Instrumented Projectile Penetration Testing of Granular Materials

The results of a series of penetration experiments with cylindrical projectiles (diameter: 30 mm, length: 158 mm) of different tip geometries (hemispherical, conic and flat) impacting with approx. 380 m/s on cylindrical sand targets (diameter: 250 mm, length: 1 m) are presented. The projectiles are instrumented with an on-board data recorder system with acceleration sensor (G-Rec), allowing for in-situ measurement of the decelerations experienced during the impact and during the subsequent penetration process. During and after the acceleration stage inside the gun barrel, the velocities derived from the G-Rec data show a very good agreement with an independent reference velocity measurement obtained by a light barrier system. Immediately after the initial impact on the granular material (compacted sand for this study), the sensor signals indicate very strong amplitude oscillating decelerations in the range of 50,000 to 80,000 g. The measured penetration depth varied widely for identical conditions of projectile impact, using identical preparation procedures for the sand sample. Variables considered for the experimental program included projectile tip shape, initial sand compaction state, and projectile velocity. A data reduction procedure to obtain velocity and position information of the projectile while penetrating the sand assembly is presented, taking into account a constant value (offset) observed in the raw signals of G-Rec at the end of penetration process. The formation of a false tip of agglomerated quartz powder in front of the projectile was observed in all cases. The observed shape of the false tip (penetrator tip with comminuted sand) was found to be identical for all projectile tip shapes (flat, hemispherical, and conical) considered in this study. Initial examination results of the false tip using X-ray computed tomography are presented.     

External-cavity lasers based on a volume holographic grating at normal incidence for spectroscopy in the visible range

We present two external-cavity diode lasers that utilize a volume holographic grating as the frequency selective feedback element. By using the grating at normal incidence, it is possible to design simple and compact external-cavity diode lasers that have sufficient tunability for molecular spectroscopy. The first design utilizes a long-cavity designed for narrow linewidth and good long-term stability. The laser operates near 635 nm and it has a PZT-controlled tuning range of 28 GHz and a 1-s linewidth of 900 kHz. The second design utilizes a grating attached very close to the laser diode, making the laser compact, robust and easy to operate. The short external-cavity laser operates near 658 nm and it has a linewidth of 30 MHz. Continuous and mode-hop free tuning range of 145 GHz can be obtained by using a simple temperature tuning method.     

Post-blast detection of traces of explosives by means of Fourier transform infrared spectroscopy

Samples obtained from debris after explosions of about 30 g of energetic materials were analyzed by means of Fourier transform infrared (FTIR) spectroscopy using both, Globar and synchrotron infrared radiation at the ISMI beamline of the Singapore synchrotron light source (SSLS). Low- and high-strength-of-explosion blasts were performed during each test run with the same explosive material. From the spectroscopic measurements, traces of unreacted explosives were found on more than 200 different materials that served as sample catchers in the explosions.The integrality of the experiments done confirmed that FTIR spectroscopy is a sufficiently sensitive method to detect traces of explosives in post-blast residues even of high-strength explosions. The method requires only a minimal amount of sample and enables accurate and very fast identification of the presence of explosive material. Finally, the synchrotron radiation infrared source provided one order of magnitude higher sensitivity compared to the conventional Globar source.     

Stable oxide nanoparticle clusters obtained by complexation

We report on the electrostatic complexation between polyelectrolyte-neutral copolymers and oppositely charged 6-nm crystalline nanoparticles. For two different dispersions of oxide nanoparticles, the electrostatic complexation gives rise to the formation of stable nanoparticle clusters in the range 20-100 nm. It is found that inside the clusters, the particles are "pasted" together by the polyelectrolyte blocks adsorbed on their surface. Cryo-transmission electronic microscopy allows visualization of the clusters and determination of the probability distribution functions in size and in aggregation number. The comparison between light scattering and cryo-microscopy results suggests the existence of a polymer brush around the clusters.     

High molar extinction coefficient heteroleptic ruthenium complexes for thin film dye-sensitized solar cells

Two novel heteroleptic sensitizers, Ru((4,4-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2 and Ru((4,4-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(p-methoxystyryl)-2,2'-bipyridine) (NCS)2, coded as K-19 and K-73, respectively, have been synthesized and characterized by 1H NMR, FTIR, UV-vis absorption, and emission spectroscopy and excited-state lifetime and spectroelectrochemical measurements. The introduction of the alkoxystyryl group extends the conjugation of the bipyridine donor ligand increasing markedly their molar extinction coefficient and solar light harvesting capacity. The dynamics of photoinduced charge separation following electronic excitation of the K-19 dye was scrutinized by time-resolved laser spectroscopy. The electron transfer from K-19 to the conduction band of TiO2 is completed within 20 fs while charge recombination has a half-life time of 800 s. The high extinction coefficients of these sensitizers enable realization of a new generation of a thin film dye sensitized solar cell (DSC) yielding high conversion efficiency at full sunlight even with viscous electrolytes based on ionic liquids or nonvolatile solvents. An unprecedented yield of over 9% was obtained under standard reporting conditions (simulated global air mass 1.5 sunlight at 1000 W/m2 intensity) when the K-73 sensitizer was combined with a nonvolatile "robust" electrolyte. The K-19 dye gave a conversion yield of 7.1% when used in conjunction with the binary ionic liquid electrolyte. These devices exhibit excellent stability under light soaking at 60 degrees C. The effect of the mesoscopic TiO2 film thickness on photovoltaic performance has been analyzed by electrochemical impedance spectroscopy (EIS).     

