全文获取类型
收费全文 | 115篇 |
免费 | 5篇 |
专业分类
化学 | 87篇 |
数学 | 2篇 |
物理学 | 31篇 |
出版年
2023年 | 3篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2014年 | 1篇 |
2013年 | 3篇 |
2012年 | 14篇 |
2011年 | 7篇 |
2010年 | 7篇 |
2009年 | 2篇 |
2008年 | 11篇 |
2007年 | 7篇 |
2006年 | 3篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1996年 | 1篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 3篇 |
排序方式: 共有120条查询结果,搜索用时 15 毫秒
81.
S. Ishio T. NarisawaS. Takahashi Y. KamataS. Shibata T. HasegawaZ. Yan X. LiuH. Yamane Y. KondoJ. Ariake 《Journal of magnetism and magnetic materials》2012,324(3):295-302
FePt films that have a high degree of order S in their L10 structure (S>0.90) and well-defined [0 0 1] crystalline growth perpendicular to the film plane were fabricated on thermally oxidized Si substrates by the addition of an oxide and successive rapid thermal annealing (RTA). The mechanism of L10 ordering and [0 0 1] crystalline growth perpendicular to the film plane arising through the oxide addition and RTA process is also discussed. The L10 ordering (S>0.90) and the [0 0 1] crystalline growth were achieved by (1) lowering the activation energy due to in-plane tensile stress and the initiation of L10 ordering at a low temperature, (2) [0 0 1] crystalline growth through in-plane tensile stress, and (3) enhancement of atomic diffusion via the addition of an oxide and the resultant lowering of the ordering temperature. Effect (1) was observed in the case of SiO2 addition, effect (2) was generally observed in the case of oxide addition and the RTA process, and effect (3) was prominent in the case of ZnO addition. With the addition of ZnO, the L10 ordering started at below 400 °C and was completed at 500 °C. Finally, dot patterns were successfully fabricated down to a diameter of 15 nm using electron beam lithography, and the magnetic state of the dot pattern was observed by magnetic force microscopy. 相似文献
82.
Okada K Nandi M Maruyama J Oka T Tsujimoto T Kondoh K Uyama H 《Chemical communications (Cambridge, England)》2011,47(26):7422-7424
Mesoporous polyacrylonitrile (PAN) monolith has been fabricated by a template-free approach using the unique affinity of PAN towards a water/dimethyl sulfoxide (DMSO) mixture. A newly developed Thermally Induced Phase Separation Technique (TIPS) has been used to obtain the polymer monoliths and their microstructures have been controlled by optimizing the concentration and cooling temperature. 相似文献
83.
This paper describes preparation and properties of green nanocomposites from renewable resources. The nanocomposites were synthesized by an acid-catalyzed curing of epoxidized natural oils in the presence of silane coupling agents. The resulting nanocomposites were transparent and highly glossy. Their hardness and Young's modulus of the nanocomposite coatings improved, as compared with those only from the epoxidized natural oils. Dynamic viscoelasticity analysis and TEM observation showed the homogeneous structure of the nanocomposites. The properties of the nanocomposites were strongly affected by the structure and feed ratio of the monomers. 相似文献
84.
Thermoresponsive sol–gel transition polymers based on biodegradable poly(amino acid) were synthesized by the reaction of poly(succinimide) with dodecylamine and amino alcohols. The introduction of the hydrophobic amine into the thermoresponsive poly(amino acid)s induced the sol–gel transition in phosphate buffer saline. The effects of the side chain structure, molecular weight, concentration of the polymer, and the additives (inorganic salts and urea) in the solution on the thermoresponsive behaviors were systematically investigated. A relationship between the lowest critical solution temperature (LCST) in the dilute solution and the viscosity reduction of the concentrated solution upon heating was observed. The present poly(amino acid)s showing a thermoresponsive sol–gel transition in aqueous solutions possess immense potential as an injectable biodegradable hydrogel system for various biomedical applications. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
85.
