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261.
Critical problems of the present approach of electrolytes for Solid Oxide Fuel Cells (SOFCs) for commercialization are discussed.
Major progress is expected from the development of materials based on the “SEA (Single Element Arrangement)” concept. The
galvanic cell consists in this case basically of a single chemically homogeneous compound, which functions as electrodes at
high and low activity and as electrolyte at intermediate activities of the electroactive component.
In view of the large structural flexibility of the chemical nature of the constitutents, we explored perovskite (ABO3)-type compounds to be used as SEAs for SOFCs. Results of studies on Pr-substituted LSGM and Fe-substituted SrSnO3 perovskite-type oxides are presented. For instance, SrSn1-xFexO3-δ with x=0.1 exhibits p and n-type electronic conduction at the cathode and anode sides of the SOFC, respectively, while oxide
ion conduction prevails at intermediate oxygen partial pressures. The SEA concept is also applicable for other devices in
the field of Ionics. 相似文献
262.
263.
264.
A. I. Magunov A. Ya. Faenov I. Yu. Skobelev T. A. Pikuz E. Biémont P. Quinet F. Blasco C. Bonte F. Dorchies T. Caillaud F. Salin C. Stenz 《Journal of Experimental and Theoretical Physics》2002,95(6):998-1005
The satellite structure of 1s2p 1,3 P 1-1s 21 S 0 lines of the He-like argon ion in plasma produced by a 45-fs laser pulse in a gas-jet cluster target is measured with a high spectral resolution. Radiation transitions 2p → 1s from autoionizing states (AISs) are detected for ions ranging from Li-like to F-like. The spectrum observed is theoretically simulated with the use of the spectroscopic data for the AISs of multicharged ions obtained within the multiconfiguration relativistic Hartree-Fock method. Good agreement with experimental data is obtained when the main population channels of these states are taken into account for typical values of cluster-target plasma parameters. 相似文献
265.
M. Gorkunov M. Lapine E. Shamonina K.H. Ringhofer 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(3):263-269
Effective magnetic properties of a composite meta-material consisting of periodically arranged circular conductive elements
are studied theoretically. A general expression for the effective bulk permeability is obtained with mutual effects and lattice
ordering being taken into account. The resonance frequency of the permeability is found to be strongly dependent on the size
and shape of the unit cell. Frequency dispersion of the permeability is studied with special attention paid to the frequency
range, where negative values of the permeability are possible. Corresponding recommendations for optimisation of the meta-materials
with negative permeability are made. The results are confirmed by numerical simulations of the finite structure behaviour
in an external magnetic field.
Received 19 April 2002 Published online 31 July 2002 相似文献
266.
Q. Sun Q. Wang X.G. Gong V. Kumar Y. Kawazoe 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(1):77-81
We report results of the atomic and electronic structures of Al7C cluster using ab initio molecular dynamics with ultrasoft pseudopotentials and generalized gradient approximation. The lowest energy structure is
found to be the one in which carbon atom occupies an interstitial position in Al7 cluster. The electronic structure shows that the recent observation [Chem. Phys. Lett. 316, 31 (2000)] of magic behavior of Al7C- cluster is due to a large highest occupied and lowest unoccupied molecular orbital (HOMO-LUMO) gap which makes Al7C- chemically inert. These results have further led us to the finding of a new neutral magic cluster Al7N which has the same number of valence electrons as in Al7C- and a large HOMO-LUMO gap of 1.99 eV. Further, calculations have been carried out on (Al7N)2 to study interaction between magic clusters.
Received 28 July 2001 相似文献
267.
An overview of theoretical and experimental studies of the coherent type-B e
+
e-pair production by photons in aligned crystals performed at Nuclear Physics Institute at Tomsk Polytechnic University is given. 相似文献
268.
M. A. Augustyniak-Jabłokow K. Łukaszewicz A. Pietraszko V. E. Petrashen Yu. V. Yablokov 《Physics of the Solid State》2002,44(8):1480-1483
The EPR spectra evolution of Cs2Zn1?x Cux(ZrF6)2 · 6H2O (x=0.01, 0.6, 0.8, and 1.0) in the temperature range 4.2–330 K and the x-ray structure analysis of the compound with x=1.0 in the range 150–327 K show that the Jahn-Teller (JT) complex Cu(H2O)6 coordination sphere undergoes a plastic deformation. The observed effect is due to the combined influence of small lattice strains existing in the paraphase and a new one appearing as a result of a ferroelastic phase transition and increasing with decreasing temperature below T c . It is proved that both cooperative interactions between JT complexes and ferroelastic strain stabilize a certain JT configuration. The problem of instability of a JT configuration compressed at T ~ 265 K is discussed. 相似文献
269.
Discharges with liquid nonmetallic electrodes of much interest for applications are investigated. It is found that a dc discharge between two streams of tap water in air at atmospheric pressure is stable at a currentof 40≤I≤100 mA. The discharge exists in the diffuse (volume) form with a relatively low current density (∼0.2 A/cm2) and a high (above one kilovolt) voltage drop across the air gap (∼1 cm) between the water electrodes. The current density and voltage depend only slightly on the discharge current. Probe measurements show that three regions can be distinguished in the discharge: two electrode regions (1–2 mm in length) and a discharge column with a constant electric field of ≈0.8 kV/cm (i.e., E/N≈20 Td, because the gas in the discharge is heated up to 1500–2000 K). The average electric field strength near the electrodes is E≈2–3×103 V/cm (E/N≈60–80 Td). The charged particle density in the column is n ∼ 1012 cm−3. The probe measurements of n agree with the previous microwave absorption measurements. The water vapor concentration in the column is also estimated from probe measurements. 相似文献
270.
The present paper analyzes the properties of structural phase transitions under the extremal conditions of high pressures. In the context of the theory of density functional (TDF), the pressures of the B1–B2 transitions are calculated for small alkali-halide crystals as functions of the crystal size. The size effect of the B1–B2 transition – an increase in the transition pressure with the decreasing crystal grain radius – has been established for all investigated halides except lithium fluoride for which the dependence is reverse. 相似文献