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221.
A novel procedure for the determination of stability constants in systems with neutral analytes and charged complexation agents by affinity capillary electrophoresis was established. This procedure involves all necessary corrections to achieve precise and reliable data. Temperature, ionic strength, and viscosity corrections were applied. Based on the conductivity measurements, the average temperature of the background electrolyte in the capillary was kept at the constant value of 25°C by decreasing the temperature of the cooling medium. The viscosity correction was performed using the viscosity ratio determined by an external viscosimeter. The electrophoretical measurements were performed, at first, at constant ionic strength. In this case, the increase of ionic strength caused by increasing complexation agent concentration was compensated by changing of the running buffer concentration. Subsequently the dependence of the analyte effective mobility on the complexation agent concentration was measured without the ionic strength compensation (at variable ionic strength). The new procedure for determination of the stability constants even from such data was established. These stability constants are in a very good agreement with those obtained at the constant ionic strength. The established procedure was applied for determination of the thermodynamic stability constants of (R, R)-(+)- and (S, S)-(-)-hydrobenzoin and R- and S-(3-bromo-2-methylpropan-1-ol) complexing with 6-monodeoxy-6-mono(3-hydroxy)propylamino-β-cyclodextrin hydrochloride. 相似文献
222.
Characterization of metal threads on historical textile materials is important for preservation of valuable cultural heritage. Obtained results dictate decisions on cleaning, conservation and restoration steps. The most important part of characterization is chemical analysis of originally applied materials, since this enables understanding the nature of chemical and physical degradation and determines the cleaning methods. Methods applied should be non-destructive and sensitive enough to detect trace elements in small sample amounts. The goal of this research was to describe the most useful procedures for fast and simple determination of specific metals of interest. Therefore we propose application of scanning electron microscopy equipped with EDS detector (SEM-EDS) for sample surface analysis and inductively coupled plasma-optical emission spectroscopy (ICP-OES) for chemical analysis of metals threads. For quality insurance reasons, a comparative method applied for chemical analysis was atomic absorption spectrometry (AAS). This combination of methods has proven to be very useful in analysis of historical samples, since SEM-EDS was a simple and non-destructive method which provided information on chemical composition of sample surfaces, while ICP-OES and AAS enabled the full insight into the average chemical composition of samples. Nevertheless, both ICP-OES and AAS were destructive methods which demanded dissolving of samples prior to the analysis. In this work nine different metal fibers collected from historical textile materials were characterized. Proposed methods enabled obtaining information on sample constitution, morphology, topology and chemical composition. 相似文献
223.
Iva Jovanovic Jon K. Magnuson Frank Collart Barbara Robbertse William S. Adney Michael E. Himmel Scott E. Baker 《Cellulose (London, England)》2009,16(4):687-697
Genome sequencing of a variety of fungi is a major initiative currently supported by the Department of Energy’s Joint Genome
Institute. Encoded within the genomes of many fungi are upwards of 200+ enzymes called glycoside hydrolases (GHs). GHs are
known for their ability to hydrolyze the polysaccharide components of lignocellulosic biomass. Production of ethanol and “next
generation” biofuels from lignocellulosic biomass represents a sustainable route to biofuels production. However, this process
has to become more economical before large scale operations are put into place. Identifying and characterizing GHs with improved
properties for biomass degradation is a key factor for the development of cost effective processes to convert biomass to fuels
and chemicals. With the recent explosion in the number of GH encoding genes discovered by fungal genome sequencing projects,
it has become apparent that improvements in GH gene annotation processes have to be developed. This will enable more informed
and efficient decision making with regard to selection and utilization of these important enzymes in bioprocess that produce
fuels and chemicals from lignocellulosic feedstocks. 相似文献
224.
Based on Lie groups theory, this work considers the problem of decomposition of a given rotation into three successive finite rotations with prescribed in advance axes. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
225.
Bojinov Martin Betova Iva Karastoyanov Vasil 《Journal of Solid State Electrochemistry》2023,27(7):1835-1846
Journal of Solid State Electrochemistry - Anodic film growth on a Ti alloy in water-containing ethylene glycol electrolyte with addition of fluoride... 相似文献
226.
227.
Lea Vuletić Ivana Lapić Stjepan Špalj Iva Marolt Banek Domagoj Jakovac Jasmina Šipkar Dunja Rogić 《Electroanalysis》2023,35(5):e202200399
Ion-selective electrode pocket meters available for use with saliva could be a convenient tool to assess how diseases, drugs, exercise or nutrition affect salivary composition. This study compared salivary sodium and potassium concentrations measured by handheld LAQUAtwin meters and a fully-automated biochemical analyzer. Agreement between two methods was assessed with Passing-Bablok regression and Bland-Altman plots. LAQUAtwin meters measured lower values of both analytes and provided repeatable though not accurate results. The meters may serve as an alternative to laboratory methods to gain insight into between-group differences in electrolyte concentrations, or a concentration change induced by an experimental procedure. 相似文献