Ar在玻璃微球中的辐照增强扩散效应研究

为满足惯性约束聚变实验诊断的需求,需要在空心玻璃微球内充入DT燃料气体的同时充入一定量的Ar诊断气体,由于Ar原子尺寸较大,一般热扩散技术难以实现对玻璃微球充Ar。为解决充Ar问题,研究了不同反应堆中子注量对玻璃微球的改性作用。测试结果表明：当中子注量达到1×1018 cm-2时,在500 ℃和室温情况下都可以向玻璃微球内充入Ar。辐照增强扩散后的扩散系数高于3.6×10-13 cm2/s。     

同轴电缆头和转接头HPM击穿现象初步分析

介绍了同轴电缆头和转接头的HPM击穿实验研究方法,给出了几种电缆头和转接头微波击穿功率随微波频率、脉冲宽度、重复频率和脉冲持续时间变化规律的实验研究结果。结果表明：微波击穿发生在同轴电缆头连接处,是电缆接头沿面滑闪,且击穿功率随同轴电缆及转接头尺寸的减小而降低;击穿功率也随微波脉冲宽度（30 ns～1 μs）的增大而减小,并且在100 ns附近有一拐点;在低重复频率（1～1000 Hz）下,重频对击穿功率的影响不大;微波频率在2.856～9.37 GHz变化时,微波频率对击穿功率的影响不明显;微波脉冲宽度较窄时（几十ns以下）,击穿功率随持续时间变化不大,脉冲宽度较宽时（百ns以上）,击穿阈值随持续时间的增大而下降。     

CSRm束流径向和轴向振荡的耦合

介绍了由于磁铁的安装误差和螺线管的存在而造成的束流径向和轴向的耦合,以及耦合对束流稳定的影响。结合CSRm结构的典型参数分析得出：二极磁铁和四极磁铁在纵向角安装偏差为-0.5~0.5 mrad;有螺线管存在的情况下,工作点落在和共振线时,将导致束流不稳定而大量损失,落在差共振线时,束流稳定。通过模拟计算发现：螺线管产生的耦合远大于磁铁的纵向角安装偏差产生的耦合。     

电流型探测器单粒子灵敏度标定的原理及应用

采用电荷模数转换记录单个脉冲电荷的方法,标定了单能射线在电流型闪烁探测器中产生的平均电流,从而得到其灵敏度。标定结果与传统的电流法在±8%的范围内一致。该标定方法准确度高,扣除本底容易,对标定源的强度要求也大大降低。加上飞行时间法,还可对粒子进行甄别,能在中子-γ射线混合场中将中子和γ射线的电荷贡献分开,得到探测器对每种射线单独的灵敏度。该方法适用于在单个脉冲电荷信噪比较高的场合下标定脉冲电流型探测器。     

TLCODE模拟方法介绍

探讨了TLCODE传输线模拟方法的基本原理、求解方法及步骤,推导了传输线驱动电阻负载、静态电感负载和混合型负载三种典型负载时末端界面电压的表达式,用PSPICE构造一个电路模型,以静态电感负载的计算结果为例,对所介绍的TLCODE方法及推导的公式模型予以验算。结果表明,在计算负载电压时,TLCODE与PSPICE的最大偏差仅为0.2%,在计算电流时,最大偏差仅为0.1%。     

Stereoselectivity in Diphos Addition to Molybdenum Complex with Pyridine‐2‐thionate (pyS) and η3‐Methallyl Coordinated Ligands

The conformational isomers endo‐ and exo‐[Mo{η³‐C₃H₄(CH₃)}(η²‐pyS)(CO)(η²‐diphos)] (diphos: dppm = {bis(diphenylphosphino)methane}, 2 ; dppe = {1,2‐bis(diphenylphosphino)ethane}, 3 ) are prepared by reacting the double‐bridged pyridine‐2‐thionate (pyS) complex [Mo{η³‐C₃H₄(CH₃)}(CO)₂]₂(η¹:η²:μ‐pyS)₂, 1 with diphos in refluxing acetonitrile. Stereoselectivity of the methallyl, C₃H₄(CH₃), ligand improves the formation of the exo‐conformation of 2 and 3 . Orientations and spectroscopy of these complexes are discussed.     

