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151.
E. Makrlík P. Toman P. Vaňura R. Rathore 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):775-779
In methods for quantification of 63Ni, in e.g. reactor coolant water, a chemical separation is required due to 63Ni being a pure beta emitter with limited means of quantification. 60Co, a common radionuclide in reactor coolant water, is not completely separated with the commonly used separation procedure, and it is not resolved from 63Ni in the beta spectrum. The separation method discussed in this work consists of TRU resin (Eichrom) and Ni resin (Eichrom). After running the separation procedure, depending on the initial activity of 60Co, there may still remain enough 60Co to interfere in the measurement of 63Ni. The 60Co interference is corrected for via a gamma spectrometric measurement. This correction may, depending on the 63Ni/60Co ratio, introduce a large contribution to the measurement uncertainty. The aim of this work was to evaluate the possibility to reduce the measurement uncertainty of 63Ni measurements by adding a second Ni separation to the method. Double Ni separations were performed on reactor coolant water having a 60Co activity much higher than the 63Ni activity (63Ni/60Co = 0.01), in order to decrease the radioactivity of 60Co in the sample. The measurement uncertainty of the 63Ni measurement result was reduced by a factor of about three. 相似文献
152.
Scott C. Hagen D. Michael Parrish ? 《International Journal of Computational Fluid Dynamics》2013,27(7):585-595
This paper presents an a posteriori approach to unstructured mesh generation via a localized truncation error analysis and applies it to the Western North Atlantic Tidal (WNAT) model domain. The WNAT model domain encompasses the Gulf of Mexico, the Caribbean Sea, and the North Atlantic Ocean east to the 60°W Meridian. Herein, we pay particular attention to the area surrounding the Bahamas. A bathymetric data set with fine resolution is employed in seven separate linear, harmonic simulations of shallow water tidal flow for seven different tidal-forcing constituents. Each set of simulation results is used to perform a truncation error analysis of a linear, harmonic form of the depth-averaged momentum equations for each of the seven different tidal-forcing frequencies. Truncation error is then driven to a more uniform, domain-wide value by solving for local node spacing requirements. The process is built upon successful research aiming to produce unstructured grids for large-scale domains that can be used in the accurate and efficient modeling of shallow water flow. The methodology described herein can also be transferred to other modeling applications. 相似文献
153.
154.
A convenient procedure for the preparation of various substituted (thio)hydantoins is described. The method is based on Wittig and aza-Wittig reactions of parabanic acids with phosphonium ylides. The reactions occurred both regio- and stereo-selectively. 相似文献
155.
156.
G. D?browska 《Journal of Thermal Analysis and Calorimetry》2012,109(2):745-749
A new compound in the Al?CSb?CV?CO system of the composition AlSbVO6 was successfully synthesized by a solid-state reaction and characterized by powder XRD diffraction. The structural and thermal properties of AlSbVO6 were investigated. The infra-red spectrum of the new phase is presented. 相似文献
157.
Pál Perjési Gábor Maász Renáta Reisch András Benk? 《Monatshefte für Chemie / Chemical Monthly》2012,5(3):1107-1114
Abstract
The non-enzyme-catalyzed reaction of reduced glutathione (GSH) with two tumor cell cytotoxic cyclic chalcone analogues was investigated by reversed-phase high-performance liquid chromatography (RP-HPLC). HPLC analysis of the reaction mixtures indicated the formation of two diastereomeric chalcone–GSH adducts in each case, whose structural assignments were supported by MALDI-TOF-MS and HPLC–MS with electrospray ionization (ESI) measurements. Such reactivity accounts for the previously observed effect of the two cyclic chalcone analogues on the in vivo cellular thiol level of Jurkat T cells. 相似文献158.
Roman Staník Jan Světlík Ivan Benkovsky 《Journal of Radioanalytical and Nuclear Chemistry》2012,293(2):545-554
Meso-2,3-dimercaptosuccinic acid (DMSA) forms stable complexes with a remarkable wide range of metal ions. This relatively small molecule has attracted increasing attention in the field of radiopharmacy, treatment of heavy metal intoxications and nanoparticles preparation. In this review detailed summary of all physical, chemical and biological properties of DMSA and its complex compounds with 99mTc, 186/188Re, 166Ho, 177Lu and 90Y is provided. The clinical utilisation of DMSA complexes in the nuclear medicine and its use for treatment of heavy metal intoxication is briefly summarised. The aspects of its application in the field of nanoparticles preparation is behind the scope of this review, therefore it is only shortly described. 相似文献
159.
Elgiz Bairamov Rukiye ?zturk Mert Zameddin Ismailov 《Journal of mathematical chemistry》2012,50(5):1100-1110
In this work, firstly in the Hilbert space of vector-functions all selfadjoint extensions of the minimal operator generated by linear singular symmetric differential expression with a selfadjoint operator coefficient A in any Hilbert space H, are described in terms of boundary values. Later structure of the spectrum of these extensions is investigated. 相似文献
160.
The reaction of [RuHCl(CO)(PPh3)3] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)2(pyrim-4-Ph)]. The complex has been studied by IR and UV?Cvis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet?Csinglet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV?Cvis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied. 相似文献