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51.
Sherrod L. Maxwell Brian A. Culligan Vernon D. Jones Sheldon T. Nichols Gary W. Noyes 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(1):223-230
A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of 237Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry. 238U can interfere with 239Pu measurement by ICP-MS as 238UH+ mass overlap and 237Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4?C6 h, and can also be used for emergency response. 239Pu, 242Pu and 237Np were measured by ICP-MS, while 236Pu, 238Pu, and 239Pu were measured by alpha spectrometry. 相似文献
52.
Kotani H Ohkubo K Crossley MJ Fukuzumi S 《Journal of the American Chemical Society》2011,133(29):11092-11095
Addition of potassium superoxide with 18-crown-6 ether (KO(2)(?-)-18-crown-6) to a toluene solution of an acridinium ion-linked porphyrin triad (Acr(+)-H(2)P-Acr(+)) resulted in a remarkable enhancement of the fluorescence intensity. Thus, Acr(+)-H(2)P-Acr(+) acts as an efficient fluorescence sensor for superoxide. Electron transfer from KO(2)(?-)-18-crown-6 to the Acr(+) moiety to produce the two-electron-reduced species (Acr(?)-H(2)P-Acr(?)) results in inhibition of the fluorescence quenching via photoinduced electron transfer, as revealed by laser flash photolysis measurements. 相似文献
53.
Ou Z Zhu W Fang Y Sintic PJ Khoury T Crossley MJ Kadish KM 《Inorganic chemistry》2011,50(24):12802-12809
The electrochemistry of gold(III) mono- and bis-quinoxalinoporphyrins was examined in CH(2)Cl(2) or PhCN containing 0.1 M tetra-n-butylammonium perchlorate (TBAP) before and after the addition of trifluoroacetic acid to solution. The investigated porphyrins are represented as Au(PQ)PF(6) and Au(QPQ)PF(6), where P is the dianion of the 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin and Q is a quinoxaline group fused to a β,β'-pyrrolic position of the porphyrin macrocycle; in Au(QPQ)PF(6) there is a linear arrangement where the quinoxalines are fused to pyrrolic positions that are opposite each other. The porphyrin without the fused quinoxaline groups, Au(P)PF(6), was also investigated under the same solution conditions. In the absence of acid, all three gold(III) porphyrins undergo a single reversible Au(III)/Au(II) process leading to the formation of a Au(II) porphyrin which can be further reduced at more negative potentials to give stepwise the Au(II) porphyrin π-anion radical and dianion, respectively. However, in the presence of acid, the initial Au(III)/Au(II) processes of Au(PQ)PF(6) and Au(QPQ)PF(6) are followed by an internal electron transfer and protonation to regenerate new Au(III) porphyrins assigned as Au(III)(PQH)(+) and Au(III)(QPQH)(+). Both protonated gold(III) quinoxalinoporphyrins then undergo a second Au(III)/Au(II) process at more negative potentials. The electrogenerated monoprotonated monoquinoxalinoporphyrin, Au(II)(PQH), is then further reduced to its π-anion radical and dianion forms, but this is not the case for the monoprotonated bis-quinoxalinoporphyrin, Au(II)(QPQH), which accepts a second proton and is rapidly converted to Au(III)(HQPQH)(+) before undergoing a third Au(III)/Au(II) process to produce Au(II)(HQPQH) as a final product. Thus, Au(P)PF(6) undergoes one metal-centered reduction while Au(PQ)PF(6) and Au(QPQ)PF(6) exhibit two and three Au(III)/Au(II) processes, respectively. These unusual multistep sequential Au(III)/Au(II) processes were monitored by thin-layer spectroelectrochemistry and a reduction/oxidation mechanism for Au(PQ)PF(6) and Au(QPQ)PF(6) in acidic media is proposed. 相似文献
54.
Real-time volumetric growth rate measurements and feedback control of three-dimensional laser chemical vapor deposition 总被引:1,自引:0,他引:1
J.L. Maxwell J. Pegna D.V. Messia 《Applied Physics A: Materials Science & Processing》1998,67(3):323-329
Received: 4 June 1997/Accepted: 12 June 1997 相似文献
55.
The optical loss is an important parameter for waveguides used in integrated optics. We measured the optical loss in waveguides written in silicate glass slides with high repetition-rate (MHz) femtosecond laser pulses. The average transmission loss of straight waveguides is about 0.3 dB/mm at a wavelength of 633 nm and 0.05 dB/mm at a wavelength of 1.55 μm. The loss is not polarization dependent and the waveguides allow a minimum bending radius of 36 mm without additional loss. The average numerical aperture of the waveguides is 0.065 at a wavelength of 633 nm and 0.045 at a wavelength of 1.55 μm. In straight waveguides more than 90% of the transmission loss is due to scattering. 相似文献
56.
57.
M. Nilmani T.T. Maxwell D.G.C. Robertson D.B. Spalding 《Applied Mathematical Modelling》1981,5(1):24-28
Numerical predictions are presented for the motion and distortion of a single gas bubble rising through the liquid. The computations were made with an implicit finite-difference procedure which solves the transient equations of motion throughout the bubble and the liquid, such that the free surface between the gas bubble and the liquid is not a boundary of the computational domain.The predictions compare well with the experimental results of others. Computations are presented for bubble sizes from 0.02 to 0.05 m radius and for bubbles of different gas densities rising in liquids of different densities. Surface tension effects are neglected. 相似文献
58.
C. J. Maxwell 《Zeitschrift fur Physik C Particles and Fields》1982,12(1):35-41
It is shown that the additive quark model is compatible with the data on double scattering of pions and protons in deuterium. The cross-section for interaction of the hadrons created in the first collision with the second nucleon of the target is determined to be 20–25 mb. 相似文献
59.
60.