Investigation of microbial—mineral interactions by Mössbauer spectroscopy

Mössbauer spectroscopy was used to investigate the reactions of microbes with iron minerals in aqueous solutions and as components of rocks in banded iron formations and granite. A microbial biofilm that formed on a wall of an excavated granite vault in a deep underground laboratory initiated this research. At the aerobic face of the biofilm, iron was found in a form of ferrihydrite; in the anaerobic face against the rock, iron was found as very small siderite particles. Laboratory incubations of the biofilm microbial consortium showed different mineral species could be formed. When the microbial consortium from the biofilm was incubated with magnetite grains, up to about 10% of the iron was altered in three weeks to hematite. The ability of the consortium to precipitate iron both as Fe²⁺ and Fe³⁺ in close proximity may have a bearing on the deposition of banded iron formations. These reactions could also be important in microbially induced corrosion.     

Photodiffraction in InGaAs/InGaAsP multiple quantum wells enclosed in a microcavity

We report new results on the diffraction properties of photoinduced gratings in InGaAs/InGaAsP MQW structures. The original feature of this device is that the QWs are enclosed in an asymmetric Fabry–Perot microcavity in order to increase the diffraction efficiency. We observe oscillations in the diffraction efficiency due to resonant effects in the microcavity. The experimental spectra are compared with theory. Diffraction efficiency at 1.55 μm attains a maximum value of 2.7% at a write beam fluence of 260 μ J cm⁻², and then decreases at higher fluences. We explain this phenomenon by an absorption saturation at high excitation.     

The Modeling of Velocity Enhancement in Polymer Flooding

In single-phase polymer flooding experiments it has repeatedly been observed that the average velocity of the polymer molecules is higher than the average velocity of the water molecules. This effect is incorporated in many conventional Enhanced Oil Recovery (EOR) simulators by the introduction of a constant velocity enhancement factor. In this paper we show that, in absence of dispersion, a constant enhancement factor in the mathematical model for two-phase polymer flow (Buckley--Leverett displacement) leads to ill-posedness of the model equations. We propose a saturation dependent enhancement factor, derived from a model based on percolation concepts, for which this problem does not occur.     

On outer automorphism groups of coxeter groups

Summary It is shown that the outer automorphism group of a Coxeter groupW of finite rank is finite if the Coxeter graph contains no infinite bonds. A key step in the proof is to show that if the group is irreducible andΠ ₁ andΠ ₂ any two bases of the root system ofW, thenΠ ₂ = ±ωΠ ₁ for some ω εW. The proof of this latter fact employs some properties of the dominance order on the root system introduced by Brink and Howlett. This article was processed by the author using the Springer-Verlag TEX PJour1g macro package 1991.     

Success and survival of operational research groups—A review

Operational Research groups were established in private and public sector organizations following on from their success supporting the military in the Second World War. In the early years their numbers grew rapidly but by the mid-1970s evidence started to accumulate that they were being viewed less favourably. Many organizations chose not to set up OR groups. Established groups were closed down or dispersed to operating units in organizations, particularly during the recessionary periods. In 1993 following on the closures of some major OR groups in the UK, the Operational Research Society decided to fund research to examine those factors influencing a group's success and survival. This review, which forms part of the research, first examines the history of OR groups in the UK and North America, arguing that in practice they were one of a number of internal organizational consultancies. As such they were judged by their competitive performance. Despite the intent of the founding fathers of OR many groups found their scope was limited to mainly tactical problems using analytical model based approaches although there were exceptions that were successful in making major contributions at the strategic level also. Within their chosen fields of activity however many groups flourished whilst some failed. This review presents a comprehensive list of influences on success and survival. They include changes in the external environment, together with shifts in managerial style and culture, organizational factors, and the OR group itself. The review concludes that, while OR groups can do much to protect themselves from closure, organizational changes within a hostile managerial culture demand a creative response that acknowledges new requirements. Areas where an OR group has greatest influence over its effectiveness include its leadership and personnel, project balance and management. In addition, to be successful OR groups need to positively develop and market their services in an increasingly competitive managerial climate.     

The Characterisation of the Products of Reduction of Chinkombe Ilmenite

The characterisation of iron-containing species in Chinkombe ilmenite and its reduction products was undertaken using Mössbauer Spectroscopic techniques. The ore was reduced by graphite in an inert atmosphere. The effects of such variables as quantity of reductant, temperature and preoxidation were investigated. The ore was completely reduced to alpha-iron and titanium dioxide with 20% carbon for a period of one hour at 1373 K. Chemical mechanisms are proposed for the reduction and oxidation of Chinkombe ilmenite. In the processing of ilmenite to obtain synthetic rutile, the ultimate desire is to separate the Fe phase from the TiO₂. Mössbauer Spectroscopy has unambiguously confirmed the desired transformation of the iron phase according to thermodynamic predictions. The information gained would be used to choose the conditions of the reduction process. The alpha-iron could be separated physically or chemically from the completely reduced product mass to obtain synthetic titanium dioxide suitable for the paint industry.