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11.
Isabelle Vidal 《manuscripta mathematica》2005,118(1):43-70
Let S be the spectrum of a discrete valuation ring of residue characteristic p>0. Let Z be a scheme separated and of finite type over S, and denote by Kc(Z,) (l≠p) the Grothendieck group of -constructible sheaves on the etale site of Z. In this article, we introduce the subgroup of virtual sheaves with virtual wild ramification zero, and we prove that this subgroup is preserved by the formalism of six operations “à la Grothendieck”. 相似文献
12.
Local Dispersive and Strichartz Estimates for the Schrödinger Operator on the Heisenberg Group 下载免费PDF全文
Hajer Bahouri & Isabelle Gallagher 《数学研究通讯:英文版》2023,39(1):1-35
It was proved by Bahouri et al. [9] that the Schrödinger equation on
the Heisenberg group $\mathbb{H}^d,$ involving the sublaplacian, is an example of a totally
non-dispersive evolution equation: for this reason global dispersive estimates
cannot hold. This paper aims at establishing local dispersive estimates on $\mathbb{H}^d$ for the linear Schrödinger equation, by a refined study of the Schrödinger kernel $S_t$ on $\mathbb{H}^d.$ The sharpness of these estimates is discussed through several
examples. Our approach, based on the explicit formula of the heat kernel on $\mathbb{H}^d$ derived by Gaveau [19], is achieved by combining complex analysis and
Fourier-Heisenberg tools. As a by-product of our results we establish local Strichartz estimates and prove that the kernel $S_t$ concentrates on quantized horizontal hyperplanes of $\mathbb{H}^d.$ 相似文献
13.
Nash constructible functions on a real algebraic set V are defined as linear combinations, with integer coefficients, of Euler characteristic of fibres of proper regular morphisms restricted to connected components of algebraic sets. We prove that if V is compact, these functions are sums of signs of semialgebraic arc-analytic functions (i.e. functions which become analytic when composed with any analytic arc). We also give a sharp upper bound to the number of semialgebraic arc-analytic functions which are necessary to define any given Nash constructible functions. 相似文献
14.
Vijay Singh R.P.S. Chakradhar Isabelle Ledoux-Rak Laurent Badie Fabienne Pelle Svetlana Ivanova 《Journal of luminescence》2009,129(11):1375-1380
New near-infrared luminescent, monoclinic CaAl2O4:Er3+ phosphor was prepared by using the combustion route at furnace temperatures as low as 500 °C in a few minutes. Combustion synthesized phosphor has been well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive analysis of X-ray (EDAX) mapping studies. The luminescence spectra of Er3+-doped calcium aluminate were studied at UV (380 nm), vis (488 nm) and IR (980 nm) excitation. Upon UV and vis excitation, the CaAl2O4:Er3+ phosphor exhibits emission bands at ~523 nm and at ~547 nm, corresponding to transitions from the 2H11/2 and 4S3/2 erbium levels to the 4I15/2 ground state. A strong luminescence at 1.55 μm in the infrared (IR) region due to 4I13/2→4I15/2 transition has been observed in CaAl2O4:Er3+ phosphor upon 980 nm CW pumping. In the spectrum of IR-excited up-conversion luminescence, green (~523 and ~547 nm) and red (662 nm) luminescence bands were present, the latter associated with the 4F9/2→4I15/2 transitions of Er3+ ions. Both excited state absorption and energy transfer may be proposed as processes responsible for the population of the 4S3/2 and 4F9/2 erbium levels upon IR excitation. The mechanisms responsible for the up-conversion luminescence are discussed. 相似文献
15.
Vijay Singh Vineet Kumar Rai S. Watanabe T. K. Gundu?Rao Isabelle Ledoux-Rak Ho-Young Kwak 《Applied Physics A: Materials Science & Processing》2010,100(4):1123-1130
YAG phosphor powders doped/codoped with Er3+/(Er3+ + Yb3+) have been synthesised by using the solution combustion method. The effect of direct pumping into the 4I11/2 level under 980 nm excitation of doped/codoped Er3+/Yb3+−Er3+ in Y3Al5O12 (YAG) phosphor responsible for an infrared (IR) emission peaking at ∼1.53 μm corresponding to the 4I13/2→4I15/2 transition has been studied. YAG exhibits three thermally-stimulated luminescence (TSL) peaks at around 140°C, 210°C and
445°C. Electron spin resonance (ESR) studies were carried out to identify the centres responsible for the TSL peaks. The room
temperature ESR spectrum of irradiated phosphor appears to be a superposition of two distinct centres. One of the centres
(centre I) with principal g-value 2.0176 is identified as O− ion, while centre II with an isotropic g-factor 2.0020 is assigned to an F+ centre (singly ionised oxygen vacancy). An additional defect centre is observed during thermal-annealing experiments and
this centre (assigned to F+ centre) seems to originate from an F-centre (oxygen vacancy with two electrons) and these two centres appear to correlate
with the observed high-temperature TSL peak in YAG phosphor. 相似文献
16.