Er3+/Yb3+-activated silica-hafnia planar waveguides for photonics fabricated by rf-sputtering

95.8SiO₂–4.2HfO₂ planar waveguide activated by 0.2 mol% Er and 0.2 mol% Yb was fabricated by multi-target rf-sputtering technique. The optical parameters were measured by an m-line apparatus operating at 543.5, 632.8, 1319 and 1542 nm. The waveguide compositions were investigated by energy dispersive spectroscopy. The waveguide exhibits a single propagation mode at 1.3 and 1.5 μm with an attenuation coefficient of 0.2 dB/cm at 1.5 μm. The emission of ⁴I_13/2 → ⁴I_15/2 transition of Er³⁺ ion, with a 42 nm bandwidth was observed upon TE₀ mode excitation at 980 and 514.5 nm. Photoluminescence excitation spectroscopy was used to obtain information about the effective excitation efficiency of Er³⁺ ions by co-doping with Yb³⁺ ions. Channel waveguide in rib configuration were fabricated by wet etching process in the active film.     

Voltage enhancement in dye-sensitized solar cell using (001)-oriented anatase TiO2 nanosheets

A nanocrystalline TiO₂ (anatase) nanosheet exposing mainly the (001) crystal faces was tested as photoanode material in dye-sensitized solar cells. The nanosheets were prepared by hydrothermal growth in HF medium. Good-quality thin films were deposited on F-doped SnO₂ support from the TiO₂ suspension in ethanolic or aqueous media. The anatase (001) face adsorbs a smaller amount of the used dye sensitizer (C101) per unit area than the (101) face which was tested as a reference. The corresponding solar cell with sensitized (001)-nanosheet photoanode exhibits a larger open-circuit voltage than the reference cell with (101)-terminated anatase nanocrystals. The voltage enhancement is attributed to the negative shift of flatband potential for the (001) face. This conclusion rationalizes earlier works on similar systems, and it indicates that careful control of experimental conditions is needed to extract the effect of band energetic on the current/voltage characteristics of dye-sensitized solar cell.     

Minimizers of a weighted maximum of the Gauss curvature

On a Riemann surface [`(S)]{\overline{\Sigma}} with smooth boundary, we consider Riemannian metrics conformal to a given background metric. Let κ be a smooth, positive function on [`(S)]{\overline{\Sigma}}. If K denotes the Gauss curvature, then the L ^∞-norm of K/κ gives rise to a functional on the space of all admissible metrics. We study minimizers subject to an area constraint. Under suitable conditions, we construct a minimizer with the property that |K|/κ is constant. The sign of K can change, but this happens only on the nodal set of the solution of a linear partial differential equation.     

Interface induced crystal structures of dioctyl-terthiophene thin films

Temperature dependent structural and morphological investigations on semiconducting dioctyl-terthiophene (DOTT) thin films prepared on silica surfaces reveals the coexistence of surface induce order and distinct crystalline/liquid crystalline bulk polymorphs. X-ray diffraction and scanning force microscopy measurements indicate that at room temperature two polymorphs are present: the surface induced phase grows directly on the silica interface and the bulk phase on top. At elevated temperatures the long-range order gradually decreases, and the crystal G (340 K), smectic F (348 K), and smectic C (360 K) phases are observed. Indexation of diffraction peaks reveals that an up-right standing conformation of DOTT molecules is present within all phases. A temperature stable interfacial layer close to the silica-DOTT interface acts as template for the formation of the different phases. Rapid cooling of the DOTT sample from the smectic C phase to room temperature results in freezing into a metastable crystalline state with an intermediated unit cell between the room temperature crystalline phase and the smectic C phase. The understanding of such interfacial induced phases in thin semiconducting liquid crystal films allows tuning of crystallographic and therefore physical properties within organic thin films.     

Experimental observation of spatially localized dynamo magnetic fields

We report the first experimental observation of a spatially localized dynamo magnetic field, a common feature of astrophysical dynamos and convective dynamo simulations. When the two propellers of the von Kármán sodium experiment are driven at frequencies that differ by 15%, the mean magnetic field's energy measured close to the slower disk is nearly 10 times larger than the one close to the faster one. This strong localization of the magnetic field when a symmetry of the forcing is broken is in good agreement with a prediction based on the interaction between a dipolar and a quadrupolar magnetic mode.