全文获取类型
收费全文 | 1184篇 |
免费 | 42篇 |
国内免费 | 4篇 |
专业分类
化学 | 712篇 |
晶体学 | 30篇 |
力学 | 22篇 |
数学 | 237篇 |
物理学 | 229篇 |
出版年
2023年 | 9篇 |
2022年 | 60篇 |
2021年 | 50篇 |
2020年 | 25篇 |
2019年 | 23篇 |
2018年 | 22篇 |
2017年 | 19篇 |
2016年 | 44篇 |
2015年 | 32篇 |
2014年 | 46篇 |
2013年 | 60篇 |
2012年 | 63篇 |
2011年 | 56篇 |
2010年 | 46篇 |
2009年 | 55篇 |
2008年 | 71篇 |
2007年 | 49篇 |
2006年 | 43篇 |
2005年 | 52篇 |
2004年 | 35篇 |
2003年 | 23篇 |
2002年 | 25篇 |
2001年 | 17篇 |
2000年 | 26篇 |
1999年 | 20篇 |
1998年 | 15篇 |
1997年 | 6篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 11篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 8篇 |
1989年 | 10篇 |
1988年 | 13篇 |
1987年 | 11篇 |
1986年 | 16篇 |
1985年 | 10篇 |
1984年 | 19篇 |
1983年 | 9篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 11篇 |
1979年 | 4篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1974年 | 4篇 |
1937年 | 3篇 |
1873年 | 6篇 |
排序方式: 共有1230条查询结果,搜索用时 0 毫秒
31.
The Effect of the Modification of Carbon Spheres with ZnCl2 on the Adsorption Properties towards CO2
Iwona Peech Piotr Staciwa Daniel Sibera Ewelina Kusiak-Nejman Antoni W. Morawski Joanna Kapica-Kozar Urszula Narkiewicz 《Molecules (Basel, Switzerland)》2022,27(4)
Zinc chloride and potassium oxalate are often applied as activating agents for carbon materials. In this work, we present the preparation of ZnO/carbon spheres composites using resorcinol-formaldehyde resin as a carbon source in a solvothermal reactor heated with microwaves. Zinc chloride as a zinc oxide source and potassium oxalate as an activating agent were applied. The effect of their addition and preparation conditions on the adsorption properties towards carbon dioxide at 0 °C and 25 °C were investigated. Additionally, for all tested sorbents, the CO2 sorption tests at 40 °C, carried out utilizing a thermobalance, confirmed the trend of sorption capacity measured at 0 and 25 °C. Furthermore, the sample activated using potassium oxalate and modified using zinc chloride (a carbon-to-zinc ratio equal to 10:1) displayed not only a high CO2 adsorption capacity (2.69 mmol CO2/g at 40 °C) but also exhibited a stable performance during the consecutive multicycle adsorption–desorption process. 相似文献
32.
33.
The heat capacity at constant pressure of CuGe2P3 is measured in the temperature range from 180 to 550 K. Standard enthalpies and entropies relative to 298.15 K are calculated from the heat capacity data. The Debye temperature in the high-temperature limit is estimated to be about 710 K. 相似文献
34.
Florin Radu Alexei Nefedov Johannes GrabisGregor Nowak Andre BergmannHartmut Zabel 《Journal of magnetism and magnetic materials》2006
We have used soft X-ray resonant magnetic scattering (XRMS) to search for the presence of an effective ferromagnetic moment belonging to the antiferromagnetic (AF) layer which is in close contact with a ferromagnetic (F) layer. Taking advantage of the element specificity of the XRMS technique, we have measured hysteresis loops of both Fe and CoO layers of a CoO(40 Å)/Fe (150 Å) exchange bias bilayer. From these measurements we have concluded that the proximity of the F layer induces a magnetic moment in the AF layer. The F moment of the AF layer has two components: one is frozen and does not follow the applied magnetic field and the other one follows in phase the ferromagnetic magnetization of the F layer. The temperature dependence of the F components belonging to the AF layer is shown and discussed. 相似文献
35.
