Directed random polymers via nested contour integrals

We study the partition function of two versions of the continuum directed polymer in 1+1$1+1$ dimension. In the full-space version, the polymer starts at the origin and is free to move transversally in R$\mathbb{R}$, and in the half-space version, the polymer starts at the origin but is reflected at the origin and stays in R₋${\mathbb{R}}_{-}$. The partition functions solve the stochastic heat equation in full-space or half-space with mixed boundary condition at the origin; or equivalently the free energy satisfies the Kardar–Parisi–Zhang equation.     

Gravitomagnetic and Gravitoelectric Waves in General Relativity

Lower-order terms in expansions of the equations of General Relativity in powers of v/c (post-Newtonian approximations) have long been a source of analogies with em theory. A classic textbook example is the steadily spinning sphere generating a constant dipole gravitomagnetic field, with its associated vector potential B^* ₀ = × (analog of the magnetic field B of a spinning charged sphere). In the nonsteady case there are associated gravitoelectric fields E* = – _t – * also, where * is the gravitational Coulomb potential. The case of a rigid sphere spun up from rest by an external (nongravitational) torque at t = 0 is enlightening, as it demonstrates the generation of B* and E* wave fields propagating outward with the velocity of light c: for large t, B* B^* ₀. In a coordinate system for which the metric tensor is nearly equal to the Minkowski tensor, the three-vector potential obeys an equation isomorphic to the electrodynamic equation, that is, ² = –*j* with j* = –v, where is the mass density, v the three-velocity, and * = 16Gc^–2 = 3.7 × 10^–26 mksu, G being the gravitational constant. Significantly, one can construct a gauge invariant four-vector potential F* = (ic^–14*, ), obeying field equations isomorphic to Maxwell's in the Lorentz gauge F _, = 0. The traveling transient dipole field exerts torques on matter in its path, setting up shear strains that may be measurable for very large momentum transfers, for example, between massive astronomical bodies. A rough calculation suggests that such strains are in principle observable.     

Mass Spectrometry of Some Benzylidene Imidazolidinediones and Thiazolidinediones. II- chlorobenzyl imidazolidinedione and Fluoro or Chlorobenzyl Thiazolidinedione Compounds

In the present investigation, a study of the electron impact mass spectrometry data is reported for seven compounds of a series of some 3-(4-chlorobenzyl)-5-benzylidene-imidazolidine-2, 4-diones and 3-(4-fluoro or chlorobenzyl)-5-benzylidene-thiazolidine-2, 4-diones previously synthesized.     

Theoretical study of the helio hydrogen cyanide dication HeCNH2+

The structure and stability of the helio hydrogen cyanide molecular ion, HeCNH²⁺, is investigated by standard quantum chemical methods. Single reference calculations are carried out using second-order perturbation theory (MP2), the coupled cluster expansion in the CCSD approximation, and the hybrid approach using a perturbative estimate of the triple excitation energy component designated CCSD(T). Multireference calculations using a complete active space (CASSCF) and a second-order perturbation theory estimate of correlation effects (CASPT2) are reported.     

Spaces of Abstract Events

We generalize the concept of a space of numerical events in such a way that this generalization corresponds to arbitrary orthomodular posets whereas spaces of numerical events correspond to orthomodular posets having a full set of states. Moreover, we show that there is a natural one-to-one correspondence between orthomodular posets and certain posets with sectionally antitone involutions. Finally, we characterize orthomodular lattices among orthomodular posets.     

Assessment of dynamic closure for premixed combustion large eddy simulation

Turbulent piloted Bunsen flames of stoichiometric methane–air mixtures are computed using the large eddy simulation (LES) paradigm involving an algebraic closure for the filtered reaction rate. This closure involves the filtered scalar dissipation rate of a reaction progress variable. The model for this dissipation rate involves a parameter β_c representing the flame front curvature effects induced by turbulence, chemical reactions, molecular dissipation, and their interactions at the sub-grid level, suggesting that this parameter may vary with filter width or be a scale-dependent. Thus, it would be ideal to evaluate this parameter dynamically by LES. A procedure for this evaluation is discussed and assessed using direct numerical simulation (DNS) data and LES calculations. The probability density functions of β_c obtained from the DNS and LES calculations are very similar when the turbulent Reynolds number is sufficiently large and when the filter width normalised by the laminar flame thermal thickness is larger than unity. Results obtained using a constant (static) value for this parameter are also used for comparative evaluation. Detailed discussion presented in this paper suggests that the dynamic procedure works well and physical insights and reasonings are provided to explain the observed behaviour.     

Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction

Time-resolved single-crystal diffraction performed with synchrotron radiation shows that the 53(1) micros phosphorescent state, generated in the crystalline phase of trimeric {[3,5-(CF3)(2)Pyrazolate]Cu}(3) molecules by exposure to 355 nm of light at 17 K, is due to the formation of an excimer rather than the shortening of the intramolecular Cu...Cu distances within the trimeric units, or the formation of a continuous chain of interacting molecules. One of the intermolecular Cu...Cu distances contracts by 0.56 Angstroms from 4.018(1) to 3.46(1) Angstroms;, whereas the interplanar spacing of the trimers is reduced by 0.65 Angstroms; from 3.952(1) to 3.33(1) Angstroms. Density-functional theory calculations support the formation of a Cu...Cu bond through the intermetallic transfer of a Cu 3d electron to a molecular orbital with a large 4p contribution on the reacting Cu atoms.     

Two-zone elastic-plastic single shock waves in solids

By decoupling time and length scales in moving window molecular dynamics shock-wave simulations, a new regime of shock-wave propagation is uncovered characterized by a two-zone elastic-plastic shock-wave structure consisting of a leading elastic front followed by a plastic front, both moving with the same average speed and having a fixed net thickness that can extend to microns. The material in the elastic zone is in a metastable state that supports a pressure that can substantially exceed the critical pressure characteristic of the onset of the well-known split-elastic-plastic, two-wave propagation. The two-zone elastic-plastic wave is a general phenomenon observed in simulations of a broad class of crystalline materials and is within the reach of current experimental techniques.