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91.
Zhang GJ Song KS Nakamura Y Ueno T Funatsu T Ohdomari I Kawarada H 《Langmuir : the ACS journal of surfaces and colloids》2006,22(8):3728-3734
We report a novel method of one-step direct amination on polycrystalline diamond to produce functionalized surfaces for DNA micropatterning by photolithography. Polycrystalline diamond was exposed to UV irradiation in ammonia gas to generate amine groups directly. After patterning, optical microscopy confirmed that micropatterns covered with an Au mask were regular in size and shape. The regions outside the micropatterns were passivated with fluorine termination by C3F8 plasma, and the chemical changes on the two different surfaces--the amine groups inside the patterned regions by one-step direct amination and fluorine termination outside the patterned regions--were characterized by spatially resolved X-ray photoelectron spectroscopy (XPS). The patterned areas terminated with active amine groups were then immobilized with probe DNA via a bifunctional molecule. The sequence specificity was conducted by hybridizing fluorescently labeled target DNA to both complementary and noncomplementary probe DNA attached inside the micropatterns. The fluorescence micropatterns observed by epifluorescence microscopy corresponded to those imaged by optical microscopy. DNA hybridization and denaturation experiments on a DNA-modified diamond show that the diamond surfaces reveal superior stability. The influence of a different amination time on fluorescence intensity was compared. Different terminations as passivated layers were investigated, and as a result, fluorine termination points to the greatest signal-to-noise ratio. 相似文献
92.
Kashimoto K Takata Y Matsuda T Ikeda N Matsubara H Takiue T Aratono M Tanida H Watanabe I 《Langmuir : the ACS journal of surfaces and colloids》2006,22(20):8403-8408
The total-reflection X-ray absorption fine structure (XAFS) method previously employed for the adsorption of dodecyltrimethylammonium bromide (DTAB) at the air/water interface was applied to that in the presence of NaBr. The surface concentration of the bromide ions Gamma(X)(B) of DTAB and NaBr was evaluated by using the Br K-edge absorption jump values of the total-reflection XAFS spectra and was compared to the corresponding value Gamma(H)(B) estimated from the dependence of surface tension on the bulk concentrations of DTAB m(1) and NaBr m(2). The Gamma(X)(B) values trace almost perfectly the Gamma(X)(B) versus m(1) curve up to a concentration near the critical micelle concentration (cmc) and deviate gradually above the concentration. This behavior is basically similar to that of the single DTAB system and ensures that the XAFS method is also applicable to the DTAB system, even in the presence of NaBr. In addition, this method was extended to the single nonionic amphiphile with covalently bonded bromine, and the surface concentrations of 6-bromo-1-hexanol (BrC6OH), Gamma(X)(1) and Gamma(H)(B), were evaluated and compared with each other. It was found that the Gamma(X)(1) value almost perfectly traces the Gamma(H)(1) versus m(1) curve, even at high surface concentrations. The excellent coincidence confirmed that the total-reflection XAFS method can be applied to the nonionic amphiphile system as well as a cationic surfactant with or without an added salt system. Finally, the difference between the Gamma(X)(B) and Gamma(H)(B) values observed in the DTAB with and without an added salt system is briefly described. 相似文献
93.
Aida H Mori K Yamaguchi Y Mizuta S Moriyama T Yamamoto I Fujimoto T 《Organic letters》2012,14(3):812-815
A phosphinite derivative that can be easily prepared in two steps from commercially available aminoindanol was found to be an effective catalyst for enantioselective acylation of diols. For the asymmetric desymmetrization of meso-1,2-diols, the corresponding monoester was obtained in up to 95% ee from the reaction in the presence of 5 mol % catalyst. 相似文献
94.
Iwao Soga Steve Granick 《Colloids and surfaces. A, Physicochemical and engineering aspects》2000,170(2-3):113-117
We measure, for the first time, the separate surface coverage-dependent orientations of trains and of loops/tails in the structure of an adsorbed polymer, and show that these have different average orientations. The system was PMMA (atactic polymethylmethacrylate) adsorbed onto oxidized silicon from dilute solution in carbon tetrachloride at 25.0°C. The method was FTIR-ATR (infrared spectroscopy in attenuated total reflection). With increasing surface coverage, train segments were observed to maintain constant average anisotropy with respect to the solid surface. Free segments were preferentially flattened when the surface coverage was low, but with increasing surface coverage became progressively more random in orientation. Free and bound segments were separated according to shifts of the vibrational frequencies of carbonyl segments upon hydrogen-bonding to the surface silanol groups. The dependence of segmental orientation on molecular weight of the chain is also discussed. 相似文献
95.
A systematic renormalization procedure used in the perturbative calculation of the real-time causal Green's functions at finite temperature is presented. The formalism of thermo field dynamics is employed throughout, permitting the use of Feynman diagram techniques. The renormalizability by means of the temperature-independent counterterms is proved. 相似文献
96.
97.
98.
A series of novel chiral bisazetidines in which two azetidine rings are either directly connected or coupled in tandem style, are synthesized in good yields by the hydroalane reduction of the corresponding bis-beta-lactame. 相似文献
99.
We give a determinant expression for the Bartholdi zeta function of a digraph which is not symmetric. This is a generalization of Bartholdi’s result on the Bartholdi zeta function of a graph or a symmetric digraph. 相似文献
100.
Iwao Katayama Yoshihiro Suzuki Yoshiaki Yamamoto Toshio Oishi 《Monatshefte für Chemie / Chemical Monthly》2005,15(2):1955-1961
The EMF of galvanic cells with stabilized zirconia solid electrolyte was measured to determine the activity of indium in solid
Ni–In alloys in the temperature range of 970–1170 K and composition range of 5–55 mol% In. Activity of indium increases sharply
in the ζ phase and Ni13In9 phase. The activity values are compared with literature data. 相似文献