Synthesis and Crystal Structures of the Molybdenum(II) Complexes with the N,N‐dimethylthiocarbamoyl Containing Ligand: Crystal Structures of β [Mo(CO)2{η2‐S2P(OEt)2}(η2‐SCNMe2)(PPh3)] and [Mo(CO)2(η3‐Tp)(η2‐SCNMe2)(PPh3)]

Reactions of the thiocarbamoyl‐molybdenum complex [Mo(CO)₂(η²‐SCNMe₂)(PPh₃)₂Cl] 1 , and ammonium diethyldithiophosphate, NH₄S₂P(OEt)₂, and potassium tris(pyrazoyl‐1‐yl)borate, KTp, in dichloromethane at room temperature yielded the seven coordinated diethyldithiophosphate thiocarbamoyl‐molybdenum complexe [Mo(CO)₂{η²‐S₂P(OEt)₂}(η²‐SCNMe₂)(PPh₃)] β‐3 , and tris(pyrazoyl‐1‐yl)borate thiocabamoyl‐molybdenum complex [Mo(CO)₂(η³‐Tp)(η²‐SCNMe₂)(PPh₃)] 4 , respectively. The geometry around the metal atom of compounds β‐3 and 4 are capped octahedrons. The α‐ and β‐isomers are defined to the dithio‐ligand and one of the carbonyl ligands in the trans position in former and two carbonyl ligands in the trans position in later. The thiocabamoyl and diethyldithiophosphate or tris(pyrazoyl‐1‐yl)borate ligands coordinate to the molybdenum metal center through the carbon and sulfur and two sulfur atoms, or three nitrogen atoms, respectively. Complexes β‐3 and 4 are characterized by X‐ray diffraction analyses.     

NaCl对水稻谷氨酰胺合成酶活性及同工酶的影响

在营养液中 Ｎａ Ｃｌ的胁迫下,水稻根和叶的谷氨酰胺合成酶（ Ｇ Ｓ）的活性降低,但叶的 Ｇ Ｓ活性对 Ｎａ Ｃｌ浓度的敏感性大于根根和叶中的 Ｇ Ｓ活性变化与根和叶的平均质量和可溶性蛋白水平的变化是一致的 Ｎａｔｉｖｅ Ｐ Ａ Ｇ Ｅ活性染色以及 Ｉｍ ｍ ｕｎｏｂｌｏｔｔｉｎｇ 检测表明,根和叶的 Ｇ Ｓ活性的降低主要是由于 Ｇ Ｓｒｂ 和 Ｇ Ｓ２的活性及其相应蛋白质水平降低所致     

Structural characterization of aldehyde-terminated self-assembled monolayers

The structure of aldehyde-terminated alkanethiol self-assembled monolayers (SAMs) on Au(111) is investigated using scanning tunneling microscopy (STM), atomic force microscopy (AFM), and density functional theory (DFT) calculations. For the first time, the structures of aldehyde-terminated SAMs are revealed with molecular resolution. SAMs of 11-mercapto-1-undecanal exhibit the basic (radical3xradical3)R30 degrees periodicity and form various c(4x2) superstructures upon annealing. In conjunction with DFT studies, the models of the (radical3xradical3)R30 degrees and the c(4x2) superstructures are constructed. In comparison with alkanethiol SAMs, the introduction of aldehyde-termini results in smaller domain size, lower degree of long-range order, large coverage of disordered areas, and higher density of missing molecules and other point defects within domains of closely packed molecules. The origin of these structural differences is mainly attributed to the strong dipole-dipole interactions among the aldehyde termini.     

A mathematical model of measurement uncertainty of single substrate enzyme assays

Clinical laboratory tests provide critical information at every stage of the medical decision‐making process, and measurement of the activity levels of enzymes such as alkaline phosphatase, lactate dehydrogenase, etc. provide information regarding various body functions such as the liver and gastrointestinal tract. The uncertainty associated with these enzyme measurement processes describes the quality of the measurement process, and therefore methods to improve the quality of the measurement process require minimizing the measurement uncertainty of the enzyme assay. In this study, we develop a mathematical model of the lactate dehydrogenase measurement process, with uncertainty introduced into its parameters that represent the sources of variation in the different components and stages of the measurement process. The Monte Carlo method is then utilized to estimate the uncertainty associated with the model, and therefore the measurement process. An empirical function used to generate estimates of uncertainty for patient samples with unknown activity levels is constructed using the model. The model is then used to quantify the contributions of the individual sources of uncertainty to the net measurement uncertainty and also quantify the effect of uncertainty within the calibration process on the distribution of the measurement result. Copyright © 2014 John Wiley & Sons, Ltd.