Hayashi H Lightcap IV Tsujimoto M Takano M Umeyama T Kamat PV Imahori H 《Journal of the American Chemical Society》2011,133(20):7684-7687
A bottom-up strategy has been developed to construct a multiple electron transfer system composed of organic/inorganic ternary composites (porphyrin, zinc oxide nanoparticles, reduced graphene oxide) on a semiconducting electrode without impairing the respective donor-acceptor components. The hierarchical electron transfer cascade system exhibited remarkably high photocurrent generation with an incident-photon-to-current efficiency of up to ca. 70%. 相似文献
86.
Ken‐Ichi Seno Itsuko Tsujimoto Takunobu Kikuchi Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2008,46(18):6151-6164
Thermosensitive forced gradient copolymers with various sequence distributions were synthesized by living cationic polymerization in the presence of an added base. The synthesis was conducted using a semibatch reaction method, which is unfavorable for ionic polymerization, especially when a simple apparatus is employed. Polymerization of 2‐ethoxyethyl vinyl ether (EOVE) was initiated using a conventional syringe technique. Immediately after initiation, 2‐methoxyethyl vinyl ether (MOVE) was continuously added using a syringe pump at regulated feed rates, which allowed control of the sequence distribution. The resulting gradient copolymers of EOVE and MOVE underwent thermally induced association in water, forming micelles with a hydrophobic core derived from EOVE‐rich segments. Interestingly, the size of the micelles obtained from gradient copolymers decreased monotonously with increasing solution temperature, while the micelles of the corresponding block copolymers were unchanged in size. This self‐association behavior can be controlled by designing the gradient pattern of the instantaneous composition. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6151–6164, 2008 相似文献
87.
Takashi Murashima Satoshi Tsujimoto Toshifumi Miyazawa Noboru Ono 《Tetrahedron letters》2005,46(1):113-116
Water-soluble bicycloporphyrin and benzoporphyrin having octacarboxyl groups are synthesized from the corresponding octaester porphyrin by simple hydrolyzing and heating procedures. These compounds are characterized by UV-vis, NMR and mass spectroscopies. The benzoporphyrin octacarboxylic acid exhibits extremely high planarity in spite of its poly-substitution. 相似文献
88.
Masaki Tsujimoto Tomoki Yabutani Atsushi Sano Yuji Tani Hiroki Murotani Yuji Mishima Kenichi Maruyama Mikito Yasuzawa Junko Motonaka 《Analytical sciences》2007,23(1):59-63
A glucose sensor was developed by electrocopolymerization using pyrroles containing a tris-bipyridine (bpy) osmium complex (Os-py), pyrrole (py), pyrrole propanoic acid (PPA) and glucose oxidase (GOx) to improve the key performance characteristics, such as the sensitivity, selectivity, and long-term stability. Tris-bipyridine osmium pyrrole complexes with four different methylene moieties were utilized to correlate the methylene length with the glucose sensor performance. The electrocatalytic response of glucose was clearly observed at electrodes modified with Os-py, except for the electrode immobilized with the Os-py complex containing the shortest methylene moiety. The current response to glucose increased up to a concentration of 100 mmol dm(-3). The electrocatalytic response to glucose at the [Os(bpy)(2)(py(6)-bpy)](2+/3+)/py/PPA/GOx electrode was stable for more than 100 days. Dissolved oxygen and potential interference compounds (ascorbic acid, uric acid, and acetaminophen) minimally perturbed the current response to glucose at the [Os(DM-bpy)(2)(py(6)-bpy)](2+/3+)/py/PPA/GOx electrode. Based on these results, a longer methylene moiety appears to improve the performance characteristics of a glucose sensor fabricated via the electropolymerization of tris-bipyridine osmium pyrrole complexes. 相似文献
89.
90.
The forced volume magnetostriction of the fcc Fe-Ni Invar alloys has been measured in the temperature range from 77 to 900 K to elucidate the magnetovolume effect at finite temperatures. The temperature dependence of (θ ω/θ(H/M) is evaluated as well as (θ ω/θH), where ω is the volume expansion. These results are discussed using a phenomenological model for the magnetovolume effect which takes into account the contribution of the correlation between local magnetic moments. 相似文献