. The syntheses were accomplished in 10–11 steps and good overall yields.  相似文献   
87.
Chemical analysts use analytical blanks in their analyses, but seldom is this source of uncertainty evaluated. Generally, there is great confusion. Although the numerical value of the blank, in some situations, can be negligible, its source of uncertainty cannot be. This article discusses the uncertainty contribution of the analytical blank using a numerical example of the copper content in waters by flame atomic absorption spectrometry. The results indicate that the uncertainties of the analytical blank can contribute up to 50% when the blank sample is considered in this analysis, confirming its high impact. This effect can be primarily observed where the analyte concentration approaches the lower range of the analytical curve. Even so, the blank is not always computed. Therefore, the relevance of the analytical blank can be confirmed by uncertainty evaluation.  相似文献   
88.
Consider a communication system in which a transmitter equipment sends fixed-size packets of data at a uniform rate to a receiver equipment. Consider also that these equipments are connected by a packet-switched network, which introduces a random delay to each packet. Here we propose an adaptive clock recovery scheme able of synchronizing the frequencies and the phases of these devices, within specified limits of precision. This scheme for achieving frequency and phase synchronization is based on measurements of the packet arrival times at the receiver, which are used to control the dynamics of a digital phase-locked loop. The scheme performance is evaluated via numerical simulations performed by using realistic parameter values.  相似文献   
89.
This note establishes a new sufficient condition for the existence and uniqueness of the Alizadeh-Haeberly-Overton direction for semidefinite programming. The work of these authors was based on research supported by the National Science Foundation under grants INT-9600343 and CCR-970048 and the Office of Naval Research under grant N00014-94-1-0340.  相似文献   
90.
In this paper we show that a variant of the long-step affine scaling algorithm (with variable stepsizes) is two-step superlinearly convergent when applied to general linear programming (LP) problems. Superlinear convergence of the sequence of dual estimates is also established. For homogeneous LP problems having the origin as the unique optimal solution, we also show that 2/3 is a sharp upper bound on the (fixed) stepsize that provably guarantees that the sequence of primal iterates converge to the optimal solution along a unique direction of approach. Since the point to which the sequence of dual estimates converge depend on the direction of approach of the sequence of primal iterates, this result gives a plausible (but not accurate) theoretical explanation for why 2/3 is a sharp upper bound on the (fixed) stepsize that guarantees the convergence of the dual estimates. The work of this author was based on research supported by the Overseas Research Scholars of the Ministry of Education, Science and Culture of Japan, 1992. The work of this author was based on research supported by the National Science Foundation (NSF) under grant DDM-9109404 and the Office of Naval Research (ONR) under grant N00014-93-1-0234. This work was done while the second author was a faculty member of the Systems and Industrial Engineering Department at the University of Arizona.  相似文献   
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