Étude du comportement viscoélastique du polycarbonate de bisphénol-A partiellement cristallisé

Résumé On étudie dans cet article un procédé pour obtenir des polycarbonates de bisphénol-A de divers taux de cristallinité. On détermine la variation thermique du module-(10 sec) et la résistance au choc des ces polymères. On étudie également l'influence du recuit sur les propriétés mécaniques.

---

Summary This paper describes a procedure to obtain polycarbonate of bisphenol A samples of various degrees of crystallinity. The modulus-temperature curves and the impact strength of these materials are investigated. The results show the importance of the annealing procedure on the mechanical properties of these systems.

     

Integrated-plane photoelastic method—Application of photoelastic isodynes

It has been shown by Pindera and Mazurkiewicz that a new type of scattered-light modulation in the plane of a two-dimensional photoelastic object can be obtained when the stationary integrated photoelastic method developed by Pindera and Straka is applied in a scanning mode and when the transfer function of the photoelastic system satisfies certain conditions. The new type of light modulation, called field of isodynes by the authors, carries information on stress components normal to the direction of propagation of primary beam, and on corresponding total-force component. The points where this stress component is equal to zero can be easily determined. The classical scattered-light modulation along a chosen line represents a cross section of a corresponding isodynes field. It is shown that these features of the method of isodynes make it possible to easily determine the distribution and values of normal stress components at any arbitrary rectilinear cross section, and to check immediately the accuracy of measurements. The experimental determination of contact stresses and contact regions using the method of isodynes is especially simple and elegant.     

Potentiostat for use in electro-chemical experiments

Summary In many electro-chemical experiments it is desirable that one of the current-carrying electrodes of an electrolytic bath has a constant potential. This may be realized by manual control of the bath current. Owing to the sudden and unpredictable potential fluctuations of the electrode concerned, this is very difficult and even impossible in some special cases, e.g. when passivating an Fe-electrode in aqueous H₂SO₄. In addition there may be a considerable time-lag between the potential and the current fluctuations. The different types of potentiostats described so far seem to have too large a time-lag or/and too low a sensitivity for this purpose. The authors describe a potentiostat with proportional and integrating properties resulting in a stabilization of the potential within 1/2 mV in favourable sections of the potential current characteristic. Even with an electrode with a very steep potential current characteristic (e.g. the above mentioned Fe-electrode) the ripple never exceeds a few mV. The bath current, the maximum value of which is 30 mA, is the differential current of two electronic tubes. This type of circuit offers various advantages.     

Measurements on a molecular beam apparatus for mass spectrometric study of reactions in flames

Summary The formation of a molecular beam in sampling 1 torr to 1 atm. gases (Ar or H₂) is studied for three diameters of the sampling orifice. To modulate the beam, use is made of a mechanical chopper placed very near the sampling orifice. This enables us to measure the scattering of the beam by collisions between beam molecules. From our measurements it follows that these collisions are very important for >0.020 mm at an initial pressure of 1 atm. We discuss the consequences of our results for mass spectrometric studies of flames.     

On a Model of a Currency Exchange Rate – Local Stability and Periodic Solutions

A delay differential equation is presented which models how the behavior of traders influences the short time price movements of an asset. Sensitivity to price changes is measured by a parameter a. There is a single equilibrium solution, which is non-hyperbolic for all a>0. We prove that for a< 1 the equilibrium is asymptotically stable, and that for a>1 a 2-dimensional global center-unstable manifold connects the equilibrium to a periodic orbit. Its birth at a=1 is not of Hopf type and seems part of a Takens–Bogdanov scenario.     

A numerical investigation of transient detonation in granulated material

A two-phase model based upon principles of continuum mixture theory is numerically solved to predict the evolution of detonation in a granulated reactive material. Shock to detonation transition (SDT) is considered whereby combustion is initiated due to compression of the material by a moving piston. In particular, this study demonstrates the existence of a SDT event which gives rise to a steady two-phase Chapman-Jouguet (CJ) detonation structure consisting of a single lead shock in the gas and an unshocked solid; this structure has previously been independently predicted by a steady-state theory. The unsteady model equations, which constitute a non-strictly hyperbolic system, are numerically solved using a modern high-resolution method. The numerical method is based on Godunov's method, and utilizes an approximate solution for the two-phase Riemann problem. Comparisons are made between numerical predictions and known theoretical results for 1) an inert two-phase shock tube problem, 2) an inert compaction wave structure, and 3) a reactive two-phase detonation structure; in all cases, good agreement exists. Received 4 August 1995 / Accepted 17 February 1996     

Schnelle Berechnung der mittleren Temperaturdifferenz in luftgekühlten Kreuzstromwärmeaustauschern

Zusammenfassung Es wird eine bekannte, explizite Näherungsgleichung mit zehn neuen Sätzen von jeweils sechzehn empirischen Konstanten vorgestellt zur schnellen Berechnung der mittleren Temperaturdifferenz von nunmehr insgesamt achtzehn Kreuzstromführungen. Die mittlere Temperaturdifferenz wird aus der dimensionslosen Abkühlung des Prozeßstromes und der Zahl der Übergangseinheiten auf der Luftseite berechnet.

---

Fast calculation of mean temperature difference in air-cooled cross-flow heat exchangers

A known approximate explicit equation together with ten new sets of sixteen empirical coefficients is presented for the fast calculation of the mean temperature difference of by now all together eighteen crossflow arrangements. The mean temperature difference is calculated from the effectiveness of the process stream and the number of transfer units on the air side.

---

Bezeichnungen b_{i, K} Konstanten in Gl. (6) - c_p spezifische Wärmekapazität der Luft bei Konstanten Druck - Wärmekapazitätsstrom der Luft - F Austauschfläche, Fläche - f mittlerer absoluter Fehler von r - i, k Exponenten und Summenzähler in Gl. (6) - K Wärmedurchgangskoeffizient - m, n Maximalwerte von i bzw. k - p, q dimensionslose Temperaturänderungen beider Fluide, definiert durch Gln. (2) und (3) - r dimensionslose mittlere Temperaturdifferenz, definiert durch Gl. (1) - s Zahl der Übergangseinheiten (NTU) auf der Luftseite, definiert durch Gl. (4) - T Temperatur des Prozeßstroms - w Anströmgeschwindigkeit der Luft - z Zahl der Punkte - endliche Differenz - Dichte der Luft Indices I eine Rohrreihe - 1, 2 Eintritt, Austritt - a Anströmquerschnitt - Ge Gegenstrom - Gl Gleichstrom - M Mittelwert - max Maximalwert (nicht Mittelwert) Herrn Prof. em. Dr.-Ing. Dr.-Ing. E. h. H. Hausen zur Vollendung seines 85. Lebensjahres     

A theory of finite elastic consolidation

Presented in this paper is a general theory describing the consolidation of a porous elastic soil. The formulation allows for the occurrence of finite geometry changes and finite elastic strains during the consolidation process. The governing equations have been cast in a rate form and the laws which determine deformation and pore fluid flow, i.e. Hooke's law and Darcy's law, are presented in a frame indifferent manner. A numerical technique is described that provides an approximate solution to the governing equations. The theory and the solution technique are illustrated by several examples of practical interest.