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21.
22.
GRIGORII YA. FRAIKIN MARINA G. STRAKHOVSKAYA EMMA V. IVANOVA REW B. RUBIN 《Photochemistry and photobiology》1989,49(4):475-477
Near-UV (337 nm) photoactivation of the 5-hydroxytryptophan decarboxylation reaction producing serotonin has been observed. The photoactivation effect was investigated as a function of fluence rate and fluence, and pH. Photoactivation of decarboxylase activity was found to occur at nearly neutral pH values (low activity of the enzyme in the dark). The findings indicate that the effect of light is similar to a pH shift toward the acid region, which causes the enzyme conversion from the inactive to active form. Pyridoxal phosphate, the decarboxylase cofactor, in the form of an adduct absorbing at 330-340 nm, is suggested as a candidate for the role of the photoactive chromophore of decarboxylase. 相似文献
23.
L. Yu Izotova K. M. Beketov B. T. Ibragimov A. É. Érmonov M. P. Irismetov K. D. Praliev B. Zh. Dzhiembaev 《Chemistry of Natural Compounds》1996,32(3):348-351
The crystal structure of the complex of 18-dehydroglycyrrhetic acid (GLD) with DMSO (C30H41O4·C2H6OS) has been determined by x-ray structural analysis. Syntex P21 diffractometer, CuK radiation, 1309 reflections, R = 0.080. A conformational analysis has been made of the GLD molecule in comparison with that of glycyrrhetic acid. The conformations of rings A and B in the GLD molecule do not differ from the conformations of the corresponding rings of glycyrrhetic acid. Differences arise in ringsC,D, andE because of the presence of the double bond between the C18 and C19 atoms.Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 362–366, May-June, 1996. Original article submitted Novemher 11, 1995. 相似文献
24.
ÜMMÜHAN OCAK HALIT KANTEKIN YAŞAR GÖK H. BASIR ŞENTÜRK 《Journal of inclusion phenomena and macrocyclic chemistry》2006,55(1-2):87-91
The selective liquid–liquid extraction of various transition metal cations from the aqueous phase to the organic phase was carried out using a 14-membered N2O2S2-macrobicycle. Metal picrates such as Pb2+, Co2+, Zn2+, Ni2+,Cu2+ and Cd2+ were used in this extraction studies. It was found that the ligand showed moderate selectivity towards Pb2+ only among the other metals. The extraction constant (log K
ex) was determined to be 13.8 for Pb2+ complex. 相似文献
25.
B. T. Ibragimov L. Yu. Izotova D. M. Ashurov E. Weber S. A. Talipov 《Journal of Structural Chemistry》2005,46(1):S109-S115
From acetophenone solution with a small amount of water, a widely used clathrate forming compound, trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid (DED), crystallizes either in the form of a clathrate with acetophenone (25°C) or in the form of hydrate (5°C). The clathrate of DED with acetophenone is triclinic, space group P-1 with the unit cell parameters: a = 8.5002(2) Å, b = 12.5247(8) Å, c = 12.8251(8) Å; α = 62.876(2)°, β = 80.454(2)°, γ = 89.789(2)°; V = 1194.4(1) Å3, Z = 2; the molar ratio DED:acetophenone is 2:3. The clathrate is of channel type; the system of mutually intersecting channels propagates in [100] and [01–1] directions in the structure. The guest molecules of acetophenone are included in the channels and do not form any H-bonds with the host molecules of DED. The hydrate of DED crystallizes in monoclinic system, in space group C2/c, with the unit cell parameters: a = 31.770(6) Å, b = 8.503(2) Å, c = 12.888(3) Å; β = 104.26(3)°; V = 3374(1) Å3, Z = 8; the molar ratio DED:water is 1:3. One of two carboxylic groups of the molecule of DED is deprotonated and the proton is incorporated into the hydroxonium ion H3O+. The crystal structure of the hydrate of DED is of layer type with well distinguished hydrophobic and hydrophilic parts. 相似文献
26.
B. G. Udarov É. N. Manukov O. G. Vyglazov V. A. Chuiko L. V. Izotova 《Chemistry of Natural Compounds》1987,22(4):398-403
The retention indices of synthesized alkyl derivatives of carane and of cycloheptane in capillary columns with tricresyl phosphate and squalane at 70°C have been determined. The influence of the structure of the hydrocarbons studied on the values of their retention parameters is considered. An estimate is given of the nature of the interrelationship between the physical properties of these hydrocarbons and their retention indices on a nonpolar stationary phase.Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 427–432, July–August, 1986. 相似文献
27.
28.
Babkin O. E. Babkina L. A. Vasilevskaya T. N. Yastrebov S. G. Andreeva V. D. Kozyrev S. V. Drinberg A. S. Izotova M. V. Aikasheva O. S. 《Physics of the Solid State》2018,60(12):2663-2667
Physics of the Solid State - X-ray diffraction patterns of a photocurable epoxy acryl-based polymer composite with addition of ZnO nanocrystals are analyzed. We recover the size distribution... 相似文献
29.
L. Yu. Izotova S. A. Talipov B. T. Ibragimov B. Bekbulatova R. Islamov U. N. Zainutdinov 《Chemistry of Natural Compounds》2000,36(2):181-184
The molecular structures of two diterpene lagochilins, triacetyllagochilin and lagochilin tetraformate, are determinated by x-ray structure analysis.Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 142–144, March–April, 2000. 相似文献
30.
E. A. PAZYUK A. V. STOLYAROV V. I. PUPYSHEV N. F. STEPANOV S. YA. UMANSKII A. A. BUCHACHENKO 《Molecular physics》2013,111(2):91-101
The valence electronic states of the iodine molecule are analysed by means of a simple atoms-in-molecule model which accounts for the lowest 2P states of iodine atoms and approximates the spin-orbit interaction by its atomic part. For this model, an inverse problem is solved, i.e. non-relativistic potential energy curves and diabatic couplings are determined by a least-squares fit to known relativistic potential energy curves. The resulting adiabatic wave functions are used to calculate the electronic matrix elements responsible for natural, hyperfine and magnetic predissociation of the iodine molecule in the B0+ u: state. The results are in reasonable agreement with experimental data, being stable enough with respect to the variation of input relativistic potentials. They also indicate the importance of diabatic couplings between the non-relativistic states of the same symmetry. 相似文献