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951.
952.
G A van't Klooster F M Woutersen-van Nijnanten H J Kolker J Noordhoek A S van Miert 《Journal of chromatography. A》1992,579(1):158-164
Ethylmorphine N-demethylation is used as a marker pathway in studies of rat cytochrome P450 3A and 2C11 biotransformations. At present, microsomal activities are generally measured by a colorimetric determination of the formed formaldehyde. In the present study, a high-performance liquid chromatographic method of separating and quantifying both the N-demethylated (norethylmorphine) and the O-de-ethylated (morphine) metabolites is described. Either samples are extracted with ethyl acetate or proteins are precipitated with zinc sulphate-barium hydroxide. Separation is achieved on a CN reversed-phase column, using a mobile phase of phosphate buffer (pH 4.5)-acetonitrile (90:10, v/v). At a flow-rate of 1.5 ml/min, the analysis time is 30 min. The limit of detection (ultraviolet, 210 nm) for ethylmorphine and its metabolites is 0.5 micrograms/ml. 相似文献
953.
Muscarine, oxazole, thiazole, imidazole and peptide alkaloids and other miscellaneous alkaloids. 总被引:1,自引:0,他引:1
J R Lewis 《Natural product reports》1992,9(1):81-101
954.
D. J. Hartfiel 《Linear and Multilinear Algebra》1994,36(4):293-304
In this paper we consider the nonnegative matrix system ciA+uiB=ci+1 where the nonnegative matrix A is allowed to vary, within bounds. The cone control problem is to find a nonnegative matrix B such that if Ci is a nonnegative vector in a specified cone, then there is a nonnegative vector ui such that ci+1 is in that cone. We extend this problem to input control by finding a B such that the cone, generated by the rows of B, is as small as possible. Thus, the percent distribution of ∣uiB∣ through the states of the sustem by uiB is either constant or varies little. 相似文献
955.
956.
Applied Biochemistry and Biotechnology - In summary, it appears that the microbial reduction process is clearly not competitive with conventional SO2-reduction techniques when glucose (DE95 corn... 相似文献
957.
The authors study concentration profiles of solutes undergoingequilibrium absorption in the vicinity of a water well. Forthe case of a contamination event, the limit problem of vanishingwell radius, which is of self-similar nature, is analysed indetail. Existence, uniqueness, and qualitative properties ofsolutions of the corresponding ordinary differential equationsare shown. Some numerical examples are also presented. 相似文献
958.
Within the framework of a simple electrostatic model, as compared to recent experimental results, we here discuss the stability
of very weakly bound molecular negative ions. In contrast with the case of conventional valence anions, the excess electron
is then located in a very diffuse orbital and is mainly bound by electrostatic dipolar, quadrupolar, and polarization forces,
at large distances from the neutral molecular core. By fitting a single repulsion parameter of the model to the available
experimental data, it is possible to make quantitative predictions of the excess-electron binding energies in these species.
Critical values of the dipole moment, quadrupole moment or polarizability required for the observation of stable multipole-bound
negative ions are predicted and compared to available experimental data and ab initio calculations.
Received October 24, 2001; accepted for publication November 16, 2001 相似文献
959.
960.
Fluorescence line narrowing (FLN) spectroscopy was used to study the role of the polypeptide chain in influencing the spectrum of Zn-substituted cytochrome c (Zn cyt c) and metal-free cyt c (porphyrin cyt c). For both derivatives the spectra show characteristics of relaxed fluorescence from an inhomogeneously broadened sample. Zero phonon lines and phonon wings can be clearly distinguished, and vibrational frequencies of the ground and excited states were identified. The inhomogeneous distribution width for porphyrin cyt c is slightly wider than that of Zn cyt c and a second population of molecules was apparent in the porphyrin cyt c. The phonon coupling was greater for Zn cyt c than for porphyrin cyt c, which may be due to the extra coupling to the polypeptide chain by metal ligation.This work has been done in partial fulfillment of the requirements for the Doctor of Philosophy degree. 相似文献