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251.
252.
The properties of decays that take place during jet formation cannot be easily deduced from the final distribution of particles in a detector. In this work, we first simulate a system of particles with well-defined masses, decay channels, and decay probabilities. This presents the “true system” for which we want to reproduce the decay probability distributions. Assuming we only have the data that this system produces in the detector, we decided to employ an iterative method which uses a neural network as a classifier between events produced in the detector by the “true system” and some arbitrary “test system”. In the end, we compare the distributions obtained with the iterative method to the “true” distributions. 相似文献
253.
Md Khairul Islam Ivan Lozada Lawag Tomislav Sostaric Edie Ulrich Danny Ulrich Terrence Dewar Lee Yong Lim Cornelia Locher 《Molecules (Basel, Switzerland)》2022,27(7)
Despite its cultural and nutritional importance for local Aboriginal people, the unusual insect honey produced by Western Australian honeypot ant (Camponotus inflatus) has to date been rarely investigated. This study reports on the honey’s physicochemical properties, its total phenolic, major sugars and 5-hydroxymethylfurfural contents, and its antioxidant activities. The honey’s color value is 467.63 mAU/63.39 mm Pfund, it has a pH of 3.85, and its electric conductivity is 449.71 µSiemens/cm. Its Brix value is 67.00, corresponding to a 33% moisture content. The total phenolics content is 19.62 mg gallic acid equivalent/100 g honey. Its antioxidant activity measured using the DPPH* (2,2-diphenyl-1-picrylhydrazyl) and FRAP (ferric reducing–antioxidant power) assays is 1367.67 µmol Trolox/kg and 3.52 mmol Fe+2/kg honey, respectively. Major sugars in the honey are glucose and fructose, with a fructose-to-glucose ratio of 0.85. Additionally, unidentified sugar was found in minor quantities. 相似文献
254.
Flow injection hydride generation electrothermal atomic absorption spectrometric determination of toxicologically relevant arsenic in urine 总被引:6,自引:0,他引:6
Analytical procedure for the determination of toxicologically relevant arsenic (the sum of arsenite, arsenate, monomethylarsonate and dimethylarsinate) in urine by flow injection hydride generation and collection of generated inorganic and methylated hydrides on an integrated platform of a transverse-heated graphite atomizer for electrothermal atomic absorption spectrometric determination (ETAAS) is elaborated. Platforms are pre-treated with 2.7 μmol of zirconium and then with 0.10 μmol of iridium which serve both as an efficient hydride sequestration medium and permanent chemical modifier. Arsine, monomethylarsine and dimethylarsine are generated from diluted urine samples (10–25-fold) in the presence of 50 mmol L−1 hydrochloric acid and 70 mmol L−1 l-cysteine. Collection, pyrolysis and atomization temperatures are 450, 500, 2100 and 2150 °C, respectively. The characteristic mass, characteristic concentration and limit of detection (3σ) are 39 pg, 0.078 μg L−1 and 0.038 μg L−1 As, respectively. The limits of detection in urine are ca. 0.4 and 1 μg L−1 with 10- and 25-fold dilutions. The sample throughput rate is 25 h−1. Applications to several urine CRMs are given. 相似文献
255.
Boris N. Kozlov Ivan I. Pilyugin Valerii G. Shchebelin Alexander V. Bulgakov Alexander P. Mayorov Mikhail R. Predtechenskii 《Mikrochimica acta》1995,120(1-4):111-119
A time-of-flight mass spectrometer with electron impact ionization facility was used in investigations of the laser plume structure. Densities and velocity distributions of positively charged and neutral species were measured 12 cm downstream of the target. Velocities of particles in a plume were measured by the retarding potential method. The combination of a skimmer and declining electric field was used to suppress the influence of charged particles during the measurement of the neutral component parameters. In the case of YBaCuO ceramic laser ablation, a strong variation of the laser-induced plume composition was observed from its head to its tail. It seems to be accounted for by the difference of the starting (phase transition) temperatures of various layers of a plume. Ions detected mainly in the head of a plume were followed by atoms, molecules and clusters in inverse succession to their appearance in the plume under the light intensity increase. The characteristic of the number density dependence upon the laser spot diameter make it clear that most of the molecules BaO and YO are the direct product of ablation. In contrast, the detected clusters with masses up to 2000 amu are the product of condensation in the expanding plume under the conditions of the experiments. 相似文献
256.
Violeta D. Kassabova-Zhetcheva Lilyana P. Pavlova Bisserka I. Samuneva Zara P. Cherkezova-Zheleva Ivan G. Mitov Mikhail T. Mikhov 《Central European Journal of Chemistry》2007,5(1):107-117
Structural and magnetic properties of Mg
x
Zn1−x
Fe2O4 powders have been studied with respect to the application for thermal cancer therapy (magnetic hyperthermia). Mg
x
Zn1−x
Fe2O4 (x=0.1–0.5) powders with particle sizes between 5 and 8 nm were produced by citrate method. The X-ray diffraction patterns
of the samples correspond to a spinel phase. The lattice constant and the volume of the elementary cell increase when x changes
from 0.1 to 0.5. The FTIR-spectra ascertain the spinel phase formation. The Mossbauer studies reveal the presence of extremely
small particles, which undergo superparamagnetic relaxation at room temperature. The core-shell model has been applied to
explain quadruple doublets. The quadruple splitting at “shells” is bigger than those at “cores” whereas the isomer shifts
remain close. Magnetic studies confirm the presence of extremely small particles that behave as superparamagnetic ones.
