Novel bent-shaped liquid crystalline compounds II. Synthesis and properties of the 1,3-bis4-[4-(4-alkyloxybenzoyloxy)benzylidene]aminophenoxypropan-2-ols

A series of new symmetric dimer compounds was synthesized, constaining 2-hydroxy-1,3-dioxypropylene as the central linkage and terminal alkyl chains with different lengths. The chemical structures of the liquid crystal dimers (2ES-n) were examined by FTIR and ¹H NMR spectroscopy. Their mesomorphism, thermodynamic properties and optical textures were investigated by differential scanning calorimetry, polarizing optical microscope and X-ray diffraction. For homologues with terminal propyloxy and butyloxy chains, no liquid crystalline phase was observed. Homologues with pentyloxy and hexyloxy terminal chains showed nematic phases, while those with heptyloxy, octyloxy, nonyloxy and decyloxy terminal chains displayed nematic phases and smectic phases. The results confirmed that the liquid crystalline phase changes from nematic to smectic as the terminal chain length increases.     

镍基双晶体晶界断裂特性研究

对单晶体以及晶界平行晶粒裂纹和晶界垂直晶粒裂纹的双晶体的断韧性进行了实验研究,设计了三种三点弯曲试件,得到了单晶体和晶界的断裂韧性值,在晶界垂直晶粒裂纹的双晶体试验中,揭示了晶界对晶粒断裂的屏蔽效应;当裂纹距晶界某一特定长度时,断裂韧性值最大,理论分析和晶体滑移有限元数值分析揭示了这种屏蔽效应的机理,双晶晶界处的变表相容性导致了理解纹尖端应国和场的重新分布,并由此产生了晶界屏蔽效应。     

便携式红外甲烷浓度测试仪的研制

利用红外吸收原理,研制一种测量1．33um波段甲烷浓度的测试仪,该仪器的特点是测量时不受其他气体成份影响,体积小,精度高,采用数字显示,操作简单,适合野外条件下使用。     

复合材料和粘弹性材料中的应力奇异性

在各种材料中,出现的应力奇异性已为工程技术人员的科学研究提供了丰富的素材,本文的主要目的在于对粘弹性材料的应力奇异性进行探讨,利用对应性原理从弹性材料导出粘生材料的应力奇异分布。     

A pressure correction method for fluid–particle interaction flow: Direct‐forcing method and sedimentation flow

A direct‐forcing pressure correction method is developed to simulate fluid–particle interaction problems. In this paper, the sedimentation flow is investigated. This method uses a pressure correction method to solve incompressible flow fields. A direct‐forcing method is introduced to capture the particle motions. It is found that the direct‐forcing method can also be served as a wall‐boundary condition. By applying Gauss's divergence theorem, the formulas for computing the hydrodynamic force and torque acting on the particle from flows are derived from the volume integral of the particle instead of the particle surface. The order of accuracy of the present method is demonstrated by the errors of velocity, pressure, and wall stress. To demonstrate the efficiency and capability of the present method, sedimentations of many spherical particles in an enclosure are simulated. Copyright © 2010 John Wiley & Sons, Ltd.     

A pressure correction‐volume of fluid method for simulation of two‐phase flows

A pressure correction method coupled with the volume of fluid (VOF) method is developed to simulate two‐phase flows. A volume fraction function is introduced in the VOF method and is governed by an advection equation. A modified monotone upwind scheme for a conservation law (modified MUSCL) is used to solve the solution of the advection equation. To keep the initial sharpness of an interface, a slope modification scheme is introduced. The continuum surface tension (CST) model is used to calculate the surface tension force. Three schemes, central‐upwind, Parker–Youngs, and mixed schemes, are introduced to compute the interface normal vector and the gradient of the volume fraction function. Moreover, a height function technique is applied to compute the local curvature of the interface. Several basic test problems are performed to check the order of accuracy of the present numerical schemes for computing the interface normal vector and the gradient of the volume fraction function. Three physical problems, two‐dimensional broken dam problem, static drop, and spurious currents, and three‐dimensional rising bubble, are performed to demonstrate the efficiency and accuracy of the pressure correction method. Copyright © 2010 John Wiley & Sons, Ltd.     

台阶板中兰姆波A0模式传播特性的光弹研究

为了研究变壁厚结构中兰姆波的传播特性,以K9玻璃制成的台阶板为波导,运用动态光弹法实现了兰姆波在阶梯板中传播过程的可视化。使用MATLAB对兰姆波的理论应力分布进行了仿真,将仿真结果与光弹图像相对比以进行模式识别。此外,根据兰姆波的动态光弹图像计算了特定模式的相速度,并与相速度频散曲线相对比,以支持模式识别的结果。对4mm-3mm和4mm-2mm厚度差台阶板进行了对比分析。研究发现在激励目标模式的兰姆波时,可能会出现非目标模式,并且兰姆波的模态转换与频散程度与台阶处的厚度差有关。本文的结果可对具有相同性质类似结构材料的无损检测提供参考。     

利用图像分析实现函件自动登单处理系统

针对邮局业务的自动化、信息化改革，利用图像处理和图像分析方法， 结合模式识别理论，从复杂的信封背景中提取有用字迹信息，设计了自动化的给据函件自动登单处理系统。详细介绍了该系统的软硬件结构和整个图像处理过程。对各种信封的处理实验结果表明，所提出的该图像处理方法能够很好的满足实际邮政业务的需要，提高了邮件处理的效率和水平，减轻了工作强度。     

纳米α-Fe/PS复合材料的制备及其热力学性能研究

采用油包水(W/O)的微乳液体系制备了粒度为20~100 nm的α Fe。对纳米Fe进行表面有机改性后分散到苯乙烯（St）单体中,得到分散均匀的Fe/St分散体系,用本体聚合的方法制备了纳米Fe/PS复合材料。利用XRD,TEM,FTIR,SEM及TG DSC分别研究了所得纳米Fe的性能、复合材料的结构、纳米Fe在PS中的分散情况以及掺杂量对纳米Fe/PS复合材料的热力学行为的影响。研究结果表明：增加纳米α-Fe的掺杂量能提高PS的降解率,降低降解温度,增大热分解的焓变。