Study of Transport Properties and Microstructure of Lithium-Conducting Li0.33La0.56TiO3 Ceramic

Russian Journal of Applied Chemistry - Methods of X-ray diffraction analysis, impedance spectroscopy, and scanning electron microscopy were used to examine how thermal treatment modes affect the...     

Optimization of the magnetic field in the analyzing magnet of the axial injection beam line of the cyclotron DC-280

The optimization of the field distribution of the analyzing magnet installed in the axial injection beam line of the cyclotron DC-280 is carried out. This optimization is done on the basis of a three-dimensional calculation of the magnet field. The optimum value of the basic geometrical characteristics of the magnet influencing the form of the field distribution is found.     

Negative U centers, percolation, and the insulator-metal transition in high-T c superconductors

The mechanism of formation of ?U centers in high-T _c superconductors (HTSCs) is considered. It is shown that the transition from the insulator to the metallic state on doping passes through a certain range of dopant concentrations in which it becomes possible for local transitions of singlet electron pairs to occur from oxygen ions to two neighboring cations (a ?U center), while single-electron transitions are still forbidden. Conduction arises in such systems at a concentration of ?U centers exceeding the percolation threshold for the orbitals of singlet hole pairs. A phase diagram constructed on the basis of the proposed model for the HTSC compounds of the Ln-214 class is in complete agreement with experiment. The mechanisms of formation and relaxation of free hole carriers are considered. It is shown that a distinctive feature of the normal state of HTSCs is the dominant contribution of electron-electron scattering to the charge carrier relaxation processes. It is concluded from the analysis presented that HTSCs comprise a special class of solids in which a nonstandard mechanism of superconductivity, different from the BCS mechanism, is realized.     

Infrared absorption spectra of a Nd0.5Ho0.5Fe3(BO3)4 crystal

Infrared absorption spectra of a Nd_0.5Ho_0.5Fe₃(BO₃)₄ crystal in the spectral range of 30–1700 cm^–1 have been measured at temperatures from 6 to 300 K. The experimental spectra have been analyzed based on the semiempirical calculation of the lattice dynamics and the analysis of correlation diagrams of borate complexes. No changes associated with structural phase transitions have been detected in the temperature range of measurements; the effect of magnetic ordering on the infrared absorption spectra has not been observed.     

2-(o-Ammoniophenylamino)-4-oxo-4-phenyl-2-butenoate — Intermediate in the synthesis of 3-phenacylidene-1,2,3,4-tetrahydro-2-quinoxalone

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 697–698, May, 1991.     

On the interpretation of the phase diagram of La<Subscript>2−x</Subscript>M<Subscript>x</Subscript>CuO<Subscript>4</Subscript>

The difference between the phase diagrams of La_2?x(Ba,Sr)_xCuO₄ and Nd_2?xCe_xCuO₄ is discussed. It is proposed that the discrepancy of x-values corresponding to the transition from antiferromagnetic dielectric state to conducting one (respectively, x≈0.06 in La_2?x(Ba,Sr)_xCuO₄ and x≈0.125 in Nd_2?xCe_xCuO₄) results from non-homogeneous doping of La_2?x(Ba,Sr)_xCuO₄ over the range 0.06<x<0.125, when localized holes are added to each second CuO₂ layer. Therefore the actual phase diagram of the “holedoped” superconductor La_2?x(Ba,Sr)_xCuO₄ coincides with one for the “electron-doped” superconductor Nd_2?xCe_xCuO₄. It is shown that all features observed in La_2?x(Ba,Sr)_xCuO₄ around x=0.125 are clarified on this basis.     

Mechanism for selective <Emphasis Type="Italic">para</Emphasis>-disproportionation of toluene on pentasil-based catalysts

We propose a bimolecular mechanism for disproportionation of toluene to form benzene and para-xylene via protonation of the toluene molecule at the methyl group, reaction of the carbocation formed with the para position of the next toluene molecule, and α-scission of the complex obtained. The mechanism presumes formation of methyl diphenyl methane as a byproduct of disproportionation.     

Interference-sensitive photodetector-correlometer of optical signals

The use of an interference-sensitive photodetector for recording a correlation function of counterpropagating light beams and for recording an autocorrelation function (interferogram) of a light beam is considered. A scheme of the correlometer of optical signals without mechanical scanning is presented. Fields of application of new correlometers are suggested.     

IC-100 accelerator complex for scientific and applied research

Industrial production of nuclear filters has been implemented at the IC-100 cyclotron complex of the Laboratory of Nuclear Reactions at the Joint Institute for Nuclear Research. After the complete upgrade, the cyclotron was equipped with the superconducting ECR ion source and the system of external axial beam injection. The implantation complex was equipped with the special transportation channel with the beam scanning system and the setup for irradiation of polymer films. Intense beams of heavy ions Ne, Ar, Fe, Kr, Xe, I, and W with an energy of ～1 MeV/nucleon were obtained. the properties of irradiated crystals were studied, different polymer films were irradiated, and several thousands of square meters of track membranes with pore densities varying in a wide range were produced. Other scientific and applied problems can be solved at the cyclotron complex.     

Charge ordering,superconductivity, and stripes in doped La<Subscript>2</Subscript>CuO<Subscript>4</Subscript>

The special features of the phase diagrams of La_2?xSr_xCuO₄ are considered in terms of the high-temperature superconductivity model according to which the mechanism responsible for the anomalous properties of these compounds is the interaction of electrons with diatomic negative U-centers. A microstructural model that assumes the coexistence of domains with different types of dopant ion ordering is suggested for La_2?xSr_xCuO₄. According to this model, the main characteristics of the experimental phase diagrams of La_2?xSr_xCuO₄ only reflect square lattice geometric relations and competition between different dopant ordering types. Close agreement between the calculated and experimental “superconducting” and “magnetic” phase diagrams is an important argument in favor of the suggested high-temperature superconductivity model.