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71.
Anthony J. Burke Helmut W. Schmalle Bernard A. Brady W. Ivo O'Sullivan 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):484-486
The title compound, C17H14O4, is an unprecedented new synthetic isoaurone‐type enol ether that has the E configuration. The planar furanone ring is fused to a methoxybenzene ring system, with an interplanar angle of 175.7 (1)°. Due to this ring fusion, the six‐membered ring has a significant amount of ring strain, as shown by the internal ring angle range of 115.8 (1)–124.7 (1)°, whereas the vinylic phenyl ring has internal angles between 119.7 (1) and 120.2 (1)°. The molecules form infinite hydrogen‐bonding layers along the b direction of the form C—H?O, where the keto O atom acts as a bifurcated acceptor. These layers are connected along the c direction by another hydrogen bond with a methoxy H atom as donor. In addition to this connection, the layers are stacked via centres of symmetry by a pair of symmetry‐related benzofuranone ring systems. 相似文献
72.
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75.
De Santis F Zona D Bellagotti R Vichi F Allegrini I 《Analytical and bioanalytical chemistry》2004,380(5-6):818-823
Ambient ozone was measured in a forest in Castelporziano (Italy) characterised by the prevailing presence of Holm-oak trees (Quercus ilex L.) from June to November 2003. Two methods for measuring ozone were used: long-term monitoring using diffusive samplers at three heights within the canopy, and continuous monitoring at two heights using the UV method. Results for one week mean ozone levels above and below the canopy from the diffusive samplers were compared to those obtained using the automatic analyser at the same levels. A good correlation between the two sampling techniques was found. Continuous monitoring showed a daily cycle with a midday maximum and a nocturnal minimum. While the forest floor consistently had the lowest ozone concentration, there were no differences during most daytime hours. The midday maximum is clearly due to downward mixing with O3-rich air from above. The night-time ozone decay within the canopy is the result of dry deposition of O3 and most likely due to reaction with biogenically produced NO. AOT40 within and above the canopy mostly exceeded the critical levels. 相似文献
76.
Left Cotorsion Rings 总被引:1,自引:0,他引:1
It is proved that if R is an associative ring that is cotorsionas a left module over itself, and J is the Jacobson radicalof R, then the quotient ring R/J is a left self-injective vonNeumann regular ring and idempotents lift modulo J. In particular,if R is indecomposable, then it is a local ring. 2000 MathematicsSubject Classification 16D50, 16D90, 16L30. 相似文献
77.
Effects of uncertainties in the domain on the solution of Dirichlet boundary value problems 总被引:1,自引:0,他引:1
Summary. A domain with possibly non-Lipschitz boundary is defined as a limit of monotonically expanding or shrinking domains with
Lipschitz boundary. A uniquely solvable Dirichlet boundary value problem (DBVP) is defined on each of the Lipschitz domains
and the limit of these solutions is investigated. The limit function also solves a DBVP on the limit domain but the problem
can depend on the sequences of domains if the limit domain is unstable with respect to the DBVP. The core of the paper consists
in estimates of the difference between the respective solutions of the DBVP on two close domains, one of which is Lipschitz
and the other can be unstable. Estimates for starshaped as well as rather general domains are derived. Their numerical evaluation
is possible and can be done in different ways.
Received October 16, 2001 / Revised version received January 16, 2002 / Published online: April 17, 2002
RID="*"
ID="*" The research was funded partially by the National Science Foundation under the grants NSF–Czech Rep. INT-9724783 and
NSF DMS-9802367
RID="**"
ID="**" Support for Jan Chleboun coming from the Grant Agency of the Czech Republic through grant 201/98/0528 is appreciated 相似文献
78.
The finite element method with Lagrangian multipliers 总被引:2,自引:0,他引:2
Ivo Babuška 《Numerische Mathematik》1973,20(3):179-192
Summary The Dirichlet problem for second order differential equations is chosen as a model problem to show how the finite element method may be implemented to avoid difficulty in fulfilling essential (stable) boundary conditions. The implementation is based on the application of Lagrangian multiplier. The rate of convergence is proved.This paper was supported by the Atomic Energy Commission under Contract No. AEC AT (40-1) 3443/4. 相似文献
79.
Teplý F Stará IG Starý I Kollárovic A Saman D Vyskocil S Fiedler P 《The Journal of organic chemistry》2003,68(13):5193-5197
A nonphotochemical synthetic route to 3-hexahelicenol is reported. It involves a key [2+2+2] cycloisomerization of CH(3)O-substituted triyne that is readily available from 1-methoxy-3-methylbenzene and 1-bromo-2-(bromomethyl)naphthalene. Further functional group transformations led to 3-CO(2)CH(3), 3-NH(2), 3-PPh(2), and 3-SC(O)N(CH(3))(2) substituted hexahelicenes. 相似文献
80.
Using new molecular models of ammonia and methanol and thermodynamic perturbation theory, the global phase diagrams of model mixtures of these compounds with a van der Waals fluid, representing a simple nonpolar fluid, have been calculated. The global phase diagram of these mixtures is much richer than that of corresponding aqueous mixtures. More types of critical line behavior are found, including the presence of van Laar points and a small region where the mixtures exhibit a closed liquid-liquid immiscibility loop (Type VI phase behavior). The individual mixture components are characterized by two molecular parameters, which can be adjusted to their critical temperature and critical volume; the mixture model itself contains no adjustable parameters. It is shown that the theory gives qualitatively correct predietions of mixtures with n-alkanes. This includes the prediction of Type III critical line behavior for small and large values of the ratio of the critical temperatures of the components, and Type II over a large range of conditions, including the presence or absence of absolute or limited azeotropy, and temperature and pressure extrema of critical lines and their dependence on the number of carbon atoms. 相似文献