Bipolar tri-state resistive switching characteristics in Ti/CeO_x/Pt memory device

Highly repeatable multilevel bipolar resistive switching in Ti/Ce Ox/Pt nonvolatile memory device has been demonstrated. X-ray diffraction studies of Ce O2 films reveal the formation of weak polycrystalline structure. The observed good memory performance, including stable cycling endurance and long data retention times（〉10^4s） with an acceptable resistance ratio（～10^2）, enables the device for its applications in future non-volatile resistive random access memories（RRAMs）. Based on the unique distribution characteristics of oxygen vacancies in Ce Ox films, the possible mechanism of multilevel resistive switching in Ce Ox RRAM devices has been discussed. The conduction mechanism in low resistance state is found to be Ohmic due to conductive filamentary paths, while that in the high resistance state was identified as Ohmic for low applied voltages and a space-charge-limited conduction dominated by Schottky emission at high applied voltages.     

Heat transfer of dilute viscoelastic solutions in helical exchangers

The study examined heat transfer of two dilute viscoelastic solutions in helical exchangers of circular cross-section. Ten helical coil heat exchangers with diameter ratios ranging from 4 to 50 were constructed. Results showed doubling the concentrations of polymer increased heat transfer performance by 12 %. The results were expressed in forms of some existing equations and were found to be in fair agreement to previous results.     

Effect of localized faults on chaotic vibration of rolling element bearings

This paper investigates the effect of localized faults on the chaotic vibration of rolling element bearings. The presence of chaotic behavior is demonstrated using experimental vibration data. A nonlinear mathematical model is developed that captures bearing dynamics. The numerical simulations of the model agree with the experimental evidence and provide insight into the bearings chaotic response in a wide range of rotational speeds. The bearing chaotic behavior is quantified using the Lyapunov exponent and correlation dimension. It is further shown that these measures can be exploited in detecting bearing failure.     

Multi-wavelength ytterbium doped fiber laser based on longitudinal mode interference

Multi-wavelength Ytterbium-doped fiber laser (YDFL) is demonstrated using a longitudinal mode interference assisted by a four-wave mixing (FWM) effect in a ring laser cavity. The gain medium is a 16 m long of the fabricated (Ytterbium-doped fiber) YDF, which has a core composition of 0.8 wt % of Yb₂O₃, 1.8 wt % of Al₂O₃ and 23 wt % of GeO₂, Ytterbium ion fluorescence lifetime of 1.1 ms and absorption of 9.0 dB/m at the pump wavelength of 976 nm. 20 m long photonic crystal fiber (PCF) is used to provide FWM effect so that the energy of different oscillating lines can be redistributed to improve multi-wavelength operation. The proposed laser generates 12 lines of optical comb with a line spacing of approximately 0.59 nm at 1035 nm region.     

The influence of pressure on the electrical conductivity of molten zinc chloride and its Mixtures with potassium chloride

Abstract

The electrical conductivities of molten ZnCl₂ and its mixtures with KCl were measured as functions of pressure, temperature, and composition. The measuremkents were performed in an internally heated pressure vessel in which the melts were contained in open quartz glass cells. The addition of KCl to molten ZnCl₂ causes a large increase of the conductivity at all pressures and temperatures. With increasing pressure the conductivity increases in pure molten ZnCl₂ and in mixtures rich in ZnCl₂ and decreases in mixtures with more than 30 mol% of KCl.     

Global volume conservation in unsteady free surface flows with energy absorbing far‐end boundaries

A wave absorption filter for the far‐end boundary of semi‐infinite large reservoirs is developed for numerical simulation of unsteady free surface flows. Mathematical model is based on finite volume solution of the Navier–Stokes equations and depth‐integrated continuity equation to track the free surface. The Sommerfeld boundary condition is applied at the far‐end of the truncated computational domain. A dissipation zone is formed by applying artificial pressure on water surface to dissipate the kinetic energy of the outgoing waves. The computational scheme is tested to verify the conservation of total fluid volume in the domain for long simulation durations. Combination of the Sommerfeld boundary and dissipation zone can effectively minimize reflections and prevent cumulative changes in total fluid volume in the domain. Solitary wave, nonlinear periodic waves and irregular waves are simulated to illustrate the numerical developments. Earthquake excited surface waves and nonlinear hydrodynamic pressures in a dam–reservoir are computed. Copyright © 2009 John Wiley & Sons, Ltd.     

A necklace model for vesicles simulations in 2D

The aim of this paper is to propose a new numerical model to simulate 2D vesicles interacting with a Newtonian fluid. The inextensible membrane is modeled by a chain of circular rigid particles, which are maintained in cohesion by using two different types of forces. First, a spring force is imposed between neighboring particles in the chain. Second, in order to model the bending of the membrane, each triplet of successive particles is submitted to an angular force. Numerical simulations of vesicles in shear flow have been run using FEM and the FreeFem++ software. Exploring different ratios of inner and outer viscosities, we recover the well‐known ‘tank‐treading’ and ‘tumbling’ motions predicted by a theory and experiments. Moreover, for the first time, 2D simulations of the ‘vacillating‐breathing’ regime without special ingredient such as thermal fluctuations are recovered. Copyright © 2014 John Wiley & Sons, Ltd.     

Solvent and structural effects in tautomeric 3-cyano-4-(substituted phenyl)-6-phenyl-2(1H)-pyridones: experimental and quantum chemical study

The tautomeric equilibria between 2-pyridone and 2-hydroxypyridine forms of methoxy, chloro, and nitro derivatives of 3-cyano-4-(2-, 3-, and 4-substituted phenyl)-6-phenyl-2(1H)-pyridones were evaluated from UV/Vis spectral data. Linear solvation energy relationships of Kamlet–Taft and Catalán-rationalized solvent have influence on tautomeric equilibria. Transmission of substituent effect was analyzed by the Hammett equation. Quantum chemical calculations were performed by density functional theory (B3LYP). The experimental data were interpreted with the aid of time-dependent density functional method. Electron density distribution was analyzed by Bader’s analysis. It was found that substituents of different electronic properties change the extent of conjugation, and affect intramolecular charge transfer character. Theoretical calculations and experimental results gave insight into the influence of the molecular conformation on the transmission of substituent effects, as well as on contribution of different solvent–solute interactions.