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排序方式: 共有138条查询结果,搜索用时 146 毫秒
11.
Henriette N. Tobiesen Dr. Lars A. Leth Marc V. Iversen Dr. Line Næsborg Dr. Søren Bertelsen Prof. Dr. Karl Anker Jørgensen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(42):18648-18652
The first stereoselective, near-equimolar, and metal-free oxidative bioconjugation of amino acids and oligopeptides to aldehydes is presented. Based on a newly developed organocatalytic oxidative concept, the C-terminal and side-chain carboxylic acid functionalities of amino acids and oligopeptides are shown to couple in a stereoselective manner to α-branched aldehydes catalyzed by a chiral primary amine and a quinone as oxidizing agent. The oxidative coupling generally proceeds in high yield. For aspartic acid, selective coupling of the side-chain, or the C-terminal carboxylic acid, is demonstrated depending on the protection strategy. The stereoselective, oxidative bioconjugation concept is extended to a series of oligopeptides where coupling to carboxylic acid functionalities is presented. Bioorthogonal linker molecules for further functionalization are obtained by merging the oxidative coupling strategy with the click concept. It is demonstrated that the configuration of the new stereocenter is determined exclusively by the organocatalyst. 相似文献
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Overtone spectrum of o, m and p-nitrobenzaldehydes and p-chlorobenzaldehyde has been studied in 2000–12000 cm−1 region. Vibrational frequencies and anharmonicity constants for aryl as well as alkyl CH stretch vibrations have been determined.
We have also determined the internuclear distances for the aryl CH bond in the different molecules. The small variation observed
in these distances is an indication of the substitution effect.
It is observed that in the case of p-disubstituted benzens, the shift in aryl CH bond is proportional to sum of the Hammet σ of the substituents. However in the
case of o-disubstituted benzenes it is only 80% of the para-substituted shift. 相似文献
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King PD Hatch RC Bianchi M Ovsyannikov R Lupulescu C Landolt G Slomski B Dil JH Guan D Mi JL Rienks ED Fink J Lindblad A Svensson S Bao S Balakrishnan G Iversen BB Osterwalder J Eberhardt W Baumberger F Hofmann P 《Physical review letters》2011,107(9):096802
We report a Rashba spin splitting of a two-dimensional electron gas in the topological insulator Bi(2)Se(3) from angle-resolved photoemission spectroscopy. We further demonstrate its electrostatic control, and show that spin splittings can be achieved which are at least an order-of-magnitude larger than in other semiconductors. Together these results show promise for the miniaturization of spintronic devices to the nanoscale and their operation at room temperature. 相似文献
16.
Exposing the (111) surface of the topological insulator Bi(2)Se(3) to carbon monoxide results in strong shifts of the features observed in angle-resolved photoemission. The behavior is very similar to an often reported "aging" effect of the surface, and it is concluded that this aging is most likely due to the adsorption of rest gas molecules. The spectral changes are also similar to those recently reported in connection with the adsorption of the magnetic adatom Fe. All spectral changes can be explained by a simultaneous confinement of the conduction band and valence band states. This is possible only because of the unusual bulk electronic structure of Bi(2)Se(3). The valence band quantization leads to spectral features which resemble those of a band gap opening at the Dirac point. 相似文献
17.
Ye Sun Stela Canulescu Peijie Sun Frank Steglich Nini Pryds Jørgen Schou Bo Brummerstedt Iversen 《Applied Physics A: Materials Science & Processing》2011,104(3):883-887
Thermoelectric FeSb2 films were produced by pulsed laser deposition on silica substrates in a low-pressure Ar environment. The growth conditions
for near phase-pure FeSb2 films were confirmed to be optimized at a substrate temperature of 425°C, an Ar pressure of 2 Pa, and deposition time of
3 h by ablating specifically prepared compound targets made of Fe and Sb powders in atomic ratio of 1:4. The thermoelectric
transport properties of FeSb2 films were investigated. Pulsed laser deposition was demonstrated as a method for production of good-quality FeSb2 films. 相似文献
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Fischer A Tiana D Scherer W Batke K Eickerling G Svendsen H Bindzus N Iversen BB 《The journal of physical chemistry. A》2011,115(45):13061-13071
Analysis of accurate experimental and theoretical structure factors of diamond and silicon reveals that the contraction of the core shell due to covalent bond formation causes significant perturbations of the total charge density that cannot be ignored in precise charge density studies. We outline that the nature and origin of core contraction/expansion and core polarization phenomena can be analyzed by experimental studies employing an extended Hansen-Coppens multipolar model. Omission or insufficient treatment of these subatomic charge density phenomena might yield erroneous thermal displacement parameters and high residual densities in multipolar refinements. Our detailed studies therefore suggest that the refinement of contraction/expansion and population parameters of all atomic shells is essential to the precise reconstruction of electron density distributions by a multipolar model. Furthermore, our results imply that also the polarization of the inner shells needs to be adopted, especially in cases where second row or even heavier elements are involved in covalent bonding. These theoretical studies are supported by direct multipolar refinements of X-ray powder diffraction data of diamond obtained from a third-generation synchrotron-radiation source (SPring-8, BL02B2). 相似文献
20.
Svendsen H Overgaard J Chen YS Iversen BB 《Chemical communications (Cambridge, England)》2011,47(33):9486-9488
The excited state crystal structure of the ionic complex (Nd(DMA)(4)(H(2)O)(4)-Fe(CN)(6)·3H(2)O (DMA = dimethylacetamide) has been determined at 15 K upon UV illumination by single crystal X-ray diffraction. Significant structural changes are observed around the Fe site in the excited state. These changes are similar to those observed for a related molecular compound exhibiting photomagnetic properties. 相似文献