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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
981.
The dynamical algebra of theq-deformed harmonic oscillator is constructed. As a result, we find the free deformed Hamiltonian as well as the Hamiltonian of the deformed oscillator as a complicated, momentum dependent interaction Hamiltonian in terms of the usual canonical variables. Furthermore we construct a welldefined algebraSU q(1,1) with consistent conjugation properties and comultiplication. We obtain non lowest weight representations of this algebra. 相似文献
982.
Robert W. Baker Geoffrey R. Pocock Melvyn V. Sargent Edi Twiss 《Tetrahedron: Asymmetry》1993,4(12):2423-2426
Introduction of a 2-isopropoxycarbonyl or 2-NN-dimethylcarbamoyl group into homochiral 1-p-tolyl- or 1-t-butyl-sulfinylnaphthalenes, via directed metalation reaction, followed by ligand coupling reaction with 1-naphthylmagnesium bromide, furnished atropisomeric 1,1′-binaphthyls in 82–95% enantiomeric excess (e.e.). 相似文献
983.
984.
985.
986.
Chemical kinetics of benzonitrile nitration with mixed acid is investigated in the temperature range 283–299 K. Pseudo-first-order rate constants are evaluated by means of rate experiments on homogeneous reacting mixtures having large stoichiometric excesses of nitric acid. The second-order kinetic constants for nitronium ion attack to the aromatic substrate are derived on the basis of the assessed nitration mechanism. An activation energy of 604 ± 37 kJ mol?1 is calculated for this reaction step. © 1993 John Wiley & Sons, Inc. 相似文献
987.
R Ehrhardt 《The Journal of the Operational Research Society》1997,48(10):1013-1021
We consider a firm that manages its internal manufacturing operations according to a just-in-time (JIT) system but maintains an inventory of finished goods as a buffer against random demands from external customers. We formulate a model in which finished goods are replenished by a small fixed quantity each time period. In the interest of schedule stability, the size of the replenishment quantity must remain fixed for a predetermined interval of time periods. We analyse the single-interval problem in depth, showing how to compute a cost-minimising value of the replenishment quantity for a given interval length, and characterising the optimal cost, inventory levels and service as functions of the interval length and initial inventory. The model displays significant cost and service penalties for schedule stability. A dynamic version of the problem is also formulated, and shown to be convex in nature with relatively easily computed optima. 相似文献
988.
Convective heat transfer from an array of small, cylindrical bodies of arbitrary shape in an unbounded, two-dimensional domain is a singular perturbation problem involving an infinite logarithmic expansion in the small parameter ε, representing the order of magnitude of the size of the bodies. Using the method of matched asymptotic expansions, we formulate a hybrid asymptotic-numerical method to solve for the dimensionless, steady-state temperature. We assume that the velocity field of the fluid surrounding the bodies is arbitrary but known. From our asymptotic solution for an arbitrary velocity field, we present the results for two special cases: a uniform flow field and a simple shear flow field. We demonstrate the asymptotic results of the hybrid method through a number of examples and, in a particular case, we compare these results to an exact analytical solution. 相似文献
989.
A self-avoiding polygon (SAP) on a graph is an elementary cycle. Counting SAPs on the hypercubic lattice ℤ
d
withd≥2, is a well-known unsolved problem, which is studied both for its combinatorial and probabilistic interest and its connections
with statistical mechanics. Of course, polygons on ℤ
d
are defined up to a translation, and the relevant statistic is their perimeter.
A SAP on ℤ
d
is said to beconvex if its perimeter is “minimal”, that is, is exactly twice the sum of the side lengths of the smallest hyper-rectangle containing
it. In 1984, Delest and Viennot enumerated convex SAPs on the square lattice [6], but no result was available in a higher
dimension.
We present an elementar approach to enumerate convex SAPs in any dimension. We first obtain a new proof of Delest and Viennot's
result, which explains combinatorially the form of the generating function. We then compute the generating function for convex
SAPs on the cubic lattice. In a dimension larger than 3, the details of the calculations become very cumbersome. However,
our method suggests that the generating function for convex SAPs on ℤ
d
is always a quotient ofdifferentiably finite power series. 相似文献
990.
We study the expected delay in cyclic polling models with general ‘branching-type’ service disciplines. For this class of
models, which contains models with exhaustive and gated service as special cases, we obtain closed-form expressions for the
expected delay under standard heavy-traffic scalings. We identify a single parameter associated with the service discipline
at each queue, which we call the ‘exhaustiveness’. We show that the scaled expected delay figures depend on the service policies
at the queues only through the exhaustiveness of each of the service disciplines. This implies that the influence of different
service disciplines, but with the same exhaustiveness, on the expected delays at the queues becomes the same when the system
reaches saturation. This observation leads to a new classification of the service disciplines. In addition, we show monotonicity
of the scaled expected delays with respect to the exhaustiveness of the service disciplines. This induces a complete ordering
in terms of efficiency of the service disciplines. The results also lead to new rules for optimization of the system performance
with respect to the service disciplines at the queues. Further, the exact asymptotic results suggest simple expected waiting-time
approximations for polling models in heavy traffic. Numerical experiments show that the accuracy of the approximations is
excellent for practical heavy-traffic scenarios.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献