首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   380296篇
  免费   4185篇
  国内免费   1192篇
化学   206209篇
晶体学   5561篇
力学   15967篇
综合类   8篇
数学   43546篇
物理学   114382篇
  2021年   2516篇
  2020年   2896篇
  2019年   2997篇
  2018年   3471篇
  2017年   3485篇
  2016年   5851篇
  2015年   4153篇
  2014年   5978篇
  2013年   16826篇
  2012年   13150篇
  2011年   16072篇
  2010年   10557篇
  2009年   10549篇
  2008年   14838篇
  2007年   14968篇
  2006年   14478篇
  2005年   13107篇
  2004年   11884篇
  2003年   10584篇
  2002年   10469篇
  2001年   11897篇
  2000年   9015篇
  1999年   7126篇
  1998年   5814篇
  1997年   5582篇
  1996年   5519篇
  1995年   5049篇
  1994年   4775篇
  1993年   4638篇
  1992年   5137篇
  1991年   5059篇
  1990年   4766篇
  1989年   4578篇
  1988年   4802篇
  1987年   4456篇
  1986年   4307篇
  1985年   6041篇
  1984年   6189篇
  1983年   5069篇
  1982年   5460篇
  1981年   5393篇
  1980年   5144篇
  1979年   5327篇
  1978年   5417篇
  1977年   5413篇
  1976年   5284篇
  1975年   5161篇
  1974年   5033篇
  1973年   5154篇
  1972年   3068篇
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
101.
For fairly high concentrations, the effective arsenic diffusioncoefficient is known to grow linearly with the concentration.In this paper, we consider the strongly enhanced diffusion ofarsenic by asymptotic methods, and extend the results of a previouspaper (King & Please, 1987) in three ways: we characterizean additional (low-concentration) region; we consider the influenceof the initial data; and we consider the case of constant surfaceconcentration.  相似文献   
102.
103.
Optics and Spectroscopy - The fluorescence of the nematic liquid crystal n-butyl-n′-methoxyazoxybenzene (BMAOB) in the form of a layer and in porous glasses with pores of different diameter...  相似文献   
104.
The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (Tg's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the Tg values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003  相似文献   
105.
R.J Hand 《Journal of Non》2003,315(3):276-287
Glass may be strengthened by epoxy coatings although the strengthening mechanisms remain unclear. Possible strengthening mechanisms are reviewed and are used to analyse strength data for both a solvent based and a water based coating system. The coatings either fill (solvent based coatings), or partially fill (water based coatings) surface cracks and it is shown that closure stresses arising from the thermal expansion mismatch of the coating within these cracks can account for the observed degrees of strengthening. It is also demonstrated that other suggested mechanisms such as flaw healing cannot fully account for the observed degree of strengthening.  相似文献   
106.
We investigate Banach spaces possessing (or not possessing) the approximation properties AP s, 0 < s ≤ 1, in connection with the following known question in the geometric theory of operators: under which conditions on Banach spaces X and Y and on positive numbers r and p does the p-nuclearity of the second adjoint of a continuous operator T from X to Y imply the p-nuclearity of T? Actually, we give necessary and sufficient conditions under which this question is answered affirmatively. In addition, the corresponding counterexamples are obtained in the maximally strong form. For instance, it is shown (and this statement is a significant strengthening of the previous results of that sort) that there exists a pair of separable Banach spaces Z and W such that the spaces Z ** and W have Schauder bases, while for every p, 1 ≤ p < 2, there is a non-p-nuclear operator from W to Z with a p-nuclear second adjoint. Earlier, in similar examples, the corresponding spaces did not possess even the Grothendieck approximation property. The technique developed in this paper does not allow us to treat the case p > 2. That case will be studied in a forthcoming paper of the author. Bibliography: 11 titles.  相似文献   
107.
The very weak water vapor absorption spectrum has been investigated between 9520 and 10 010 cm−1 by intracavity laser absorption spectroscopy based on a vertical external cavity surface emitting laser. The rovibrational assignment performed on the basis of the ab initio calculations of Schwenke and Partridge has allowed for determining 156 new energy levels belonging to a total of 13 vibrational states. The assignment process is detailed. The results are compared with the available databases and discussed in regard of recent investigations by Fourier transform spectroscopy.  相似文献   
108.
We prove that the sufficient conditions for the asymptotic stability of impulsive systems obtained by Gurgula and Perestyuk are also necessary conditions.  相似文献   
109.
The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by 1H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (Mw) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (Mw/Mn)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with Mw = 12,100 and Mw/Mn = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in Mw of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003  相似文献   
110.
We studied the low speed fracture regime (10−4-10−9 m s−1) in different glassy materials (soda-lime glass, glass ceramics) with variable but controlled length scale of heterogeneity. The chosen mechanical system enabled us to work in pure mode I (tensile) and at a fixed load on double cleavage drilled compression specimen. The internal residual stresses of studied samples were carefully relaxed by appropriate thermal treatment. By means of optical and atomic force microscopy techniques fracture surfaces have been examined. We have shown for the first time that the crack front line underwent an out-of-plane oscillating behavior as a result of a reproducible sequence of instabilities. The wavelength of such a phenomenon is in the micrometer range and its amplitude in the nanometer range. These features were observed for different glassy materials providing that a typical length scale characterizing internal heterogeneities was lower than a threshold limit estimated to few nanometers. This effect is the first clear experimental evidence of crack path instabilities in the low speed regime in a uniaxial loading experiment. This phenomenon has been interpreted by referring to the stability criterion for a straight crack propagation as presented by Adda-Bedia et al. [Phys. Rev. Lett. 76 (1996) 1497].  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号