全文获取类型
收费全文 | 441篇 |
免费 | 26篇 |
专业分类
化学 | 389篇 |
晶体学 | 3篇 |
力学 | 7篇 |
数学 | 39篇 |
物理学 | 29篇 |
出版年
2023年 | 5篇 |
2022年 | 34篇 |
2021年 | 22篇 |
2020年 | 15篇 |
2019年 | 14篇 |
2018年 | 10篇 |
2017年 | 15篇 |
2016年 | 22篇 |
2015年 | 13篇 |
2014年 | 25篇 |
2013年 | 29篇 |
2012年 | 29篇 |
2011年 | 32篇 |
2010年 | 17篇 |
2009年 | 23篇 |
2008年 | 34篇 |
2007年 | 12篇 |
2006年 | 14篇 |
2005年 | 28篇 |
2004年 | 20篇 |
2003年 | 12篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 1篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1985年 | 1篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1974年 | 3篇 |
1943年 | 1篇 |
排序方式: 共有467条查询结果,搜索用时 15 毫秒
21.
22.
Iwona Kwiecień Grażyna Adamus Marek Kowalczuk 《Rapid communications in mass spectrometry : RCM》2012,26(23):2673-2682
23.
Iwona E. Głowacka Dorota G. Piotrowska Andrzej E. Wróblewski Aleksandra Trocha 《Tetrahedron: Asymmetry》2017,28(11):1602-1607
A simple and efficient synthetic strategy to all four enantiomerically pure diethyl 1,2-di(N-Boc-amino)propylphosphonates has been elaborated starting from the corresponding N-[(R)-(1-phenylethyl)]aziridine-(2S)- and N-[(S)-(1-phenylethyl)]aziridine-(2R)-carboxaldehydes, employing a one-pot three-components Kabachnik-Fields reaction followed by the hydrogenolytic removal of the chiral auxiliary and aziridine ring opening with simultaneous protection of the amino groups as the N-Boc derivatives. 相似文献
24.
25.
This paper presents a comparison of certain direct algorithms for computing the Moore-Penrose inverse, for matrices of full column rank, from the point of view of numerical stability. It is proved that the algorithm using Householder QR decomposition, implemented in floating point arithmetic, is forward stable but only conditionally mixed forward-backward stable. A similar result holds also for the Classical Gram-Schmidt algorithm with reorthogonalization (CGS2). This algorithm was developed and analyzed by Abdelmalek (BIT, 11(4):354–367, 1971) and its detailed error analysis was given in Giraud et al. (Numer. Math. 101(1):87–100, 2005). 相似文献
26.
In a route towards enantiomerically enriched 1-(β-hydroxypropyl)indoles, which are potentially useful building blocks for high value-added chemicals synthesis, a kinetic resolution approach by means of lipase-catalyzed enantioselective acylation as well as hydrolysis/methanolysis has been elaborated for the first time. The enzymatic resolution of chiral N-substituted indole-based sec-alcohols was successfully accomplished, yielding both enantiomeric forms of the employed derivatives with up to >99% enantiomeric purity via an enantioselective transesterification under mild reaction conditions. The most selective resolutions were obtained using fungal (CAL-B and TLL) and bacterial (PFL and BCL) lipases and vinyl acetate as the acyl?group donor. The synthetic protocol described herein is very simple, user-friendly and efficient, thus paving the way for future access towards more complex compounds of this type. The absolute configurations of novel enantiomeric derivatives, and thus stereoselectivity of the described enzymatic reactions were confirmed by application of CDA-based NMR methodology and single-crystal X-ray diffraction analysis. 相似文献
27.
28.
Prof. Dr. Antoni W. Morawski Dr. Ewelina Kusiak-Nejman Dr. Iwona Pełech Katarzyna Ćmielewska Dr. Daniel Sibera Piotr Staciwa Dr. Agnieszka Wanag Marcin Gano Dr. Ewa Ekiert Dr. Joanna Kapica-Kozar Kordian Witkowski Prof. Dr. Urszula Narkiewicz 《ChemistryOpen》2022,11(4):e202100262
A new approach to hydrogen production from water is described. This simple method is based on carbon dioxide-mediated water decomposition under UV radiation. The water contained dissolved sodium hydroxide, and the solution was saturated with gaseous carbon dioxide. During saturation, the pH decreased from about 11.5 to 7–8. The formed bicarbonate and carbonate ions acted as scavengers for hydroxyl radicals, preventing the recombination of hydroxyl and hydrogen radicals and prioritizing hydrogen gas formation. In the presented method, not yet reported in the literature, hydrogen production is combined with carbon dioxide. For the best system with alkaline water (0.2 m NaOH) saturated with CO2 under UV-C, the hydrogen production amounted to 0.6 μmol h−1 during 24 h of radiation. 相似文献
29.
Dorota G. Piotrowska Iwona E. Głowacka 《Phosphorus, sulfur, and silicon and the related elements》2014,189(7-8):1237-1253
AbstractEnantiomerically pure orthogonally protected dimethyl 1-aminophosphonates (2R,5R,6R,1′R)- and (2R,5R,6R,1′S)-10, phosphonate analogs of 4-hydroxythreonine, were prepared employing the three-component reaction between trimethyl phosphite, (2R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde (Ley’s aldehyde), and benzhydrylamine. Since both aminophosphonates 10 exist in a chloroform solution as single rotamers, the absolute configurations at C1′ were unequivocally established based on 1H and 13C NMR spectral data. Studies on stereochemistry of the addition of trialkyl phosphites showed that in chloroform in all cases the nucleophile preferentially attacks the si-face of the C?N bond, while in alcohols the 1,2-stereoinduction is negligible, and sense of chirality of phenylethylamines is solely responsible for a π-facial discrimination in the 1,3-asymmetric inductions. 相似文献
30.
Anna Onopiuk Klaudia Koodziejczak Monika Marcinkowska-Lesiak Iwona Wojtasik-Kalinowska Arkadiusz Szpicer Adrian Stelmasiak Andrzej Poltorak 《Molecules (Basel, Switzerland)》2022,27(1)
Marinating is one of the most common methods of pre-processing meat. Appropriate selection of marinade ingredients can influence the physicochemical properties of the meat and can reduce the level of polycyclic aromatic hydrocarbons (PAHs) in the final product. The effects of the inclusion of natural plant extracts such as bay leaf (BL), black pepper (BP), turmeric (TU), jalapeno pepper (JP) and tamarind paste (TA) in marinades on the physicochemical properties of grilled pork neck were studied. The addition of spice extracts to marinades increased the proportion of colour components L* and b*. The use of TU, TA, JP, MX and C marinades lowered the hardness and pH of the meat. The highest phenolic compound levels were observed in the case of the mixture of all extracts (MX) and JP marinades, and the highest total antioxidant capacity was exhibited by the BL and MX marinades. The highest PAH content was recorded in the CON marinade (Σ12PAH 98.48 ± 0.81 µg/kg) and the lowest in the JP marinade (4.76 ± 0.08 µg/kg), which had the strongest, statistically significant reducing effect (95% reduction) on PAH levels. Analysis of correlation coefficients showed a relationship between the total antioxidant capacity of the marinades and the PAH content in grilled pork. 相似文献