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61.
CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献
62.
Tomoyuki Sekine Kunimitsu Uchinokura Mitsuru Izumi Etsuyuki Matsuura 《Solid State Communications》1984,52(4):379-383
The phase transition of the linear chain compound (NbSe4)3I was studied by Raman scattering. At 78 K three new peaks were observed at 73 cm?1, 205 cm?1 and 261 cm?1. The totally symmetric Raman peak at 73 cm?1 shows anomalous temperature dependence. The frequency decreases with increasing temperature, and at high temperatures an anticrossing occurs with another peak observed at about 58 cm?1. The Raman intensity decreases and the linewidth broadens remarkably as the temperature increases. These properties allow us to assign this peak to a soft phonon. This fact indicates clearly the existence of a structural phase transition of a displacive type below room temperature. 相似文献
63.
64.
Ohne Zusammenfassung 相似文献
65.
Shosuke Yamamura Masatoki Ito Masatake Niwa Izumi Hasegawa Shigeru Ohba Yoshihiko Saito 《Tetrahedron letters》1981,22(8):739-740
Tricyclosolidagolactone has been isolated from the leaves of L., and its structure also been elucidated on the basis of its spectral data coupled with an X-ray crystallographic analysis of the corresponding trihydroxy compound produced on LiAlH4 reduction. 相似文献
66.
Izumi M Tsuruta O Kajihara Y Yazawa S Yuasa H Hashimoto H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(10):3032-3038
5-Thio-L-fucose-containing trisaccharide H-type II was synthesized. The 3',4'-O-isopropylidene-2-azido-2-deoxylactoside derivative, which was prepared from lactose by azidonitration of lactal, was used as a starting material. By regio- and stereoselective 5-thio-L-fucosylation of the 6,6'-dibenzoate 5 with 5-thiofucosyl trichloroacetimidate 6 and subsequent deprotection gave the 5-thio-L-fucose-containing H-type II 1. Conformational analysis of the 5-thio-L-fucose-containing H-type II and the native H-type II was carried out through NOESY experiments. The observed NOE values between N-acetylglucosamine and galactose, and galactose and fucose were same for these two trisaccharides. However, NOE values between fucose and N-acetylglucosamine were significantly different. Binding of the 5-thio-L-fucose-containing H-type II to lectins and antibodies were in some case stronger and in some case weaker than those of the native trisaccharide. 相似文献
67.
Masaki Izumi Sergey Neshveyev Lars Tuset 《Communications in Mathematical Physics》2006,262(2):505-531
We prove that for any non-trivial product-type action α of SUq(n) (0<q<1) on an ITPFI factor N, the relative commutant is isomorphic to the algebra L∞() of bounded measurable functions on the quantum flag manifold . This is equivalent to the computation of the Poisson boundary of the dual discrete quantum group . The proof relies on a connection between the Poisson integral and the Berezin transform. Our main technical result says
that a sequence of Berezin transforms defined by a random walk on the dominant weights of SU(n) converges to the identity on the quantum flag manifold.
Supported by JSPS.
Partially supported by the Norwegian Research Council.
Supported by the SUP-program of the Norwegian Research Council. 相似文献
68.
Maeyama T Yagi I Murota Y Fujii A Mikami N 《The journal of physical chemistry. A》2006,110(51):13712-13716
Vibrational spectra of microsolvated benzonitrile radical anions (C6H5CN- -S; S = H2O and CH3OH) were measured by probing the electron detachment efficiency in the 3 microm region, representing resonance bands of autodetachment via OH stretching vibrations of the solvent molecules. The hydrogen-bonded OH band for both the cluster anions exhibited a large shift to the lower energy side with approximately 300 cm-1 compared to those for the corresponding neutral clusters. The solvent molecules are bound collinearly to the edge of the CN group of the benzonitrile anion in the cluster structures optimized with the density functional theory, in which the simulated vibrational energies are in good agreement with the observed band positions. Natural population analyses were performed for a qualitative implication in changes of solvent orientation upon electron attachment. Asymmetric band shapes depending on the vibrational modes are discussed with respect to dynamics of the autodetachment process from a theoretical aspect incorporated with density functional calculations. 相似文献
69.
Izumi T Naitou Y Shimbo Y Takanishi Y Takezoe H Watanabe J 《The journal of physical chemistry. B》2006,110(47):23911-23919
The mesomorphic behavior and phase structure were examined in the mixture of two kinds of dimeric compounds, alpha,omega-bis(4-alkoxyanilinebenzylidene-4'-carbonyloxy)pentane (mOAM5AMOm), by optical microscopy, X-ray diffraction, polarization switching, and second-harmonic generation measurements. One compound is 4OAM5AMO4 with a short terminal alkyl chain that forms a single-layer smectic phase (SmCAs) with a random mixing of spacer and tail groups. Another compound is 16OAM5AMO16 with a long terminal alkyl chain that forms a chiral, anticlinic, and antiferroelectric bilayer phase (SmCAb) with the bent molecules tilted to the bilayer. By mixing these two compounds, the SmCAs phase of 4OAM5AMO4 is easily destabilized, leading to the wide content region of the bilayer phases. In the bilayer regime, three other smectic phases are newly induced. Two of them are antiferroelectric and ferroelectric phases in which the molecules lie perpendicularly with respect to the layer. The other shows no polar response to an external electric field and behaves like a smectic A. The new appearance of these bilayer phases is discussed as a mixing effect of long and short tail groups. 相似文献
70.
We numerically study the performance of the displacement based quantum receiver for the discrimination of weak 3- and 4-phase-shift keyed (PSK) coherent state signals. We show that due to the nontrivial asymmetry of the receiver structure, optimization of the prior probability increases the mutual information and achieves sub-shot-noise limit discrimination. Moreover, we estimate the cutoff rate for a 4-PSK signal and confirm that the prior probability optimization shortens the code length for a given decoding error criterion. Such consideration for the asymmetric channel matrix is essential in a study of the compassable quantum receiver. 相似文献