Ohkoshi S Tokoro H Hozumi T Zhang Y Hashimoto K Mathonière C Bord I Rombaut G Verelst M Cartier dit Moulin C Villain F 《Journal of the American Chemical Society》2006,128(1):270-277
This article describes the studies of a photomagnetic cyanide-bridged Cu-Mo bimetallic assembly, Cu(II)(2)[Mo(IV)(CN)(8)].8H(2)O (Cu(II), S = (1)/(2); Mo(IV), S = 0) (1), which has an intervalence transfer (IT) band from Mo(IV)-CN-Cu(II) to Mo(V)-CN-Cu(I) around 480 nm. Wide-angle X-ray scattering and X-ray spectroscopic studies provide precise information about the 3D connectivity and the local environment of the transition metal ions. Irradiating with blue light causes solid 1 to exhibit a spontaneous magnetization (Curie temperature = 25 K). The thermal reversibility is carefully studied and shows the long-time stability of the photoinduced state up to 100 K. Photoreversibility is also observed; i.e., the magnetization is induced by irradiation with light below 520 nm, while the magnetization is reduced by irradiation with light above 520 nm. The UV-vis absorption spectrum after irradiation shows a decrease of the IT band and the appearance of the reverse-IT band in the region of 600-900 nm (lambda(max) = 710 nm). This UV-vis absorption spectrum is recovered to the original spectrum by irradiation with 658-, 785-, and 840-nm light. In this photomagnetic effect, the excitation of the IT band causes an electron transfer from Mo(IV) to Cu(II), producing a ferromagnetic mixed-valence isomer of Cu(I)Cu(II)[Mo(V)(CN)(8)].8H(2)O (Cu(I), S = 0; Cu(II), S = (1)/(2); Mo(V), S = (1)/(2)) (1'). 1' returns to 1 by irradiation of the reverse-IT band, which obeys the scheme for the potential energy surface in mixed-valence class II compounds. 相似文献
17.
Absalon C Fabre S Tarascou I Fouquet E Pianet I 《Analytical and bioanalytical chemistry》2011,401(5):1489-1499
Tannins represent a key element in red wine flavors, so researchers have made a lot of effort to try to understand the role
of their structure in wine taste in recent decades. We report some new routes to achieve a true structure–taste relationship
for the major tannins found in wine, which are procyanidins in their monomeric or oligomeric state. All these routes use synthetic
standards. New advances in their synthesis and their analyses using chromatographic methods, NMR spectroscopy, and mass spectrometry
to obtain more precise information about their chemical structure, including their stereochemistry and their precise degree
of polymerization and galloylation, are described. 相似文献
18.
19.
Fave C Hissler M Sénéchal K Ledoux I Zyss J Réau R 《Chemical communications (Cambridge, England)》2002,(16):1674-1675
In plane parallel arrangement and enhancement of NLO-activity are observed upon coordination of heteroditopic dipoles containing a phosphole ring on square-planar d8-palladium centre. 相似文献
20.
Lana G. Kaiser Ma?gorzata Marjańska Gerald B. Matson Isabelle Iltis Seth D. Bush Brian J. Soher Susanne Mueller Karl Young 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2010,202(2):259-266
Glutathione (GSH) is a powerful antioxidant found inside different kinds of cells, including those of the central nervous system. Detection of GSH in the human brain using 1H MR spectroscopy is hindered by low concentration and spectral overlap with other metabolites. Previous MRS methods focused mainly on the detection of the cysteine residue (GSH-Cys) via editing schemes. This study focuses on the detection of the glycine residue (GSH-Gly), which is overlapped by glutamate and glutamine (Glx) under physiological pH and temperature. The first goal of the study was to obtain the spectral parameters for characterization of the GSH-Gly signal under physiological conditions. The second goal was to investigate a new method of separating GSH-Gly from Glx in vivo. The characterization of the signal was carried out by utilization of numerical simulations as well as experiments over a wide range of magnetic fields (4.0–14 T). The proposed separation scheme utilizes J-difference editing to quantify the Glx contribution to separate it from the GSH-Gly signal. The presented method retains 100% of the GSH-Gly signal. The overall increase in signal to noise ratio of the targeted resonance is calculated to yield a significant SNR improvement compared to previously used methods that target GSH-Cys residue. This allows shorter acquisition times for in vivo human clinical studies. 相似文献