Werner-Georg Nowak 《Monatshefte für Mathematik》1979,87(4):297-307
In this paper we consider lattice points in domains bounded by algebraic curves of the formx
n+yn=Rn fulfilling the additional condition
where and are fixed positive real numbers. The number of these lattice points is estimated for largeR and it appears that for rational or badly approximable and the error term in the final result can be made smaller (at least forn3) than it is best possible when counting the lattice points without the additional condition indicated above. 相似文献
36.
The hysteresis in Ni/Pb multilayers with layer thickness of 1.7, 5.5, 9.4 and 24.8 nm have been examined at low and room temperatures. The Stoner-Wohlfarth model, modified by the introduction of a constant internal field, well describes the shape of experimental hysteresis loops. The two components of internal field and anisotropy constant are fit to an individual loop. The transversal component of the internal field is related to a dispersion of local magnetization directions and determines a deviation of the rotation process from the Stoner-Wohlfarth model. At room temperature, the transversal component of the internal field for Ni/Pb multilayers is about 1000 Oe and is much greater than the effective anisotropy field and, as a result, the directions of magnetization rotate smoothly under the influence of resultant field. At low temperature, the longitudal component of the internal field is of the order of 1000 Oe and determines the incoherent rotations. 相似文献
37.
38.
Katarzyna Paradowska Micha Wolniak Maciej Pisklak Jan A. Gliski Matthew H. Davey Iwona Wawer 《Solid state nuclear magnetic resonance》2008,34(4):202-209
Oxindole alkaloids, isolated from the bark of Uncaria tomentosa [Willd. ex Schult.] Rubiaceae, are considered to be responsible for the biological activity of this herb. Five pentacyclic and two tetracyclic alkaloids were studied by solid-state NMR and theoretical GIAO DFT methods. The 13C and 15N CPMAS NMR spectra were recorded for mitraphylline, isomitraphylline, pteropodine (uncarine C), isopteropodine (uncarine E), speciophylline (uncarine D), rhynchophylline and isorhynchophylline. Theoretical GIAO DFT calculations of shielding constants provide arguments for identification of asymmetric centers and proper assignment of NMR spectra. These alkaloids are 7R/7S and 20R/20S stereoisomeric pairs. Based on the 13C CP MAS chemical shifts the 7S alkaloids (δ C3 70–71 ppm) can be easily and conveniently distinguished from 7R (δC3 74.5–74.9 ppm), also 20R (δC20 41.3–41.7 ppm) from the 20S (δC20 36.3–38.3 ppm). The epiallo-type isomer (3R, 20S) of speciophylline is characterized by a larger 15N MAS chemical shift of N4 (64.6 ppm) than the allo-type (3S, 20S) of isopteropodine (δN4 53.3 ppm). 15N MAS chemical shifts of N1–H in pentacyclic alkaloids are within 131.9–140.4 ppm. 相似文献
39.
Summary We provide a general asymptotic formula which permits applications to sums like <InlineEquation ID=IE"1"><EquationSource Format="TEX"><![CDATA[<InlineEquation
ID=IE"2"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"3"><EquationSource Format="TEX"><![CDATA[<InlineEquation
ID=IE"4"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"5"><EquationSource Format="TEX"><![CDATA[<InlineEquation
ID=IE"6"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"7"><EquationSource Format="TEX"><![CDATA[<InlineEquation
ID=IE"8"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"9"><EquationSource Format="TEX"><![CDATA[$]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>$]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>
\sum_{x< n\le x+y} \big(d(n)\big)^2, \quad \sum_{x< n\le x+y} d(n^3),\quad \sum_{x< n\le x+y}\big(r(n)\big)^2, \quad \sum_{x<
n\le x+y}r(n^3), $$ where $d(n)$ and $r(n)$ are the usual arithmetic functions (number of divisors, sums of two squares),
and $y$ is small compared to~$x$. 相似文献
40.
Piotr W. Nowak 《Journal of Functional Analysis》2007,243(1):323-344
We introduce a quasi-isometry invariant related to Property A and explore its connections to various other invariants of finitely generated groups. This allows to establish a direct relation between asymptotic dimension on one hand and isoperimetry and random walks on the other. We apply these results to reprove sharp estimates on isoperimetric profiles of some groups and to answer some questions in dimension theory. 相似文献