相似文献
257.
Goodchild I Collier L Millar SL Prokes I Lord JC Butts CP Bowers J Webster JR Heenan RK 《Journal of colloid and interface science》2007,307(2):455-468
The surface, phase and aggregation behaviour of mixtures of 1-alkyl-3-methylimidazolium halide, [C(n)mim]X, where n is the alkyl chain length, with water has been explored using a variety of methods. Critical micelle concentrations (cmc) and micelle structures have been determined for aqueous [C(n)mim]Br solutions for n=2, 4, 6, 8, and 10. Small-angle neutron scattering (SANS) measurements reveal that for the n=8 and 10 systems, at concentrations just above the cmc, small near-spherical aggregates exist, which, after initial growth, possess core radii (aggregation numbers) at intermediate concentrations of 10.5+/-0.5 Angstrom (22+/-2) and 13.2+/-0.5 Angstrom (40+/-3), respectively, for n=8 and n=10. Towards higher concentrations, the aggregates appear to grow, with the aggregates in the [C(10)mim]Br system becoming increasingly elongated (prolate) with increasing concentration. No evident aggregates are formed in the systems with n=2 and 4. In the n=6 system, it appears that oblate aggregates with radius approximately 9 Angstrom form at the cmc and that the radius increases with increasing concentration. For longer alkyl chain lengths, at high concentrations lyotropic mesophases form in some systems. The mesophase region for the [C(8)mim]Cl system has been explored across the composition range using X-ray diffraction and (2)H NMR spectroscopy. Both techniques suggest that a major hexagonal phase with lattice parameter of 29.5+/-0.5 Angstrom coexists with a minor lamellar phase (23.5+/-0.3 Angstrom) or possibly a second hexagonal phase (27.1+/-0.4 Angstrom). The area per adsorbed molecule at the surface of [C(8)mim]Br solutions has been measured as a function of concentration using neutron reflectometry. A minimum in the area per molecule behaviour is coincident with a minimum identified in the surface tension isotherm occurring close to the cmc. The data suggest depletion of [C(8)mim]Br from the surface region occurs at concentrations immediately above the cmc. 相似文献
258.
Oleksii Zozulia Ivan V. Korendovych 《Angewandte Chemie (International ed. in English)》2020,59(21):8108-8112
The self‐assembly of short peptides gives rise to versatile nanoassemblies capable of promoting efficient catalysis. We have semi‐rationally designed a series of seven‐residue peptides that form hemin‐binding catalytic amyloids to facilitate enantioselective cyclopropanation with efficiencies that rival those of engineered hemin proteins. These results demonstrate that: 1) Catalytic amyloids can bind complex metallocofactors to promote practically important multisubstrate transformations. 2) Even essentially flat surfaces of amyloid assemblies can impart a substantial degree of enantioselectivity without the need for extensive optimization. 3) The ease of peptide preparation allows for straightforward incorporation of unnatural amino acids and the preparation of peptides made from d ‐amino acids with complete reversal of enantioselectivity. 相似文献
259.
Anna Tashchilova Nadezhda Podoplelova Alexey Sulimov Danil Kutov Ivan Ilin Mikhail Panteleev Khidmet Shikhaliev Svetlana Medvedeva Nadezhda Novichikhina Andrey Potapov Vladimir Sulimov 《Molecules (Basel, Switzerland)》2022,27(4)
In the modern world, complications caused by disorders in the blood coagulation system are found in almost all areas of medicine. Thus, the development of new, more advanced drugs that can prevent pathological conditions without disrupting normal hemostasis is an urgent task. The blood coagulation factor XIIa is one of the most promising therapeutic targets for the development of anticoagulants based on its inhibitors. The initial stage of drug development is directly related to computational methods of searching for a lead compound. In this study, docking followed by quantum chemical calculations was used to search for noncovalent low-molecular-weight factor XIIa inhibitors in a focused library of druglike compounds. As a result of the study, four low-molecular-weight compounds were experimentally confirmed as factor XIIa inhibitors. Selectivity testing revealed that two of the identified factor XIIa inhibitors were selective over the coagulation factors Xa and XIa. 相似文献
260.
Ivan P. Gavrilyuk Wolfgang Hackbusch Boris N. Khoromskij. 《Mathematics of Computation》2005,74(250):681-708
In earlier papers we developed a method for the data-sparse approximation of the solution operators for elliptic, parabolic, and hyperbolic PDEs based on the Dunford-Cauchy representation to the operator-valued functions of interest combined with the hierarchical matrix approximation of the operator resolvents. In the present paper, we discuss how these techniques can be applied to approximate a hierarchy of the operator-valued functions generated by an elliptic operator .