The string coupling accelerates the expansion of the universed

Generic cosmological models in non-critical string theory have a time-dependent dilaton background at a late epoch. The cosmological deceleration parameter q ₀ is given by the square of the string coupling, g _s ², up to a negative sign. Hence the expansion of the Universe must accelerate eventually, and the observed value of q ₀ corresponds to g _s ² ∼ 0.6. In this scenario, the string coupling is asymptotically free at large times, but its present rate of change is imperceptibly small. First Award in the 2005 Essay Competition of the Gravity Research Foundation. - Ed.     

Measurement of CP violation in stop cascade decays at the LHC

We study the potential observation at the LHC of CP-violating effects in stop production and subsequent cascade decays, , , , within the Minimal Supersymmetric Standard Model. We study T-odd asymmetries based on triple products between the different decay products. There may be a large CP asymmetry at the parton level, but there is a significant dilution at the hadronic level after integrating over the parton distribution functions. Consequently, even for scenarios where large CP intrinsic asymmetries are expected, the measurable asymmetry is rather small. High luminosity and precise measurements of masses, branching ratios and CP asymmetries may enable measurements of the CP-violating parameters in cascade decays at the LHC.     

Development and use of a virtual NMR facility

We have developed a "virtual NMR facility" (VNMRF) to enhance access to the NMR spectrometers in Pacific Northwest National Laboratory's Environmental Molecular Sciences Laboratory (EMSL). We use the term virtual facility to describe a real NMR facility made accessible via the Internet. The VNMRF combines secure remote operation of the EMSL's NMR spectrometers over the Internet with real-time videoconferencing, remotely controlled laboratory cameras, real-time computer display sharing, a Web-based electronic laboratory notebook, and other capabilities. Remote VNMRF users can see and converse with EMSL researchers, directly and securely control the EMSL spectrometers, and collaboratively analyze results. A customized Electronic Laboratory Notebook allows interactive Web-based access to group notes, experimental parameters, proposed molecular structures, and other aspects of a research project. This paper describes our experience developing a VNMRF and details the specific capabilities available through the EMSL VNMRF. We show how the VNMRF has evolved during a test project and present an evaluation of its impact in the EMSL and its potential as a model for other scientific facilities. All Collaboratory software used in the VNMRF is freely available from www.emsl.pnl.gov:2080/docs/collab.     

Design, synthesis, and characterization of a calcium-sensitive near infrared dye

Intracellular calcium concentration in biological cells varies from 0.1 to 10 μM depending upon cell signaling and disease states. A direct estimate of calcium concentration in cell tissues within this range is possible with a novel calcium-selective reagent 15C5-774. The molecule of 15C5-774 consists of a near-infrared (NIR) chromophore (λ_max=774 nm) and a metal complexing moiety of benzo-15-crown-5. The reagent shows a strong calcium binding affinity in a 1:1 ratio and metal selectivity in the order Ca²⁺>Mg²⁺>Sr²⁺≈K⁺≈Na⁺>Zn²⁺>Li⁺. The high sensitivity is achieved by conducting absorption measurements in the NIR region where background interference from the biological matrix is low.     

Search for large-rapidity-gap events in e+e− annihilation

We investigate the cross section for the production of a low-mass colour-singlet cluster ine ⁺ e ^? annihilation with a large rapidity gap between the colour-singlet cluster and the other jets. It is argued that such events are the cross-channel analogue of large-rapidity-gap events in deep-inelastic scattering, and therefore could in principle be used to investigate the analytic continuation of the BFKL pomeron to the positive-t kinematic regime, where one would expect the trajectory to pass through glueball states. The cross section can be calculated in perturbative QCD, so that the infrared scale arising from non-perturbative effects, which prevents an exponential fall-off with rapidity gap in the case of deep-inelastic scattering, is absent ine ⁺ e ^? annihilation. Correspondingly, the cross section for such events decreases rapidly with increasing rapidity gap.     

Hydrogen and carbon NMR data for aminoquinolines and aminoisoquinolines

Hydrogen and carbon chemical shifts and H? H and C? H couplings are reported for six aminoquinolines and six aminoisoquinolines in DMSO-d₆.     

General Covariance in General Relativity?

The mathematical approach to General Relativity insists that all coordinate systems are equal. However physicists and astrophysicists in fact almost always use preferred coordinate systems not merely to simplify the calculations but also to help define quantities of physical interest. This suggests we should reconsider and perhaps refine the dogma of General Covariance.